臺灣博碩士論文加值系統

本論文將首次利用電化學沈積法結合具有規則排列之多孔結構氧化鋁模板來輔助成長一維鋅錫合金奈米線，並於高溫爐於700℃持溫10小時成長一維氧化鋅錫奈米線；使用掃描電子顯微鏡 (Field-Emission-Scanning Electron Microscopy，FESEM)觀察氧化鋁模板表面形態、結構及一維氧化鋅錫奈米線填充高度與分佈情形，並利用X 光單晶繞射儀(X-Ray Diffraction，XRD)觀察一維氧化鋅錫奈米線之晶體方向，並使用X 光能量散譜儀(Energy Dispersive Spectrometer，EDS)觀察一維氧化鋅錫奈米線之元素定性及成分比例分析，觀察得到一維氧化鋅錫奈米線之鋅錫比例為 3: 97、50: 50、66: 34及90:10，最後再以紫外光-可見光光譜儀(UV-Visiuble spectrophotometer)進行分析一維氧化鋅錫奈米線之光學特性。

One-dimensional Zinc-Tin Oxide nanowires are firstly prepared by electrodeposition in the anodic aluminum oxide (AAO) template, and were oxidized at 700℃ for 10 hours. Field-Emission-Scanning electron microscopy indicates that the ordered Zinc-Tin Oxide nanowire arrays are entirely filled into pore of the AAO template. X-ray diffraction result shows that the as-synthesized one-dimensional nanowires are crystalline and have the highly preferential orientation. Energy dispersive spectrometer analysis observation shows the composition atomic ratio of Zn to Sn is very close to 3:97, 50:50, 66:34 and 90:10. The comparisons of different atomic ratio nanowire arrays are observed by the measurements of ultraviolet-visible absorption spectroscopy (UV-vis).

中文摘要 iii
Abstract iv
目錄 v
圖目錄 vii
表目錄 viii
第一章 緒論 1
1.1 前言 1
1.2 研究動機與目的 3
第二章 文獻回顧 5
2.1 奈米科技的定義與特性 5
2.1.1量子侷限效應(Quantum confinement effect) 5
2.2 透明導電氧化物 6
2.2.1 透明導電氧化物之發展 6
2.2.2 透明導電氧化物之摻雜 7
2.2.3 透明導電氧化物之製備 10
2.2.4 透明導電氧化物之光學性質 12
2.2.5 透明導電氧化物之應用 14
2.3多孔性結構之氧化鋁模板 15
2.3.1氧化鋁奈米多孔模板的結構特徵 15
2.3.2氧化鋁奈米多孔模板的成長機制 17
2.3.3氧化鋁奈米多孔模板的製備變因 20
2.3.4陽極處理近年來在製作奈米級多孔模板上的應用 23
第三章 研究方法 25
3.1 實驗流程 25
第四章 結果與結論 25
參考文獻 29

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