為妥善處理廢水酸鹼中和自動化程序，我們採用虛擬多質子酸來模擬進料組成，以修飾過後的強酸當量來推出此虛擬多質子酸之數學模型，再利用適應控制中的最小平方法來估測出相關參數，以反轉滴定將相關參數線性化，定義誤差並導入控制器中。模擬結果顯示，我們提出的控制器估算法，能夠快速獲得虛擬多質子酸的參數，使系統達到理想的pH控制。

In order to tackle waste water neutralization processes, a single fiction polyprotic acid is used to represent the influent stream. The polyprotic acid model is then derived by the modified strong acid equivalent and model parameters are estimated by on-line least squared method. Using the obtained model parameters, the error of controller is parameterized by an inverse of the titration curve instead of pH values. The computer simulation results show the proposed control algorithms are able to quickly reach the values of the parameters of the fiction polyproitc acid and provide a good performance for pH neutralization processes.

目錄 iv
中文摘要 i
英文摘要 ii
表目錄 vii
圖目錄 viii
第一章　緒論 1
1-1 前言 1
1-2　文獻回顧 1
1-3　研究動機與目的 3
1-4　論文架構 4
第二章　酸鹼中和系統 5
2-1　前言 5
2-2　反應系統動態模式 5
2-3　系統模式說明與模擬 8
2-4　本章結論 11
第三章　適應控制 18
3-1　前言 18
3-2　適應控制系統 18
3-2-1 參考模型適應控制系統 18
3-2-2 具有受控裝置數學模式線上鑑別的適應控制系統 19
3-3　遞迴最小平方法(Recursive least-squares estimation, RLS) 20
3-4　參數估測的發散 26
3-5　進料成分的震盪 26
3-6　本文系統之適應控制推導 27
3-7　控制器設計 29
3-8　本章結論 32
第四章　模擬結果 38
4-1　前言 38
4-2　單質子酸進料 38
4-2-1　單質子酸震盪進料 38
4-2-2　單質子酸加入分割範圍控制 39
4-2-3　單質子酸震盪進料 ( 加入分割範圍控制 ) 39
4-3　雙質子酸進料 40
4-3-1　雙質子酸震盪進料 40
4-3-2　雙質子酸加入分割範圍控制 40
4-3-3　雙質子酸震盪進料 ( 加入分割範圍控制 ) 41
4-4　本章結論 42
第五章 結論與未來展望 68
參考文獻 69

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