臺灣博碩士論文加值系統

亞鐵離子活化過硫酸鹽(persulfate, S2O82-)生成硫酸根自由基(SO4-•, E0~2.6 V)可有效氧化三氯乙烯(trichloroethylene, TCE)，但此方式會受限於SO4-•被過多亞鐵離子之存在而攫取抑制及Fe2+會快速氧化轉換為Fe3+。本研究探討以EDTA(ethylediaminetetraacetic acid)螯合Fe3+於pH 3、7、10條件下活化過硫酸鹽降解三氯乙烯之效能。
實驗結果顯示Fe3+和EDTA單獨存在時，並不會造成過硫酸鹽之降解。然而，EDTA/Fe3+螯合物可有效地活化S2O82-，並予以降解TCE。於較高pH條件下，EDTA/Fe3+活化過硫酸鹽系統中，因TCE之存在於氧化過程中可能造成鐵還原循環以活化過硫酸鹽，因而引起過硫酸鹽和EDTA快速降解。當反應系統中pH值增加則會加速TCE、S2O82-和EDTA之降解速率及氯離子之生成速率，其反應速率皆符合假一階反應動力。
因此，於pH 10條件下，改變EDTA/Fe3+螯合比實驗結果顯示，螯合比1/1條件相較其他比例，獲得較高TCE降解速率。由不同氧化劑量實驗結果可知，較高過硫酸鹽劑量於EDTA/Fe3+螯合比1/1時能提升TCE降解速率，但若過高過硫酸鹽濃度，僅會增加過硫酸鹽之降解速率，並無法提升TCE降解速率。綜觀實驗結果得知，於ISCO之應用上以EDTA螯合三價鐵活化過硫酸鹽以降解三氯乙烯，具有發展潛力。

中文摘要……….……………………………………………………I
英文摘要……………………………………………………………II
目錄……………………………………………………………….III
表目錄………………………………………………………………VI
圖目錄……………………………………………………………VIII
第ㄧ章　前言………………………………………………………1
1-1　研究緣起…………………………………………………1
1-2　研究目的…………………………………………………3
第二章　文獻回顧………………………………………………4
2-1　三氯乙烯污染概述…………………………………………4
2-1-1　三氯乙烯物化特性…………………………………4
2-1-2　三氯乙烯土壤及地下水污染………………………7
2-1-3　土壤及地下水污染整治方法……………………………9
2-2　過硫酸鹽之氧化原理及影響因素…………………………18
2-2-1　過硫酸鹽基本化學特性…………………………………18
2-2-2　硫酸根自由基之化學介紹………………………………20
2-2-3　過硫酸鹽處理技術及發展現況…………………………25
2-3 EDTA基本特性及應用………………………………………28
2-3-1　EDTA物化特性……………………………………………28
2-3-2　EDTA螯合特性 ………………………………………….29
2-3-3　EDTA於污染整治上之應用………………………………37
第三章　研究材料及方法……………………………………….43
3-1　實驗流程……………………………………………………43
3-2　實驗儀器及藥品…………………………………………47
3-3　實驗分析方法………………………………………………50
第四章　結果與討論…………………………………………….57
4-1　EDTA/Fe3+於不同pH下活化過硫酸鹽………………….57
4-1-1 Fe3+對過硫酸鹽降解之影響……………………………57
4-1-2 EDTA對過硫酸鹽降解之影響……………………………59
4-1-3 EDTA/Fe3+對過硫酸鹽降解之影響…………………….61
4-2　EDTA/Fe3+於不同pH下活化過硫酸鹽氧化三氯乙烯….66
4-2-1 EDTA/Fe3+或Fe3+對三氯乙烯降解之影響…………….68
4-2-2 過硫酸鹽對三氯乙烯降解之影響………………………72
4-2-3 Fe3+活化過硫酸鹽對三氯乙烯降解之影響……………76
4-2-4 EDTA/Fe3+活化過硫酸鹽降解三氯乙烯之影響……….79
4-3　EDTA/Fe3+螯合比對活化過硫酸鹽降解TCE之影響……84
4-4 氧化劑量對EDTA螯合鐵活化過硫酸鹽降解TCE之影響.88
第五章　結論與建議…………………………………………….92
5-1　結論…………………………………………………………92
5-2　建議…………………………………………………………94
參考文獻…………………………………………………………95

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