跳到主要內容

臺灣博碩士論文加值系統

(3.236.68.118) 您好!臺灣時間:2021/07/31 19:33
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果 :::

詳目顯示

: 
twitterline
研究生:吳建聖
研究生(外文):Chien-Sheng Wu
論文名稱:苝-3,4,9,10-四羧酸酐衍生物的合成、鑑定與應用
論文名稱(外文):Synthesis, Characterization and Application of Perylene-3,4,9,10-tetracarboxylic Dianhydride's Derivatives
指導教授:葉茂榮葉茂榮引用關係
指導教授(外文):Mou-Yung Yeh
學位類別:碩士
校院名稱:國立成功大學
系所名稱:化學系碩博士班
學門:自然科學學門
學類:化學學類
論文種類:學術論文
論文出版年:2008
畢業學年度:96
語文別:中文
論文頁數:83
中文關鍵詞:苝-3 4 9 10-四羧酸酐Suzuki-Coupling酯化太陽能電池
外文關鍵詞:Perylene-3 4 9 10-tetracarboxylic dianhydrideesterificationSuzuki-CouplingSolar Cell
相關次數:
  • 被引用被引用:0
  • 點閱點閱:118
  • 評分評分:
  • 下載下載:23
  • 收藏至我的研究室書目清單書目收藏:0
太陽能電池發電是現今非常熱門的研究課題,其中又以有機薄膜太陽能電池最具有發展潛力。苝是具有良好電子遷移率的化合物,已經有許多將其應用在有機薄膜太陽能電池的研究。

本論文討論從苝-3,4,9,10-四羧酸酐出發,將之溴化,再進行酯化反應,製備三種不同碳數的1,7-二溴苝-3,4,9,10-四羧酸酯。再經由Suzuki-Coupling合成一系列帶有多共軛系統的衍生物;所合成之產物的光學能階差在2.32~2.49電子伏特之間。最後透過UV-Vis、PL和CV來探討其結構與光電性質之關係。
The development of solar cell has been a popular topic, recently the researches focus on the organic-thin-film-type . Various perylene derivatives with good electron mobility are promising materials for organic solar cells .
New compounds with aromatic group were synthesized via esterification with simple phase transfer catalysis (PTC) method and Suzuki-coupling.
Several perylene-3,4,9,10-tetracarboxylic dianhydride’s have been synthesized. The optical energy gap (Eg) of these new compounds are between 2.32eV to 2.49eV. The relationship between the structure and photoelectric property of these new compounds were studied .
目次:
誌謝--------------------------------------------
中文摘要----------------------------------------
英文摘要----------------------------------------

第一章、緒論-------------------------------------1
1-1前言------------------------------------------1
1-2太陽能電池的介紹------------------------------2
1-3太陽能電池的種類------------------------------6
1-4太陽能電池發電原理----------------------------17
1-5有機薄膜太陽能電池發電原理--------------------20

第二章、實驗設計---------------------------------22
2-1研究目標--------------------------------------22
2-2文獻回顧--------------------------------------23
2-2-1 Suzuki-Coupling的介紹---------------------29
2-2-2 Suzuki-Coupling的反應機制-----------------31


2-3實驗設計與研究--------------------------------32
2-3-1苝-3,4,9,10-四羧酸酯的合成與研究------------33
2-3-2 1,7-二溴苝-3,4,9,10-四羧酸酐的合成----------37
2-3-3 1,7-二溴苝-3,4,9,10-四羧酸酯的合成與研究----38
2-3-4 1,7-二芳香環-苝-3,4,9,10-四羧酸酯的合成與研究-------------------------------------------------41

第三章、實驗內容----------------------------------43
3-1實驗藥品--------------------------------------43
3-2儀器介紹--------------------------------------46
3-3實驗步驟--------------------------------------48
3-3-1苝-3,4,9,10-四羧酸酯的合成------------------48
3-3-2 1,7-二溴苝-3,4,9,10-四羧酸酐的合成----------50
3-3-3 1,7-二溴苝-3,4,9,10-四羧酸酯的合成----------51
3-3-4 1,7-二芳香環-苝-3,4,9,10-四羧酸酯的合成-----55




第四章、結果與討論--------------------------------63
4-1苝-3,4,9,10-四羧酸酐衍生物的UV光譜討論-------63
4-2苝-3,4,9,10-四羧酸酐衍生物的PL光譜討論-------72
4-3苝-3,4,9,10-四羧酸酐衍生物的電化學性質討論----74

第五章、結論--------------------------------------80
參考文獻----------------------------------------- 83
1. 楊素華 蔡泰成 科學發展2005年6月,390期51
2. G. P. Smestad, Solar Energy Mater. Solar Cells, 82, 227 (2004).
3. a. M. A. Green, Prog. Photovolt: Res. Appl., 8, 127 (2000).
b. M. A. Green, Prog. Photovolt: Res. Appl., 8, 443 (2000).
c. M. A. Green, Prog. Photovolt: Res. Appl., 9, 123 (2001).
d. M. A. Green, Prog. Photovolt: Res. Appl., 13, 447 (2005).
4. T. Surek, J. Cryst. Growth, 275, 292 (2005).
5. H. Spanggaard, and F. C. Krebs, Solar Energy Mater. Solar Cells, 83, 125 (2004).
6. W. E. Spear and P. G. LeComber, Solid State Commun., Vol. 17, p.1193, 1975.
7. D. E. Carlson and C. R. Wronski, Appl. Phys. Lett., Vol. 28, 671-673, 1975.
8. E.Ruud ,I.Schropp and Miro Zeman, IEEE Trans. on Electron Devices, Vol. 46, 2086-2092, 1999.
9. A. Shah, P. Torres, R. Tscharner, N. Wyrsch, H. Keppner
Science 30 July 1999: Vol. 285. no. 5428, 692–698
10. E. B. Yousfi, B. Weinberger, F. Donsanti, P. Cowache and D. Lincot Thin Solid Films Volume 387, Issues 1-2, 29 May 2001, 29-32
11. T.L. Chu, S.S. Chu, J. Britt, C. Ferekides, C. Wang,
C. Q. Wu, H. S. Ullal, Electron Device Letters, IEEE Volume 13, Issue 5, May 1992 303–304
12. Y. Endo, T. Fujiwara, S. Nishizaki, K. Nishioka, and H. Matsumura 22nd European Photovoltaic Solar Energy Conference (PVSEC) and Exhibition Milan, Italy September 3–7, 2007
13. K. Fujimoto, F. Nakabeppu, Y. Sogawa, Y. Okayasu, K. Kumagai, Photovoltaic Specialists Conference, 1993., Conference Record of the Twenty Third IEEE Volume , Issue , 10-14 May 1993 83–87
14 .J. Kuendig, M. Goetz, X. Niquille, A. Shah, S. Vaccaro,
J. Mosig, L. Gerlach, P. de Maagt, E. Fernandez,
Photovoltaic Specialists Conference, 2000. Conference Record of the Twenty-Eighth IEEE Volume , Issue , 2000 1079 – 1082
15. M. A. Green, K. Emery, D. L. King, Y. Hishikawa, and W. Warta, Prog. Photovoltaics Res. Appl. 14, 455-461 (2006).
16. Brian O'Regan and Michael Grätzel
Nature 353, 737 - 740 (1991).
17. U. Bach , D. Lupo , P. Comte , J. E. Moser , F. Weissortel , J. Salbeck , H. Spreitzer , M. Gratzel Nature 1998, vol. 395,number 6702, 583-585
18. G.P. Smestad, M. Grätzel, J. Chem. Educ. 75, 752 (1998).
19. A. Kay, M. Grätzel, J. Phys. Chem. 97, 6272 (1993).
20. F. O. Lenzmann and J. M. Kroon Advances in OptoElectronics
Volume 2007 (2007), Article ID 65073, 10 pages
21. C.W. Tang, APPl. Phys. Lett. 1985, 48, 183
22. 莊嘉琛, "太陽能工程-太陽電池篇," 全華科技圖書股份有限公司,中華民國九十年十月初版三刷。
23. M. M. Shi, H.Z. Chen, J.Z. Sun, J. Ye, M. Wang, Chem. Commun. 14 (2003) 1710.
24. M. M. Shi, H.Z. Chen, J.Z. Sun, J. Ye, M. Wang, Chem. Phys.
Lett. 381 (2003) 666.

25. L. Schmidt-Mende, A. Fechtenkötter, K. Müllen, E. Moons, R. H. Friend, J. D. MacKenzie Science 10 August 2001:
Vol. 293. no. 5532, 1119 - 1122
26. B. A. Gregg, Chem. Phys. Lett. 258 (1996) 376.
27. H. Langhals , R. Ismael , O. Yuruk Tetrahedron 56 (2000) 5435-5441
28. Shengxiong Xiao, Matthew Myers, Qian Miao, Sebastien Sanaur,Keliang Pang , Michael L. Steigerwald,and Colin Nuckolls Angew. Chem. Int. Ed. 1998, 37,1434
29. Jwanro Hassan, Marc Sevignon, Christel Gozzi Emmanuelle Schulz, and MarcLemaire , Chem. Rev. 2002, 102, 1359-1469
30. Chun-Chieh Chao, Man-kit Leung, Yuhlong Oliver Su, Kuo-Yuan Chiu, Tsung-Hsien Lin, Shwu-Ju Shieh, and Shien-Chang Lin J. Org. Chem. 2005, 70, 4323-4331
31. Y. Liu, Ms. Nishiura , Y. Wang ,Z. M. Hou J.AM.CHEM. SOC. 2003, 125, 437-443
32. Hualei Qian, Zhaohui Wang, Wan Yue, and Daoben Zhu J. Am. Chem. Soc.; (Communication); 2007; 129(35);
10664-10665
33. Timothy E. Barder, Shawn D. Walker, Joseph R. Martinelli, and Stephen L. Buchwald J. AM. CHEM. SOC. 2005, 127, 4685-4696
34. Steven V. Ley, Prof. Dr., Andrew W. Thomas, Dr.
Angew. Chem. Int. Ed. 2003, 42, 5400–5449
35. Michael J. Ahrens, Louise E. Sinks, Boris Rybtchinski, Wenhao Liu, Brooks A. Jones, Jovan M. Giaimo, Alexy V. Gusev, Andrew J. Goshe, David M. Tiede, and Michael R. Wasielewski J. AM. CHEM. SOC. 2004, 126, 8284-8294
36. Tamar van der Boom, Ryan T. Hayes, Yongyu Zhao, Patrick J. Bushard, Emily A. Weiss, and Michael R. Wasielewski
J. AM. CHEM. SOC. 2002, 124, 9582-9590
37. Alix Arnaud, Jol Belleney, Francois Boue, Laurent Bouteiller,* Geraldine Carrot, and Veronique Wintgens Angew. Chem. Int. Ed. 2004, 43, 1718–1721
38. J. H. Kirchhoff, M. R. Netherton, I. D. Hill, G. C. Fu,
J. Am. Chem. Soc., 2002, 124, 13662-13663.
39. X. Cui, T. Qin, J.-R. Wang, L. Liu, Q.-X. Guo, Synthesis,
2007, 393-399.
40. S. Li, Y. Lin, J. Cao, S. Zhang, J. Org. Chem., 2007, 72,
4067-4072.
41. G. Altenhoff, R. Goddard, C. W. Lehmann, F. Glorius, Angew.
Chem. Int. Ed., 2003, 42, 3690-3693.
42. W.-J. Liu, Y.-X. Xie, Y. Liang, J.-H. Li, Synthesis, 2006,
860-864.
43. J. V. Kingston, J. G. Verkade, J. Org. Chem., 2007, 72,
2816-2822.
44. Marion, O. Navarro, J. Mei, E. D. Stevens, N. M. Scott,
S. P. Nolan, J. Am. Chem. Soc., 2006, 128, 4101-4111.
45. Billingsley, K. W. Anderson, S. L. Buchwald, Angew. Chem.
Int. Ed., 2006, 45, 3484-3488.
46. C. Song, Y. Ma, Q. Chai, C. Ma, W. Jiang, M. B. Andrus,
Tetrahedron, 2005, 61, 7438-7446.
47. A. S. Guram, X. Wang, E. E. Bunel, M. M. Faul, R. D. Larsen,
M. J. Martinelli, J. Org. Chem., 2007, 72, 5104-5112.
48. J. Baxter, D. Steinhuebel, M. Palucki, I. W. Davies,
Org. Lett., 2005, 7, 215-218.
49. K. R. Buszek, N. Brown, Org. Lett., 2007, 9, 707-710.
50. J. K. Stille, K. S. Y. Lau, Acc. Chem. Res. 1977, 10,
434–442.
51. A. L. Casado, P. Espinet, Organometallics 1998, 17,
954–959.
52. B. H. Ridgway, K. A. Woerpel, J. Org. Chem. 1998, 63,
458–460.
53. 史銘翔;”含1,3,4-二唑吡啶衍生物之合成及發光性質研究”
國立成功大學化學研究所碩士論文,民國93年.
QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top