臺灣博碩士論文加值系統

全像資訊儲存具有高傳輸速度及高儲存容量的特性，使得這項技術成為記錄媒介中最廣為被研發的應用科學之ㄧ。主要因為全像材料使用的感光高分子基材，具有高敏感度、動態範圍廣、製程簡便等特性。所以，本研究藉由添加有機金屬鐿離子 (Yb3+)和鉺離子 (Er3+)來改善9,10-phenanthrenequinone (PQ)/Poly(methyl methacylate)的全像儲存性質。這種混摻材料有效地在全像特性量測中有顯著的改善效果。添加鐿離子的PQ感光高分子從原本繞射效率40%提升到59%，而添加鉺離子的感光高分子則提升到47%，增加率分別為47%和17%。而在另一全像特性動態曲線的量測當中，累加光柵強度添加鐿離子的PQ感光高分子從原本1.16提升到2.12，而添加鉺離子的感光高分子則提升到1.58，增加率分別為82%和36%。最後，在敏感度部份，樣品掺有鐿離子的敏感度由原本0.08變為0.14，而掺有鉺離子的樣品則變為0.09。這相關的研究機制，本研究藉由UV-vis、FT-IR、PL光譜和NMR來探討其光化學反應的變化。

Holographic storage is considered a new kind of optical storage technology in the next generation because this technology has significant gains in storage densities and data transfer rate. The holographic characteristics of PQ/poly(methyl methacrylate) have been significantly improved by doping metallic ion Yb3+ and Er3+. The hybrid materials display significant enhancement in the holographic characteristics. The diffraction efficiency promote to 59% with Yb3+, to 47% with Er3+ from the undoped sample is 40%. The increment is up to 47% in Yb3+ sample；the dynamic range enhance to 2.12 and 1.58 on Yb3+ and Er3+ containing sample individually in comparison to 1.16 for the undoped copolymer. The increment of dynamic range is up to 82% for Yb3+ containing sample. The related mechanism of these changes is preliminary discussed with the analysis of UV-vis, FT-IR, PL spectroscopy and NMR.

目錄
中文摘要 I
英文摘要 II
致謝 III
目錄 IV
圖表索引 VI

第一章 序論 1
第二章 文獻回顧 3
2-1全像紀錄光學 3
2-1-1全像紀錄發展歷史 3
2-1-2全像成像技術 4
2-2全像紀錄材料 5
2-3化學相關原理 12
2-3-1起始劑遇熱分解 12
2-3-2單體聚合反應 12
2-3-3 PQ照光反應機制 13
第三章 研究動機 16
第四章 實驗方法 17
4-1化學藥品 17
4-2儀器設備及實驗條件 18
4-3單體的純化及玻璃容器製作 21
4-3-1單體的純化 21
4-3-2玻璃容器製作 22
4-4樣品的配製 22
第五章 結果與討論 24
5-1去結晶水 25
5-2光波長選擇 26
5-3全像紀錄特性量測 28
5-4化學結構分析 32
5-5 探討有機金屬離子與PQ關係 38
第六章 結論 49
第七章 未來展望 50
7-1探討氧化鋅對於全像光學性質影響 50
7-1-1化學藥品 50
7-1-2實驗流程 51
7-1-3奈米粒子檢定 52
7-1-4全像特性分析 57
7-1-5結論 60
7-2 PQ對各溶劑的溶解度 60
7-3總結與心得 61
第八章 參考文獻 62

參考文獻
1. R. A. Lessard, G. Manivannan, Proc. SPIE - Holographic Materials, 2405, 2 (1995).
2. P. Judeinstein, P. W. Oliveira, H. Krug, H. Schmidt, Adv. Mater., 7, 123 (1997)
3. ISOM’06 Optical Memory Roadmap, http://www.isom.jp/roadmap.html
4. D. Gabor, Proc. of the Royal Society A, 197, 454 (1949).
5. Stanford’ histsorical society, http://histsoc.stanford.edu/pdfmem/GouldRG.pdf
6. B. A. Lengyel, American J. of Physics, 34, 903 (1966).
7. T. H. Maiman, R. H. Hoskins, I. J. D'Haenens, C. K. Asawa, V. Evtuhov, Phys. Rev., 123, 1151 (1961).
8. E. N. Leith, J. Upatnieks, J. Opt. Soc. Am., 52, 1123 (1962).
9. S. J. Zilker, Chemphyschem, 3, 333 (2002)
10. T. Imait, S. Yagi, H. Yamazaki, Jpn. J. Appl. Phys., 38, 1984 (1999).
11. R. A. Lessard, G. Manivannan, Proc. SPIE - Holographic Materials, 2405, 2 (1995).
12. R. H. Wopschall, T. R. Pampalone, Appl. Opt., 10, 1636 (1971).
13. C. H. Wang, J. L. Xia, Macromolecules, 21, 3519 (1988).
14. J. T. Sheridan, J. R. Lawrence, J. Opt. Soc. Am. A, 17, 1108 (2000).
15. V. Weiss, E. Millul, A. A. Friesem, Proc. SPIE - Photopolymeric holographic recording media, 2688, 11 (1996).
16. K. D. Belfield, K. J. Schafer, Y. U. Liu, J. Phys. Org. Chem., 13, 837 (2000).
17. T. Suzuki, C. Q. He, V. Shantarovich, Radiation Phys. Chem., 66, 161 (2003).
18. Y. H. Cho, C. W. Shin, N. Kim, B. K. Kim, Y. Kawakami, Chem. Mater., 17, 6263 (2005).
19. V. K. S Hsiao, C. G. Lu, G. S. He, M. Pan, A. N.Cartwright, P. N. Prasad, R. Jakubiak, R. A. Vaia, T. J. Bunning, Opt. Exp., 13, 3787 (2005).
20. A. Jitianu, M. Gartner, M. Zaharescu, Mater. Sci. Eng. C, 23, 301 (2003).
21. C. Pizzocaro, C. Lafond, M. Bolte, J. Photoch. Photobio. A , 151, 221 (2002).
22. Y. J. Zhang, Z. F. Lu, X. F. Deng, Opt. Commun., 220, 289 (2003).
23. M. J. Kim, C. Chun, T. Nakayama, Jpn. J. Appl. Phys., 45, 169 (2006)
24. S. C. Fu, Y. C. Liu, L. Dong, Mater. Let., 59, 1449 (2005).
25. R. M.Tejedor, M. Millaruelo, L. Oriol, J. Mater. Chem., 16, 1674 (2006).
26. J. E. Millerd, N.J. Brock, M. S. Brown, Opt. Let., 20, 626 (1995).
27. I. G. Marine, D. Bersani, P. P. Lottici, Opt. Mater., 15, 279 (2001).
28. H. Takahashi, J. Yamauchi, Y. Tomita, Jap. J. Appl. Phys., 44, 1008 (2005).
29. J. Park, E. Kim, Eng. Mater., 277, 1039 (2005).
30. C. B. Fitzgerald, M. Venkatesan, J. G. Lunney, L. S. Dorneles, J. M. D. Coey, Apl. surf. Sci., 247, 493 (2005).
31. T. N. Smironva, O. V. Sakhno, V. I. Benzrdnyj, J. Stumpe, Appl. Phys. B, 80, 947 (2005).
32. G. Moad and D. H. Solomon, “Comprehensive polymer science: The synthesis, characterization, reactions & Applications of polymers ”, Oxford , 97 (1989).
33. G. Pfundt and G. O. Scenck, “The Diels-Alder Reaction in Heterocyclic Synthesis”, Wiely, 345 (1967).
34. D. J. Gordon, R. F. Fenske, Inorg. Chem., 21, 2907 (1982).
35. P. J. Crowley, H. M. Haendler, Inorg. Chem., 1, 904 (1962).
36. R. M. Buchanan, J. Claflin, C. G. Pierpont, Inorg. Chem., 22, 2552 (1983).
37. J. R. Caille, A. Debuigne, R. Jerome, Macromolecules , 38, 27 (2005).
38. A. Debuigne, J. R. Caille, R. Jerome, J. Poly. Sci. Poly. Chem., 44, 1233 (2006).
39. J. Yuasa, T. Suenobu, S. Fukuzumi, ChemPhysChem, 7, 942 (2006).
40. L. Dhar, MRS bulletin, 31, 324 (2006).
41. Y. N. Hsiao, W. T. Whang, S. T. Lin, Opt. Eng., 43, 1993 (2004).
42. Y. N. Hsiao, W. T. Whang, S. T. Lin, Jap. J. Appl. Phys., 44, 914 (2005).
43. F. D. Monte , O. Martínez , J . A. Rodrigo , M. L. Calvo, P. Cheben, Adv. Mater., 18, 2014 (2006).
44. E. Kim, J. Park , C. Shin, N. Kim, Nanotech., 17, 2899 (2006).
45. C. H. Hung, W. T. Whang, J. Mater. Chem., 15, 267 (2005).
46. E. A. Meulenkamp, J. Phys. Chem. B., 102, 5566 (1998).
47. M. Tay, Y. Wu, G. C. Han, T. C. Chong, Y. K. Zheng, S. J. Wang, Y. Chen, X. Pan, J. Appl. Phys., 100, 63910 (2006).