(3.238.173.209) 您好!臺灣時間:2021/05/16 04:49
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果

詳目顯示:::

: 
twitterline
研究生:王尊
研究生(外文):Wang Tsun
論文名稱:全固態厚膜電池電極製備與特性之研究
論文名稱(外文):The Preparation and Characterization of electrodes in all solid state thick film battery
指導教授:吳溪煌
指導教授(外文):She-Huang Wu
學位類別:碩士
校院名稱:大同大學
系所名稱:材料工程學系(所)
學門:工程學門
學類:綜合工程學類
論文種類:學術論文
論文出版年:2008
畢業學年度:96
語文別:英文
論文頁數:106
中文關鍵詞:全固態鋰離子二次電池厚膜電池鋰鈦氧鋰猛鎳氧鋰離子二次電池
外文關鍵詞:LiMn1.5Ni0.5O4lithium-ion batteryLi4Ti5O12all solid state lithium-ion batterythick film battery
相關次數:
  • 被引用被引用:0
  • 點閱點閱:203
  • 評分評分:
  • 下載下載:57
  • 收藏至我的研究室書目清單書目收藏:0
全固態電池電極材料Li1.0+xNi0.5Mn1.5O4 及Li4Ti5O12 藉由靜電噴塗法製備,以不同熱處理溫度製備燒結,以感應耦合電漿原子發射光譜儀,X光繞射儀與掃描式電子顯微鏡鑑定極片之化學組成,結晶結構與表面型貌。以循環伏安與循環充放電檢測材料之電化學特性。目前成膜技術有 射頻磁控濺鍍法、氣相沈積法、脈衝雷射沈積法、電子束蒸鍍、靜電噴塗法、等等。靜電噴塗法是一種優異的成膜技術,它有快速及簡單的優點。正極材料Li1.05Ni0.5Mn1.5O4 以 750oC熱處理5小時製備,其最大可逆電容量128mAhg-1。另一正極材料Li1.03Ni0.5Mn1.5O4 以 650oC熱處理10小時製備,其最大可逆電容量135mAhg-1。負極材料Li4Ti5O12 以 600oC熱處理5小時製備,其最大可逆電容量131mAhg-1。
Li1.0+xNi0.5Mn1.5O4 and Li4Ti5O12 electrodes for solid-state batteries were prepared with a electrostatic spray deposition method followed by heat-treatment at various temperatures for various durations. The compositions, crystalline and morphology of the prepared electrodes were investigated with ICP, XRD, and SEM. The electrochemical properties of thus prepared electrodes were studied by capacity retention studies. This method shows superior to other film-form techniques, such as sputtering, vapor evaporation, e-beam evaporation, and pulse laser deposition for its high speed and simplicity. The cathode of Li1.05Ni0.5Mn1.5O4 prepared with 750oC at 5h shows a reversible capacity of 128 mAhg-1 at 1C rate, whereas Li1.03Ni0.5Mn1.5O4 heat-treated at 650oC for 10 h shows a reversible capacity of 135 mAhg-1 at 1C rate. The anode of Li4Ti5O12 heat-treated at 600oC for 5 h exhibits a reversible capacity ranging between 127 and 131 mAhg-1 as the coin-cell were cycled with rate of 1 C.
致謝 I
摘要 II
ABSTRACT III
CONTENTS IV
LIST OF TABLES VIII
LIST OF FIGURES IX

CHAPTER 2 LITERATURE REVIEW 4
2.1 The Principle of Li-ion Batteries 4
2.2Cathode Material for Lithium Batteries 5
2.2.1 The LiCoO2 Material 7
2.2.2 The LiNiO2 Material 7
2.2.3 The LiNi1/3Co1/3Mn1/3O2 Material 8
2.2.4 The LiFePO4 Material 9
2.2.5 The LiMn2O4 Material 10
2.2.6The LiNi0.5Mn1.5O4 Material 11
2.3 Anodes Material for Lithium Batteries 17
2.3.1 The carbon Material 19
2.3.2 The Silicon Material 20
2.3.3 The Lithium Alloys 21
2.3.4 The Li4Ti5O12 Material 22
2.4 The Solid-State Electrolytes for Lithium Batteries 27
2.4.1 The LiTi2(PO4)3 material 28
2.4.2 The LLTO material 30
2.4.3 The LiPON material 33
2.5 The all solid-state thick film battery 33
2.6 Electrochemical Methods 35
2.6.1 Cyclic voltammetry, CV 35
2.6.2 Capacity retention study 36

CHAPTER 3 EXPERIMENTAL 37
3.1 Preparation of Cathode and Anode 37
3.1.1 Preparation of the Stock Solution 37
3.1.2 Preparation of the Precursor Solution 37
3.1.3 Synthesis of the Cathode and Anode Electrodes 38
3.2 Character of the Prepared Materials 36
3.2.1 The XRD Study 36
3.2.2 Scanning Electron Microscope (SEM) Observation 40
3.3 Assembly of the Coin-Type Cells 41
3.4 Three-electrode cell assemblage 41
3.5 Electrochemical Analysis of the prepared Electrodes and Electrolyte 42
3.5.1 Capacity Retention Study 42
3.5.2 Cyclic voltammetry 42

CHAPTER 4 RESULTS AND DISCUSSION 44
4.1 Characterization of the Li1.0+xNi0.5Mn1.5O4 cathode prepared by ESD method 44
4.2 Morphology of Li1.05Ni0.5Mn1.5O4 electrodes 55
4.3 Electrochemical properties of Li1.0+xNi0.5Mn1.5O4 55
4.4 Characterization of the Li4Ti5O12 anode prepared by ESD method 69
4.4.1 Synthesis anode Li4Ti5O12 Film Electrode 69
4.4.2 XRD Li4Ti5O12 Film Electrode 69
4.4.3 Characterization of Li4Ti5O12 electrodes 72
4.2.4 Electrochemical properties of Li4Ti5O12 72

CHAPTER 5 CONCLUSION 78

CHAPTER 6 REFERENCES 79
[01] S.D. Jones, J.R. Akridge, J. Power Sources 54 (1994) 357.
[02] J.B. Bates, N.J. Dudney, D.C. Lubben, G.R. Gruzalski, B.S. Kwak, X. Yu, R.A. Zuhr, J. Power Sources 54 (1995) 58.
[03] Y.S. Park, S.H. Lee, B.I. Lee, S.K. Joo, Electrochem. Solid State Lett. 2 (1999) 58.
[04] N.J. Dudney, B.J. Neudecker, Curr. Opin. Solid-state Mater. Sci. 4 (1999) 479.
[05] J.B. Bates, N.J. Dudney, B.J. Neudecker, A. Ueda, C.D. Evans, Solid
State Ionics 135 (2000) 33.
[06] J.L. Souquet, M. Duclot, Solid State Ionics 148 (2002) 375.
[07] N.J. Dudney, Y.I. Jang, J. Power Sources 119–121 (2003) 300.
[08] T. J. Boyle, D. Ingersoll, R. T. Cygan, M. A. Rodriguez, K. Rahimian, J.A. Voight “All-Ceramic Thin Film Battery” SANDIA REPORT, Sandia National Laboratories.
[09]M. Winter, J.O.Besenhard, M.E.Spahr,P.Novak, Adv. Mater.10 (1998) 725.
[10]J.M.Tarascon,M.Armand,Nature 414 (2001) 359.
[11]H.W.Chan, j.g.Duh,S..R.Sheen,J.Power Souces 115 (2003) 110
[12]Won-Sub Yoon, Kyung-Yoon Chung, Ki-HwanOh, Kwang-Bum Kim,J.Power Sources 119-121 (2003) 706
[13]Fei Cao, Jai Prakash, Electrochemica Actab 47 (2002) 706
[14]Chuan Wu, Zhaoxiang Wang,Feng Wu, Liquan Chen, Xuejie Huang, Solid State Ionic 44 (2001) 277
[15]I.J.Davidson, R.S.Mcimllan, J.J Murray,J.E.Greedan,J. Power Sourecs 54 (1995) 232
[16]A.J.Paterson, A.D.Robertson,P.G.Bruce,Electrochem. And Solid-State Lett. 7 (2004) A331
[17]M.Wu, Q.Zhang,H. Lu,A.Chen.Solid State Lett. 7 (2004) A331
[18]F.Nobili, F.Croce,B.Scrosati, R.Marassi, Chem. Mater.13 (2001) 1642
[19]J.Ying, C.Wan, C.Jiang,Y.Li, J.Power Sources 99 (2001) 78
[20]P.Periasamy, H.S.Kim,S.H.Na,S.I.Moon, J.C.Lee, J,Power Sources 132(2004)213
[21]N.Yabuuchi, T. Ohzuku, J,Power Sources 119-121 (2003) 171
[22]I.Belharouak,Y.K.Sun, J.Liu,K.Amine, J,Power Sources 123 (2003) 247
[23] N.Yabuuchi, T. Ohzuku, J,Power Sources 146 (2005) 636
[24] T. Ohzuku, S-T, M-I, J. Power Sources 81-82 (1999) 90-94
[25] S.-H. Park, S.-W. Oh, S.-T. Myung, Y. C. Kang, Y.-K. Sun, Solid State Ionics 176 (2005) 481
[26] H.-S. Fang, Z.-X. Wang, X.-H. Li, H.-J. Guo, W.-I. Peng, J. Power Sources 153 (2006) 174.
[27]K.Padhi, K.S.Nanjundaswamy, J.B.Goodenough, J.Electrochem.Soc. 144 (1997) 1188
[28]J.M.Osrio-Guillen,B.Holm, R.Ahuja,B.Johansson. Solid State Ionic 167 (2004) 221
[29]S.J.Kwon,C.W.Jeong,K.S.Lee, J. Power Sources 137 (2004) 93.
[30]. T. Ohzuku, A. Ueda, N. Yamamoto, J. Electrochem. Soc. 142 (1995) 1431.
[31] T. Ohzuku, A. Ueda, Solid State Ionics 69 (1994) 201.
[32] C. Jiang, Y. Zhou, I. Honma,T. Kudo , H. Zhou, J. Power Sources 166 (2007) 514–518.
[33] L. Kavan and M. Grätzel, Electrochem. Solid-State Lett., 5, A39 2002.
[34] D.W. Murphy,Mat.Res.Bull, 13 (1978) 1395
[35] M.S.Whittingham,M.S. Whittinghamand,A.J.Jacobson,Edited, Academic Press,1 (1982)
[36]M.Armand,D.W. Murphy,J.Broadhead,B.C.H.Steels,Eds, Plenum Press,New York,145 (1980)
[37]Vandersport, H.Thomas,Taylor,D.Pual, U.S. Patenrs 4, 190, 620 (1980)
[38] T.Nagaura, K.Tazawa, Prog.Batteries Solar Cell 9 (1990) 20
[39] T. Ohzuku, Y. Makimura, Chem. Lett. (2001) 642.
[40]K. Kubo, M. Fujiwara, S. Yamada, S. Arai, M. Kanada, J. Power Sources 68 (1997) 553.
[41]Arai H., Tsuda M., Sakurai Y., J. Power Sources 90 (1) (2000) 76.
[42] K.M. Shaju, G.V. Subba Rao, B.V.R. Chowdari, Electrochem. Acta 48 (2002) 145.
[43]M.S. Islam, R.A. Davies, J.D. Gale, Chem. Mater. 15 (2003) 4280.
[44]B.J. Hwang, Y.W. Tasi, D. Carlier, G. Ceder, Chem. Mater. 15 (2003) 3676.
[45]J. Reed, G. Ceder, Electrochem. Solid State Lett. 5 (2002) A145.
[46]C.S. Johnson, J.S. Kim, A.J. Kropf, A.J. Kahaian, J.T. Vaughey, L.M.L. Fransson, K. Edström, M.M Thackeray, Chem. Mater. 15 (2003) 2313.
[47]Sébastien Patoux, Marca M. Doeff, Electrochem. Commun. 6 (2004) 767.
[48]J.M. Tarason, D. Guyomard, Electrochem. Acta 38 (1993) 1221
[49] N. Ravet, J.B. Goodenough, S. Besner, M. Simoneau, P. Hovington, M. Armand, in: Abstracts of the Electrochemical Society and the Electrochemical Society of Japan Meeting, vol. 99-2, Honolulu, HI, 17-22 October 1999 (Abstract 127).
[50]H. Huang, S. C. Yin, L.F. Nazar, Electrochem. Solid State Lett. 4 (2001) A170
[51]Z. Chen, J.R. Dahn, J. Electrochem. Soc. 149 (2002) A1184.
[52]F. Croce, A.D. Epifanio, J. Hassoun, A. Deptula, T. Olczac, B. Scrosati, Electrochem. Solid State Lett. 5 (2002) A47
[53]S.Y. Chung, J. Bloking, Y.M. Chiang, Nat. Mater. 1 (2002) 123.
[54]C. Delma, I. Saadoune, Solid State Ionics 53-56 (1992) 370.
[55] H.M. Wu, J.P. Tu, Y.F. Yuan, Y. Li, X.B. Zhao, G.S. Cao, Scripta Materialia 52 (2005) 513
[56] Chih-jung Yen, “The Formation of SEI between the LiMn2O4 cathode and electrolyte,” Master Thesis, Tatung University.
[57] T. Ohzuku, S-T, M-I, J. Power Sources 81-82 (1999) 90-94
[58]S.-H. Park, S.-W. Oh, S.-T. Myung, Y. C. Kang, Y.-K.Sun, Solid State Ionics 176 (2005) 481.
[59] H.-S. Fang, Z.-X. Wang, X.-H. Li, H.-J. Guo, W.-I. Peng, J. Power Sources 153 (2006) 174.
[60] M. Okada, Y.-S. Lee, M. Yoshio, J. Power Sources 90 (2000) 196.
[61] J. D. Vyas, K. L, Choy, Mater. Sci. Eng, A277 (2000) 206.
[62] B. Su, K. L, Choy, Thin Solid Films 361-362 (2000) 102.
[63] D.Aurbach, B.Markovsky, Y. Talyossef, G. S, H. J. K, S.C, J. Power Sources 162 (2007) 780-789
[64] A. Caballero , L. Hern´an , M. Melero , J. Morales , R. Morenob,. Ferrari J. Power Sources 158 (2006) 583–590
[65]3. Gao Y, Myrtle K, Zhang MJ, Reimers JN, Dahn JR (1996) Phys Rev B 54:16670
[66] Zhong Q, Bonakdarpour A, Zhang M, Gao Y, Dahn JR (1997) J Electrochem Soc 144 205
[67] Ohzuku T, Takeda S, IwanagaM (1999) J Power Sources 81–82:90
[68] S. Flandrois, B. Simon, Carbon 37 (1999) 165.
[69] M. Endo, C. Kim, K. Nishimura, T Fujino, K. Miyashita, Carbon 38 (2000) 183.
[70] H. Y. Lee, J. K. Baek, S. W. Jang, S. M. Lee, S. T. Hong, K. Y. Lee, M. H. Kim,J. Power Sources 101 (2001) 206.
[71] Y. G. Wang, Y. C. Chang, S. Ishida, Y. Korai, I. Mochida, Carbon 37 (1999) 969.
[72] Y. Korai, S.Ishid, S. H. Yoon, Y. G. Wang, I. Mochida, Y. Nakagawa, Y. Matsumura, Y. Sakai, M. Komatu, Carbon 34 (1996) 1569.
[73] S. S. Zhang, K. Xu, T. R. Jow, Electrochemistry Communications 5 (2003) 979.
[74] M. Gaberscek, M. Bele, J. Drofenik, R. Dominko, S. Pejovnik, J. Power Sources 97 (2001) 67.
[75] E. Ferg, R. J. Gummow, A. de Kock, and M. M. Thackeray, J. Electrochem. Soc., 141, (1994) L147 .
[76] P. Reale, S. Panero, B. Scrosati, J. Garche, M. Wohlfahrt-Mehrens, and M.Wachtler, J. Electrochem. Soc., 151, (2004) A2138
[77] h. P. Reale, S. Panero, and B. Scrosati, J. Electrochem. Soc., 152, (2005) A1949
[78] Panero, S, Satolli. D, Salamon. M, Scrosati. B, Electrochem. Commun. (2000) 2, 810.
[79] T. Ohzuku, A. Ueda, N. Yamamoto, J. Electrochem. Soc. 142 (1995) 1431.
[80]T. Ohzuku, A. Ueda, Solid State Ionics 69 (1994) 201
[81] Tsutomu Ohzuku , S. Takeda, M. Iwanaga J. Power Sources 81–82 1999.90–94
[82]T. Ohzuku, S. Kitano, M. Iwanaga, H. Matsuno, A. Ueda, J. Power Sources 68 (1997) 646.
[83] J. Jiang and J. R. Dahn J. Electrochemical Society, 153 (2) (2006) A310-A315
[84] J. Jiang, J.Chen, and J. R. Dahn, J. Electrochemical Society, 151 (12) (2004) A2082-A2087
[85]. I. Belharouak, W. Lu, J. Liu, and K. Amine J. Electrochemical Society, 154 (12) (2007) A1083-A1087
[86] H. Kim, R. C.Y. Auyeung, A. Piqu´e J. Power Sources 165 (2007) 413–419
[87] S.T. Lee, S.W. Jeon , B.-J. Yoo , S.-D. Choi ,H.-J. Kim, S.-M. Lee, J. Power Sources 155 (2006) 375–380
[88] M.-S. Park, S.-H. Hyun, S.-C. Nam Electrochimica Acta 52 (2007) 7895–7902
[89] N.J. Dudney, Y.I. Jang, J. Power Sources 119–121 (2003) 300.
[90] J.F. Whitacre, W.C. West, B.V. Ratnakumar, J. Power Sources 103 (2001) 134
[91] J.B. Bates, N.J. Dudney, B.J. Neudecker, F.X. Hart, H.P. Jun, S.A. Hackney, J. Electrochem. Soc. 147 (2000) 59
[92] C.-L. Liao, K.-Z. Fung, J. Power Sources 128 (2004) 263.
[93]. J. Pracharova, J. Pridal, J. Bludska, I. Jakubec, V. Vorlicek, Th.Dikonimos Makris, R. Giorgi, L. Jastrabik, J. Power Sources 108 (2002) 204.
[94] M.K. Kim, H.T. Chung, Y.J. Park, J.G. Kim, J.T. Son, K.S. Park,H.G. Kim, J. Power Sources 99 (2001) 34.
[95] Y.H. Rho, K. Kanamura, M. Fujisaki, J. Hamagami, S. Suda, T.
Umegaki, Solid State Ionics 151 (2002) 151.
[96] Y. Iriyama, M. Inaba, T. Abe, Z. Ogumi, J. Power Sources 94 (2001) 175.
[97] C. Jiang, Y. Zhou, I. Honma,T. Kudo , H. Zhou, J. Power Sources 166 (2007) 514–518.
[98] L. Kavan and M. Grätzel, Electrochem. Solid-State Lett., 5, A39 2002.
[99] J. Barker, R. K. B. Gover, P. Burns, and A. J. Bryan J. Electrochemical Society, 154 (9) (2007)A882-A887
[100]Y. Yu, J.L. Shui, C.H. Chen Solid State Communications 135 (2005) 485–489
[101] K. Kanamura, K. Yuasa, J. Power Sources 20 (1993) 127.
[102] X.Yu,J.B.Bates, G.E.Jellison,Jr. J. Electrochemical Society, 144 (2) (1997)524-533
[103] N.-S. Roh, S.-D. Lee and H.-S. Kwon Scripta mater. 42 (2000) 43–49
[104] D. Mazza, S. Ronchetti, O. Bohnke, H. Duroy , J.L. Fourquet Solid State Ionics 149 (2002) 81– 88
[105] T. Brousse, D. Defives, L. Pasquereau, S.M. Lee, U. Herterich and D.M. Schleich Ionics 3 (1997) 332
[106] M. Wilkening,* R. Amade, W. Iwaniak and P.l Heitjans Phys. Chem. Chem. Phys. 9 ( 2007) 1239–1246
[107] S. Wong, .J. Newman,A. S. Best, K. M. Nairn,a D. R. MacFarlaneb and Maria Forsyth* J. Mater. Chem. 8(10) (1998) 2199–2203
[108] Hagman L O, Kierkegaard P. Acta Chem. Scand., 1968, 22:1822-1831
[109] Jia-Yan Luo and Yong-Yao Xia*Adv. Funct. Mater.17 ( 2007) 3877–3884
[110] M. Vallino, D. Mazza, Proceedings of the first National Meetingon Engineering Materials ASMI, Milano, Italy, 1983, pp.387–394.
[111] A.D. Robertson, S. Garcia Martin, A. Coats, A.R. West, J.Mater. Chem. 5 (1995) 1405.
[112] J.L. Fourquet, H. Duroy, M.P. Crosnier-Lopez, Structural and J. Solid State Chem. 127 (1996) 283– 294
[113] D. Mazza a,*, S. Ronchetti a, O. Bohnke´ b, H. Duroy b, J.L. FourquetSolid State Ionics 149 (2002) 81– 88
[114] Y. Inaguma, L. Chen, M. Itoh, T. Nakamura, T. Uchida, M. Ikuta, and M.Wakihara, Solid State Commun. 86, 689 (1993).
[115] 15Y. Inaguma, L. Chen, M. Itoh, and T. Nakamura, Solid State Ionics70&71 (1994) 196
[116] S. Stramare,† V. Thangadurai,* and W. Weppner Chem. Mater. 15 (2003) 3974-3990
[117] Z. S. Wen, J. Yang, B. F. Wang, K. Wang, Y. Liu, Electrochemistry Communications 5 (2003) 165.
[118] H. Y. Lee, S.M. Lee, Electrochemistry Communications 6 (2004) 465.
[119] Tamura N, Ohshita R, Yonezu I, et al. .J Power Sources, 2002, 107 (1)
[120] J. B. Bates, N. J. Dudney, G. R. Gruzalski, R. A. Zuhr, A. Choudhury, C. F. Luck, and J. D. Robertson, Solid State Ionics. 647 (1992) 53–56,.
[121] K. Ariyoshi, R. Yamato, T. Ohzuku, Electrochimica Acta 51 (2005) 1125–1129
[122] M. Kunduraciz and G. G. Amatucci Journal of The Electrochemical Society, 153 (7) A1345-A1352 (2006)
[123] S. T. Myung, S. Komaba, N. Kumagai, H. Yashiro, H. T. Chung, and T. H. Cho Electrochim. Acta, 47, 2543 (2002)
[124] J. Arrebola, A. Caballero, L. Hernán, J. Morales, E. Rodríguez Castellón,and J. R. Ramos Barradoc, Journal of The Electrochemical Society, 154 (3)A178-A184 2007
[125] J.-H. Kim,a S.-T. Myung,b,* C. S. Yoon,c I.-H. Oh,d and Y.-K. Sun Journal of The Electrochemical Society, 151 (11) A1911-A1918 (2004)
[126] A. Deschanvres, B. Raveau, and Z. Sekkal, Mater. Res.Bull. 6, 699 (1971).
[127] L. Cheng, X.L. Li, H.J. Liu, H.M. Xiong, P.W. Zhang, Y.Y. Xia, Journal of The Electrochemical Society, 154 (7) A692-A697 (2007)
[128] S. Huang, Z. Wen, J. Zhang , X. Yang Electrochimica Acta 52 (2007) 3704–3708
[129] J. Kim, J. Cho, Electrochemical and Solid-State Letters, 10 (3) A81-A84 (2007)
[130] C. Jiang , Y. Zhou, I. Honma, T. Kudo, H. Zhou, Journal of Power Sources 166 (2007) 514–518
QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top