(3.235.245.219) 您好!臺灣時間:2021/05/10 01:25
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果

詳目顯示:::

我願授權國圖
: 
twitterline
研究生:鄭健志
研究生(外文):Jian-Jr Cheng
論文名稱:含羧酸基和N,N'-二-(4-吡啶)己二醯二胺配位基與d10金屬化合物之合成,結構與特性研究
論文名稱(外文):Synthesis, Structures and Properties of d10 Metal Complexes Containing Anion of Carboxylic acid and N,N'-di(4-pyridyl)adipoamide
指導教授:陳志德
指導教授(外文):Jhy-Der Chen
學位類別:碩士
校院名稱:中原大學
系所名稱:化學研究所
學門:自然科學學門
學類:化學學類
論文種類:學術論文
論文出版年:2009
畢業學年度:97
語文別:中文
論文頁數:58
中文關鍵詞:N N'-二-(4-吡啶)己二醯二胺配位基
外文關鍵詞:N N'-di(4-pyridyl)adipoamide
相關次數:
  • 被引用被引用:0
  • 點閱點閱:48
  • 評分評分:系統版面圖檔系統版面圖檔系統版面圖檔系統版面圖檔系統版面圖檔
  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
中文摘要
本論文主要探討含N,N'-二-(4-吡啶)己二醯二胺配位基(H2dpya)及含雙羧酸基苯甲酸(1,4-BDC)與過渡金屬二價鋅與二價鎘之化學。利用了水熱法合成出[Zn(1,4-BDC)(H2dpya)] •(H2O),1和[Cd(1,4-BDC)(H2dpya)] •2(H2O) ,2,以上兩種化合物均利用元素分析儀鑑定、紅外光光譜儀、熱重分析儀和螢光光譜儀分析特性,而單晶結構均以單晶 X-ray 繞射儀鑑定。
在化合物1與化合物2中,藉由配位基N,N'-二-(4-吡啶)己二醯二胺與對苯二甲酸的橋接,形成了三維扭曲的鑽石型結構,化合物1為[4+4]的貫穿模式,化合物2為9層相互貫穿模式,配位基H2dpya在化合物1中為AGA-cis的構型;在化合物2中為AAA-trans的構型,表現出配位基H2dpya具有良好的柔軟性質。
Abstract
This thesis discusses the chemistry of znic(II) and cadmium(II) complexes containing N,N'-di(4-pyridyl)adipoamide (H2dpya) and 1,4-benzenedicarboxylate (1,4-BDC). Two new coordination polymers, [Zn(1,4-BDC)(H2dpya)] •(H2O) (1) and [Cd(1,4-BDC)(H2dpya)] •2(H2O) (2), have been synthesized by hydrothermal reactions. All the complexes have been characterized by EA, IR, TGA and PL spectroscopic methods and structurally characterized by X-ray crystallography.
Complex 1 and complex 2 form the distorted diamondoid net supported by N,N'-di(4-pyridyl)adipoamide and 1,4-benzenedicarboxylate. Complex 1 is a [4+4] mode of interpenetration and complex 2 is a 9-fold interpenetrating mode. The H2dpya ligands in complex 1 adopts the AGA-cis conformation while in complex 2 the AAA-trans onformation.
目錄
中文摘要.............................................................................I
Abstract...............................................................................II
謝誌..................................................................................III
目錄..........................................................................................................IV
表目錄......................................................................................................VI
附錄表目錄……………………………………………………………..VI
圖目錄.....................................................................................................VII
第一章 總論
1-1 序論..............................................................................................1
1-2 配位基介紹..................................................................................5
1-3 研究動機......................................................................................8
第二章 實驗
2-1 實驗藥品.....................................................................................9
2-2 合成化合物……………………………………………………10
2-3 單晶繞射X-ray與晶體解析......................................................12
第三章 化合物結構討論與性質測試
3-1 化合物結構................................................................................15
3-2 TGA熱性質分析.........................................................................22
3-3 放光性質測試………………………………...……………….24
3-4 氣體吸脫附測試………………………………………………26
第四章 結論……………………………………………………………29
參考文獻………………………………………………………………..30
附錄..........................................................................................................34

表目錄
表 1 化合物1晶體資料..........................................................................13
表 2 化合物2晶體資料..........................................................................14
表 4 配位基與化合物1化合物2激發與放光波段................................24
附錄表目錄
Table 1. Atomic coordinates ( x 104) and equivalent isotropic isplacement
parameters (A2 x 103) for [Zn(1,4-BDC)(H2dpya)] •(H2O).…...35
Table 2. Bond lengths [Å] for [Zn(1,4-BDC)(H2dpya)] •(H2O)………...37
Table 3. Bond angles [°] for [Zn(1,4-BDC)(H2dpya)] •(H2O)…………..39
Table 4. Hydrogen coordinates ( x 104) and isotropic displacement
parameters (A2 x 103) for [Zn(1,4-BDC)(H2dpya)] •(H2O) .…..41
Table 5. Atomic coordinates ( x 104) and equivalent isotropic isplacement
parameters (A2 x 103) for [Cd(1,4-BDC)(H2dpya)] •2(H2O)......42
Table 6. Bond lengths [Å] for [Cd(1,4-BDC)(H2dpya)] •2(H2O).............44
Table 7. Bond angles [°] for [Cd(1,4-BDC)(H2dpya)] •2(H2O)………...46
Table 8. Anisotropic displacement parameters (A2 x 103) for [Cd(1,4-BDC)(H2dpya)] •2(H2O) ...…………………………...48
Table 9. Hydrogen coordinates ( x 104) and isotropic displacement
parameters (A2 x 103) for [Cd(1,4-BDC)(H2dpya)] •2(H2O)…..50

圖目錄
圖 1 配位化合物自我組裝示意圖..........................................................2
圖 2 配位基分類:(A)無機配位基;(B)中性配位基
(C)陰離子型位基;(D)陽離子型配位基.......................................3
圖 3 配位高分子的結構示意圖..............................................................4
圖 4 具有雙吡啶環的架橋配位基……………………………………..5
圖 6 雙吡啶環配位基所合成多樣化的結構..........................................7
圖 7 (a) 化合物1非對稱單元結構圖 (b) 化合物1中心金屬構型…..15
圖 8 化合物1藉由配位基橋接形成扭曲鑽石型結構………………..17
圖 9 (a) 化合物1單層4個結構相互貫穿 (b) 化合物1形成[4+4]相互
貫穿結構…………………………………………………………17
圖 10 化合物2非對稱單元結構圖……………………………………18
圖 11 化合物2藉由配位基橋接形成扭曲鑽石型結構………………19
圖 12 化合物2形成9層相互貫穿結構………………………………..19
圖 13 化合物1與化合物2所形成的空間大小示意圖..........................20
圖 14 化合物1熱重損失圖……………………………………………22
圖 15 化合物2熱重損失圖....................................................................23
圖 16 配位基與化合物的放光光譜…………………………………..25
圖 17 (a) 化合物2氮氣吸脫附圖 (b) 化合物2氫氣吸脫附圖……...27
圖 18 化合物2氫氣吸脫附圖................................................................28
參考文獻
[1]Kitagawa, S., Kitaura, R., Noro, S.-I. Angew. Chem. Int. Ed. 2004, 43, 2334.
[2](a) Bailar Jr., J. C., Prep. React. 1964, 1, 1. (b) Janiak, C. J. Chem. Soc., Dalton Trans. 2003, 2781.
[3](a) Nangia, A. CrystEngComm. 2002, 4, 93. (b) Aullon, G., Bellamy, D., Orpen, A. G. Brammer, E., Bruton, E. A. Chem. Comm. 1998, 653. (c) Desiraju, G. R. Acc. Chem. Res. 1996, 29, 441.
[4]Janiak, C. J. Chem. Soc., Dalton Trans. 2000, 3885.
[5](a) Blake, A. J., Champness, N. R., Hubberstey, P., Li, W.-S., Withersby, M. A., Schroder, M. Coord. Chem. Rev. 1999, 183, 117. (b) Barnett, S. A., champness, N. R. Coord. Chem.. Rev. 2003, 246, 145.
[6](a) Holman, K. T., Hammud, H. H., Isber, S., Tabbal, M. Polyhedron 2005, 24, 221. (b) Choi, H. J., Suh, M. P. Inorg. Chem. 1999, 38, 6309. (c) Robin, A. Y., Fromm, K. M., Goesmann, H., Bernardinelli, G. CrystEngComm. 2003, 5, 405. (d) De Munno, G., Armentano, D., Poerio, T., Julve, M., Real, J. A. J. Chem. Soc., Dalton Trans. 1999, 1813. (e) Yong, G.-P., Wang, Z.-Y., Cui, Y. Eur. J. Inorg. Chem. 2004, 21, 4317.
[7](a) Manson, J. L., Lancaster, T., Chapon, L. C., Blundell, S. J., Schlueter, J. A., Brooks, M. L., Pratt, F. L., Nygren, C. L., Qualls, J. S. Inorg. Chem. 2005, 44, 989. (b) Zaman, M. B., Smith, M. D., Ciurtin, D. M., Zur Loye, H.-C. Inorg. Chem. 2005, 41, 4895. (c) Zhu, H., Huang, C., Huang, W., Gou, S. Inorg. Chem. Comm. 2004, 7, 1095. (d) Wang, R., Han, L., Xu, L., Gong, Y., Zhou, Y., Hong, M., Chan, A. S. C. Eur. J. Inorg. Chem. 2004, 3751.
[8]Horikoshi, R., Mikuriya, M. Cryst. Growth Des. 2005, 5, 223.
[9](a) Cheng, J.-Y., Dong, Y.-B., Huang, R.-Q., Smith, M.D. Inorg. Chim. Acta 2005, 358, 891. (b) Hong, M., Su, W., Cao, R., Fujita, M., Lu, J. Chem. Eur. J. 2000, 6, 427.
[10]Well, B. M., Landee, C. P., Turnbull, M. M., Awwadi, F. F., Twamley, B. J. Mol. Catal. A. 2005, 228, 117.
[11]Gao, E.-Q., Xu, Y.-X., Yan, C.-H. CrystEngComm. 2004, 6, 298.
[12](a) Xie, Y.-R., Zhao, H., Wang, X.-S., Qu, Z.-R., Xiong, R.-G., Xue, X., You, X.-Z. Eur. J. Inorg. Chem. 2003, 20, 3712. (b) Uemura, K., Kitagawa, S., Fukui, K., Saito, K. J. Am. Chem. Soc. 2004, 126, 3817. (c) Spichal, Z., Necas, M., Pinkas, J., Novosad, J. Inorg. Chem. 2004, 43, 2776. (d) Ouyang, X.-M., Fei, B.-L., Okamura,, T.-A., Bu, H.-W., Sun, W.-Y., Tang, W.-X., Ueyama, N. Eur. J. Inorg. Chem. 2003, 618.
[13](a) Chen, Z.-F., Xiong, R.-G., Abrahams, B. F., You, X.-Z., Che, C.-M. J. Chem. Soc., Dalton Trans. 2001, 2453. (b) Lin, W., Ma, L., Evans, O. R. Chem. Comm. 2000, 2263. (c) Du, M., Bu, X.-H., Guo, Y.-M., Liu, H., Batten, S. R., Ribas, J. Mak, T. C. W. Inorg. Chem. 2002, 41, 4904. (d) Carlucci, L., Giani, G., Proserpio, D. M., Rizzato, S. Chem. Eur. J. 2002, 8, 1519.
[14](a) Tao, J., Tong, M.-L., Chen, X.-M. J. Chem. Soc., Dalton Trans. 2000, 3669. (b) Eddaoudi, M., Kim, j., Rosi, N., Vodak, D., Wachter, J. O’Keeffe, M., Yaghi, O. M. Science 2002, 295, 469. (c) Noro, S.-I., Kitagawa, S., Kondo, M., Seki, k. Angew. Chem. Int. Ed. 2000, 39, 2082.
[15]Chen, H.-C., Hu, H.-L., Chan, Z.-K., Yeh, C.-W., Jia, H.-W., Wu, C.-P., Chen, J.-D., Wang, J.-C. Cryst. Growth Des. 2007, 7, 698.
[16]Hsu, Y.-F., Lin, C.-H., Chen, J.-D., Wang J.-C. Cryst. Growth Des. 2008, 8, 1094.
[17]Carlucci, L., Ciani, G., Proserpio, D. M., Rizzsto, S. Chem. Eur. J. 2002, 8, 1520.
[18](a) Du, Z.-Y., Li, X.-L., Liu, Q.-Y., Mao, J.-G. Cryst. Growth Des. 2007, 7, 1501. (b) Tian, Z., Lin, J., Su Y., Wen, L., Liu, Y., Zhu, H., Meng, Q.-J. Cryst. Growth Des. 2007, 7, 1863. (c) Qi, Y., Luo, F., Che, Y., Zheng, J. Cryst. Growth Des. 2008, 8, 606. (d) Schsste, A., Klingelhöfer, s., Behrens, P., Wiebcke, M. Cryst. Growth Des. 2008, 8, 3200.
[19]Rabenau, A. Angew. Chem. Int. Ed. 1985, 24, 1026.
[20]SMART/ASINT/ASTRO, Release 4.03, Siemens Energy & Automation, Inc., Madison, Wisconsin, USA, 1995.
[21]SHELXTL 5.10. Bruker Analytical X-ray Instruments Inc., Karlsruhe, Germany, 1997.
[22]V. Blatov, A IUCr CompComm Newsletter. 2006, 7, 4. http://www.topos.ssu.samara.ru
[23]Baburin, I. A., Blatov, V.A., Carlucci, L., Ciani, G., Proserpio, D. M. J. Solid State Chem. 2005, 178, 2452.
[24]Lee, H. Y., Park, J., Lah, M. S., Hong, J.-I. Cryst. Growth Des. 2008, 8, 587.
[25]Wang, G.-H., Li, Z.-G., Jia, H.-Q., Hu, N.-H., Xu, J.-W. Cryst. Growth Des. 2008, 8, 1932.
[26]Qi, Y., Che, Y.-X., Zheng, J.-M. Cryst. Growth Des. 2008, 8, 3602.
[27]Qi, Y., Che, Y., Luo, F., Batten, S. R., Liu, Y., Zheng, J. Cryst. Growth Des. 2008, 8, 1654.
[28]Liang, X.-Q., Zhou, X.-H, Chen, C., Xiao, H.-P., Li, Y.-Z., Zuo, J.-L., You, X.-Z. Cryst. Growth Des. 2009, 9, 1041.
[29]Chen, J.-Q., Cai, Y.-P., Fang, H.-C., Zhou, Z.-Y., Zhan, X.-L., Zhao, G., Zhang, Z. Cryst. Growth Des. 2009, 9, 1650.
QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top
系統版面圖檔 系統版面圖檔