臺灣博碩士論文加值系統

本研究採用一套靜態式液相循環的相平衡裝置，量測甲醇 ＋ 棕櫚酸甲酯、甲醇 ＋ 油酸甲酯，以及甲醇 ＋ 亞麻油酸甲酯三組雙成分混合物溫度範圍為353.15 K ∼ 403.15 K之汽液平衡數據，實驗結果顯示每組雙成分系統皆無共沸物產生，且均是正偏差。純質成分之飽和蒸氣壓數據用Antoine方程式迴歸，其平均絕對誤差皆在1 ％內。所量取的雙成分汽液平衡數據均使用NRTL-HOC、UNIQUAC -HOC與Wilson-HOC模式關聯。
此外也跟長春公司進行產學合作的研究，兩組混合物的相平衡行為及四種物質的蒸汽壓的量測，由於有保密的協定，所以不被放入本篇論文。

A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of methanol + methyl palmitate , methanol + methyl oleate, and methanol + methyl linoleate at temperatures from 353.15 K to 403.15 K. The experimental results showed no azeotrope formation and positive deviation from ideality in each binary system. The Antoine equation fitted the vapor pressure data of pure substances to within an average absolute percentage deviations of 1 %. Binary VLE data were correlated with the NRTL-HOC, the UNIQUAC-HOC, and the Wilson-HOC models, respectively.

第一章 緒論
第二章 汽液相平衡量測
第三章 相平衡研究之模式關聯
第四章 結論與建議

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