臺灣博碩士論文加值系統

本研究主要結合奈米材料Fe-Ni雙金屬的氧化分解能力及奈米碳管的吸附能力，發展新的奈米複合材料Fe-Ni/CNT，以處理日趨複雜的水污染。
本研究首先將多壁奈米碳管以化學氧化法做純化改質處理能使其純度較純化改質前提高5 wt％、比表面積提高1.89倍、表面電位下降約10~20 mV以及表面官能基(－COOH及－OH)提高1.45倍，再控制無電鍍技術之製備參數包括：析鍍時間、析鍍溫度，鍍液中金屬離子比(Fe2+/Ni2+)、鍍液pH值及是否添加分散劑(SDS)等，研究朝提高Fe-Ni粒子的含鐵量與Fe-Ni粒子散佈固定在MWCNT上等目標進行，研究結果發現當製備參數為50 ℃、pH10、不添加分散劑、鍍液金屬離子比(Fe2+/Ni2+)7時，可得到最高鐵含量Fe = 40.55 at％(單位鐵含量111.17 mg/g)之奈米複合材料Fe-Ni/CNT，接著對其作一系列性質分析，最後評估奈米複合材料Fe-Ni/CNT對共處理混合汙染物之應用效益，結果顯示其在120分鐘時能夠同時吸附重金屬硝酸鉛離子10 ppm、重金屬硒酸根離子1 ppm及降解偶氮橘色染料AO7 50 ppm達放流水標準，且共處理後奈米Fe-Ni粒子以SEM/EDS分析仍剩餘50 %以上。

The purpose of this study combined with nanoparticles Fe-Ni bi-metallic oxidation capacity and the adsorption capacity of carbon nanotubes, the development of new nanocomposites Fe-Ni/CNT, to deal with the increasing complexity of water pollution.
First of all, this study will be multi-walled carbon nanotubes by chemical oxidation process purified so it can be modified to deal with than the purification of purity before the modified 5 wt%, more than 1.89 times the surface area to increase the surface potential decrease of about 10 ~ 20 mV and the surface functional base (-COOH and-OH) to increase 1.45 times, and then the control technology of electroless preparation parameters include: analysis of plating time, plating analysis of temperature, metal ions in solution than the (Fe2+ / Ni2+), bath pH and the added value of dispersion Agent (SDS) and other research towards Fe-Ni particles to increase the iron content and Fe-Ni particles spread in the MWCNT upper fixed targets,the results found that when the parameters for the preparation of 50 ℃, pH10, do not add dispersant, metal ions than the solution (Fe2 + / Ni2 +) 7, the highest iron content can be Fe = 40.55 at% (flat iron content 111.17 mg / g) of nanocomposites Fe-Ni/CNT, then for a series of the nature of its analysis, the final evaluation Fe-Ni/CNT nanocomposites were processed on the effectiveness of the application of mixed pollutants, the results showed that in 120 minutes at the same time when Adsorption of heavy metal ions lead nitrate 10 ppm, selenium heavy metal ion degradation of 1 ppm and orange azo dye AO7 50 ppm standard of effluents, and after a total Fe-Ni nano-particles to SEM / EDS analysis of more than 50% still remaining.

摘要 I
致謝 III
目錄 IV
圖目錄 VIII
表目錄 XI
第一章 緒論 1
1.1研究緣起與動機 1
1.2 研究目的 2
1.3研究架構 4
第二章 文獻回顧 5
2-1 無電鍍技術 5
2-1-1 無電鍍配方 5
2-1-2 無電鍍過程 6
2-1-3 無電鍍反應機構 7
2-2 奈米粒子製造方法及特性 9
2-2-1 奈米粒子常見之合成方法 9
2-2-2 奈米複合粉體的結構特性 9
2-2-3 無電鍍技術製備奈米粒子之研究 10
2-2-4 奈米碳管上沉積奈米粒子之研究 14
2-3 奈米碳管之特性與應用 16
2-3-1 奈米碳管之合成 16
2-3-2 奈米碳管之性質與結構 17
2-3-3 奈米碳管前處理之研究 20
2-3-4 奈米碳管之應用 23
2-4 奈米碳管去除重金屬及有機物之研究 25
2-4-1 奈米碳管吸附重金屬之研究 25
2-4-2 奈米碳管去除有機汙染物之研究 29
2-5 水體汙染物 32
2-5-1含鉛汙染危害性及去除方法 32
2-5-2含硒汙染危害性及去除方法 33
2-5-3偶氮染料之危害性及去除方法 34
第三章 實驗方法 36
3-1 實驗材料和藥品 36
3-2 實驗儀器設備 38
3-3實驗流程概述 40
3-4製備奈米複合材料Fe-Ni/CNT 41
3-5 TEM試片製作 44
3-6多壁奈米碳管性質分析儀器 45
3-6-1 掃描式電子顯微鏡分析(SEM/FE-SEM) 45
3-6-2 穿透式電子顯微鏡(TEM) 46
3-6-3 比表面積分析儀(BET) 47
3-6-4 熱重量分析儀（TGA） 47
3-6-5 傅立葉轉換紅外線光譜(FTIR) 48
3-6-6 反滴定法（Boehm`s titration method） 49
3-6-7 表面界達電位測定(Zeta Pontential) 49
3-6-8 拉曼磷光共軛雷射顯微光度計（Raman） 50
3-7複合奈米材料Fe-Ni/CNT性質分析儀器 51
3-7-1 化學成分鑑定(ICP-OES) 51
3-7-2 晶相測定 (XRD) 52
3-7-3分光光度計分析儀 53
3-8環境應用效益分析 53
3-9樣品分析之QA/QC 54
3-9-1 分光光度計分析 54
3-9-2 ICP重金屬離子分析 55
3-9-3 pH量測分析 55
第四章 結果與討論 56
4-1 奈米碳管改質前後特性分析 56
4-1-1 表面微觀結構分析 56
4-1-2 純度分析 58
4-1-3 拉曼繞射基分析 60
4-1-4 表面官能基分析 61
4-1-5 酸鹼反滴錠法分析 63
4-1-6 比表面積分析 63
4-1-7 界達電位分析 64
4-2 製備奈米複合材料Fe-Ni/CNT 65
4-2-1 製備參數對Fe-Ni/CNT之影響 65
4-2-2奈米Fe-Ni/CNT物性分析 76
4-3 環境應用測試 84
4-3-1 共處理混合汙染物(偶氮染料AO7及重金屬Pb2+、HSeO3-)測試 84
4-3-2 Fe-Ni/CNTs共處理水中汙染物後穩定性評估 89
4-4 綜合討論 93
第五章 結論與建議 94
參考文獻 96
附錄 109

中文文獻：

謝淑惠， 洪肇嘉，“Using Fe-Ni nanoparticles deposited on aluminum oxides to decompose chlorinated solvent compounds”，2005 第二屆環境保護與奈米科技學術研討會論文，清華大學，P264-271。

謝淑惠，洪肇嘉，“Fe/Ni複合奈米金屬粒子分解氯仿的反應研究” ，2003，第一屆國際環境災害及緊急應變技術研討會論文。

蔡正國、洪肇嘉、謝淑惠，“奈米碳管/氧化鋁(CNTs/Al2O3)吸附鉛及其他重金屬之效果探討” 第一屆環境保護與奈米科技學術研討會論文P11-16，2004，交通大學。

蔣挺大編箸，2007，“壳聚糖” 化學工業出版社。

蔡正國，洪肇嘉，「複合奈米碳管吸附水溶重金屬污染物之應用研究」，2004，國立雲林科技大學環境與安全衛生工程系碩士班碩士論文。

鍾耀磊、張冠甫、盧重興，2004，「奈米碳管吸附自來水中三鹵甲烷
之研究」，第一屆環境保護與奈米科技學術研討會。

施純榮，1997，1997年特用化學品年度報告，工業技術研究院。

莊宴惠，2008，奈米碳管表面改質與複合材料合成之電性和導熱性量測，國立成功大學化學工程研究所，碩士論文。

石立節，2005，奈米碳管酸純化前後表面特性之變化，國立中央大學環境工程研所，碩士論文。

周貝倫，2006，純化程序對奈米碳管表面特性影響之研究，國立中央大學環境工程研所，碩士論文。

徐 以 玲，2007，水中銅、鎘重金屬離子於奈米碳管上之吸附研究，國立雲林科技大學，碩士論文。

邱煥宗，2005，米碳管吸附水中二價鋅離子之研究，中興大學環境工程學系，碩士論文。

王森林，劉俊杰，2008，化學鍍鎳-鈷-鐵-磷鍍層的結構和磁性能，中國有色金屬學報，第18卷，第6期。

詹雅婷，王明光，2007，“以二元氧化物系統移除硒酸鹽與亞硒酸鹽”，國立台灣大學農業化學研究所，碩士論文。

董瑞安，張淑閔，2008，綠色奈米技術之開發及應用（功能性一維奈米複合材料對水體環境污染物之共處理與環境流佈宿命研究），行政院環境保護署科技顧問室。




英文文獻：
Asefa, T.; Lennox, R. B. 2005, “Synthesis of gold nanoparticles via electroless deposition in SBA-15”, Chemistry of Materials, Vol. 17(10), 2481-2483

Avetik R. Harutyunyan, Bhabendra K. Pradhan, Jiping Chang, Gugang
Chen, and Peter C. Eklund, 2002, ”Purification of single-walled carbon nanotubes by selective microwave heating of catalyst particles,” , Vol. 106, 8671-8675.

Borse, P. H.; Yi, J. M.; Je, J. H.; Choi, S. D.; Hwu, Y.; Ruterana, P.; Nouet, G., 2004, “Formation of magnetic Ni nanoparticles in X-ray irradiated electroless solution”, Nanotechnology, Vol. 15(6), S389-S392.

Brown, P. A.; Gill, S. A.; Allen, S. J.,（2000） “Metal removal from wastewater using peat”, Water Research, Vol. 34(16), 3907.

Collins, P. G., Arnold, M. S. and Avouris, P. (2001) “Engineering carbonnanotubes and nanotube circuits using electrical breakdown” Science. Vol. 292 , 706

Díaz E.; Ordóñez S. ; Vega A.; 2007, “ Adsorption of volatile organic compounds onto carbon nanotubes, carbon nanobers, and high-surface-area graphites”, Journal of Colloid and Interface Science, Vol. 305, 7–16

Dresselhaus. M.S, Dresselhans. G, Saito. R, Physics of carbon
nanotubes. Carbon, 33, 883-891(1995).

Dujardin, E., Meny, C., Panissod, P., Kintzinger, J. P., Yao, N. and Ebbesen, T.W. (2000) “Interstitial metallic residues in purified single shell carbon nanotubes” Solid State Communications, Vol. 114, 543-546.

Davis, W. M., Erickson, C. L. and Johnston, C. T. (1999) “Quantitative Fourier Transform Infrared Spectroscopic Investigation of Humic Substance Functional Group composition” Chemospher, Vol. 38, 2913-2928.

Elliott, D. W.; Zhang, W. X., 2001, “Field assessment of nanoscale bimetallic particles for groundwater treatment”, Environ. Sci. Technol., Vol. 35, 4922-4926.

Ebbesen, T. W. and Takada, T. (1995) “Topological and sp3 defect structures in nonotubes” Carbon Vol. 33, 973-978

F.Z. Kong, X.B. Zhang, W.Q. Xiong, F. Liu, W.Z. Huang, Y.L. Sun, J.P. Tu, X.W. Chen, 2002, “Continuous Ni-layer on multiwall carbon nanotubes by an electroless plating method”, Surface and Coatings Technology, Vol. 155, 33–36.

Furukawa, Y. J.; Kim, W. ; Watkins, J.; Wilkin, R. T., 2002, “Formation of Ferrihydrite and Associated Iron Corrosion Products in Permeable Reactive Barriers of Zero-Valent Iron”, Environ. Sci. Technol., Vol. 36, 5469-5475.

Gui-Mei Shia,b, Jae-Kil Hana, Zhi-Dong Zhangb, Ho-Yeon Songc, Byong-Taek Leea，2005 “Pretreatment effect on the synthesis of Ag-coated Al2O3 powders by electroless deposition process” VoL 195 (2005) 333– 337

Guo, Z.; Kumar, Challa S. S. R.; Henry, L. L.; Hormes, J.; Podlaha, E.J., “Electroless method to fabricate core-shell nanoparticles”, 2004, Meeting Abstracts-205th meeting of the The Electrochemical society, MA 2004 01 P23.

Grujicic, M. (2002) “An Atomic-scale Analysis of Catalytically-assisted
Chemical Vapor Deposition of Carbon Nanotubes.”, Materials
Science and Engineering, B94, 247-259.

Gómez de Salazar, J. M.; Barrena , M. I.; Merino, C.; Merino, C., 2008, Preparation of CNFs surface to coat with copper by electroless process, Materials Letters, Vol.62 ,494–497.

Hsieh, S.H.; Horng, J.J., 2004b, “Fabrication of Nano-Iron-Nickel particles to De-chlorinate Chloroform and Trichloroethene”, 2004, International Symposium on Environmental Nanotechnology, Taipei, Taiwan, December 1-3.

Hong, Yan.; Ning, Xu.; Wen-Yi, Huang.; Huan-Mei, Han.; Shou-Jun, Xiao., 2009, “Electroless plating of silver nanoparticles on porous silicon for laser desorption/ionization mass spectrometry”, International Journal of Mass Spectrometry, Vol. 281, 1–7.

Himendra, Jha.; Tatsuya, Kikuchi.; Masatoshi, Sakairi.; Hideaki, Takahashi., 2009, “Palladium nanoparticle seeded electroless metallization of Al/Al2O3 surfaces”, Materials Letters, Vol. 63, 1451–1454

Hsieh, S.H.; Horng, J.J., 2004c, “The Reaction Mechanism of Decomposing Chloroform by Bi- metallic Nano- Particles of Fe/Ni ”, presented at the 227th American Chemical Society National Meeting, Anaheim, CA, USA, March 28-April 1, vol. 44 No.1.

Hsieh, S. H.; Horng, J. J.; Tsai, C. K.（2006） “ Growth of carbon nanotube on micro-sized Al2O3 particle and its application to adsorption of metal ions.”, J. Mater. Res., Vol. 21(5), 1269-1273.

Huang, L.; Ling, G.; Zhang, C.; Li, J., 2004, “Electroless plating of silver nanoparticles o silica spheres”, Plating and Surface Finishing, Vol. 91(3), 46-50

Huaping Liu, Guoan Cheng, Ruiting Zheng, Yong Zhao, Changlin Liang, 2006, “Influence of acid treatments of carbon nanotube precursors
on Ni/CNT in the synthesis of carbon nanotubes”, Journal of Molecular Catalysis, Vol. 230 , 17–22

Iijima, S. (1991) “Helical Microtubules of Graphitic Carbon.” Nature,
354, 56-58
Johansson, A.; Lu, J.; Carisson, J. –O.; Boman, M., 2004, “Deposition of Palladium nanoparticles on the pore walls of anodic alumina using sequential electroless deposition”, Journal of Applied Physics, Vol. 96(9), 5189-5194

Jie, Ding.; Hongxia, Wang.; Tong, Lin.; Bin, Lee., 2008, “Electroless synthesis of nano-structured gold particles using conducting polymer nanoparticles”, Synthetic Metals, Vol. 158, 585-589

Kalkan, A. K.; Fonash, S. J., 2005, “Electroless synthesis of Ag nanoparticles on deposited nanostructured Si films”, Journal of Physical Chemistry B, Vol. 109(44), 20779-20785.

Konstantin B. Shelimov, Rinat O. Esenaliev, Andrew G. Rinzler, and Chad B. Huffman, 1998, “Purification of single-walled carbon nanotubes by ultrasonically assisted filtration,” Chemical Physics Letters, Vol. 282, 429-434

Kong, J., Franklin, N. R., Zhou, C., Chapline, M. G., Cho, S. P. K. and Dai, H. (2000) “Nanotube molecular wires as chemical sensors” Science, Vol. 287, 622-625.

Ko, C. J., Lee, C. Y., Ko, F. H., Chen, H. L. and Chu, T.C. (2004) “Highly efficient microwave-assisted purification of multiwalled carbon nanotubes” Microelectronic Engineering, Vol. 73-74, 570-577

Ko Fu-Hsiang , Chung-Yang Lee, Chu-Jung Ko, and Tieh-Chi Chu,2005, “Purification of multi-walled nanotubes through microwave heating of nitric acid in a closed vessel,”, Vol. , 43, .727-733.

Li, Y. H.; Ding, J.; Luan, Z.; Di, Z.; Zhu, Y.; Xu, C.; Wu, D.; Wei, B., 2003a, “Competitive adsorption of Pb+2, Cu+2 and Cd+2 ions from aqueous solutions by multiwalled carbon nanotubes”, Carbon, Vol. 41, 2787.

Lui, C., Fan, Y. Y., Lui, M., Cong, H. T., Cheng, H. M. and Dresselhaus, M. S. (1999) “Hydrogen storage in single-walled carbon nanotubes at room temperature”Science , Vol. 286, 1127.

Li, Y. H.; Wang, S.; Luan, Z.; Ding, J.; Xu, C.; Wu, D., 2003b, “Adsorption of cadmium(II) from aqueous solution by surface oxidized carbon nanotubes”, Carbon, Vol. 41, 1057.

Li, Y. H., Wang, S., Wei, J., Zhang, X., Xu, C., Luan, Z., Wu, D. and Wei, B. (2002) “Lead adsorption on carbon nanotubes” Chem. Phys. Let., Vol. 357, 263-266.

Long, R. Q. and Yang, R. Y. ( 2001) “Carbon nanotubes as superior sorbent for dioxin removal” J. Am Chem Soc., Vol. 123, 2058-2059.

Li, Y. H.; Zhu, Y.; Zhao, Y.; Wu, D.; Luan, Z., 2006,“Different morphologyies of carbon nanotubes effect on the lead removeal from aqueous soluteion”, Diamond & Related Materials, Vol. 15, 90-94.

Li, Y.; Wang, S.; Cao, A.; Zhao, D.; Zhang, X.; Xu, C.; Luan, Z.; Ruan, D.; Liang, J.; Wu, D.; Wei, B., 2001, “Adsorption of fluoride from water by amorphous alumina supported on carbon nanotubes”, Chem. Phys. Let, Vol. 350, 412–416.

Ling, G.; He, J.; Huang, L., 2004, “Size control of silver nanoparticles deposited on silica dielectric spheres by electroless plating technique”, Journal of Materials Science, Vol. 39(8), 2955-2957

Ling, Y. Li G.P.2005 “Influencing factors on the uniformity of copper coated nano-Al2O3 powders prepared by electroless plating” Materials Letters 59 (2005) 1610– 1613

Liu, C. M.; Liu, W. L.; Hsieh, S. H.; Tsai, T. K.; Chen, W. J., 2005,“Interfacial reactions of electroless nickel thin film on silicon”, Applied Surface Science, Vol. 243, 259-264.

Liu,Y.; Yang, F.; Yue, P. L.; Chen, G., 2001, “Catalytic dechlorination of chlorophenols in water by palladium/iron”, Water Research, Vol. 35(8), 1887-1890

Lu, C.; Chiu, H., 2006, “Adsorption of zinc (II) from water with purified carbon nanotubes”, Chemical Engineering Science, Vol. 61, 1138-1145.

Lu, C.; Chung, Y. L.; Chang, K. F., 2005, “Adsorption of trihalomethanes from water with carbon nanotubes”, Water Research, Vol. 39, 1183-1189.

Lu, C.; Su, F., 2007, “Adsorption of natural organic matter by carbon nanotubes”, Separation and Purification Technology, Vol. 58, 113-121.

NIOSH; Criteria Document: Inorganic Lead DHEW Pub.NIOSH 78-158 （1978）

Netzer, A.; Hughes, D. E.,（1984）“Adsorption of copper, lead and cobalt by activated carbon”, Water Res., Vol. 18(8), 927

Merkulov, V.I. (2001) “Shaping Carbon Nanostructures by Controlling
the Synthesis Process.” Applied Physics Letter, 79, 1178-1180

Odom. T.W, Huang. J.L, Kim. P, Lieber. C.M, Atomic structure and
electronic properties of single walled carbon nanotubes. ,Nature, 391,
62 (1998).

Pang L. S. K., J. D. Saxby, and S. P. Chatfield, 1993, “Thermogravimetric analysis of carbon nanotubes and nanoparticles,“ Journal of Physical Chemistry,Vol. 27, 6941-6942

Peng, X.; Li, Y.; Luan, Z.; Di, Z.; Wang, H.; Tian, B. ; Jia, Z., 2003“Adsorption of 1,2- dichlorobenzene from water to carbon nanotubes”, Chem. Phys. Let, Vol. 376, 154–158.

Ma, X.; Lun, N.; Wen, S., 2005, Formation of gold nanoparticles supported oncarbon nanotubes by using an electroless plating method, Diamond and Related Materials, Vol. 14(1), 68-73.

Mallory, G. O.; Hajdu, J. B., 1990, Electroless Plating: Fundamentals and Applications, AESF, Orlando, Florida, USA

Schmeckenbecher A.F., 1971, “Autocatalytic (Electroless) nickel and nickel- iron plating for electronic applications”, Plating, v 58, n 9, Sept, 1971, p 905-9

Stafiej, A.; Pyrzynska, K., 2007, “Adsorption of heavy metal ions with carbon nanotubes”, Separation and Purification Technology, Vol. 58, 49-52.

Sone, H.; Fugetsu, B.; Tsukada, T.; Endo, M., 2008, “Affnity-based eliminateion of aromatic VOCs by highly crystalline multi-walled carbon nanotubes”, Talanta, Vol. 74, 1265-1270

Takamura, T., Saito, M., Shimokawa, A., Nakahara, C., Sekine, K. Maeno, S. and Kibayashi, N. (2002) “Charge/discharge efficiency improvement by the incorporation of conductive carbons in the carbon anode of Li-ion batteries” J.Power Sources ,Vol. 90, 45-51

Tsai, C. L. and Chen, C. F. (2003) “Characterization of bias-controlled carbon nanotubes” Diamond and Related Materials, Vol. 12, 1615-1620

Tsang S. C., P. J. Harris, and M. L. Green, 1993, “Thinning and opening of carbon nanotubes by oxidation using carbon dioxide,” Nature,Vol. 62, 520

R. Paul, P. Buisson, and N. Joseph, Ind. Eng. Chem, 44 (1952) 1006

Ruoff, R. S. and Lorents, D. C. (1995) “Mechanical and thermal properties of carbon nanotubes” Carbon, Vol. 33 , 925-930.

Wang, C. B.; Zhang, W. X., 1997, “Synthesizing nanoscale iron particles for rapid and complete dechlorination of TCE and PCBs”, Environ. Sci. Technol. Vol. 31, 2154-2156.

W.L. Liu , S.H. Hsieh , W.J. Chen, 2007, “Preparation of Sn films deposited on carbon nanotubes”, Applied Surface Science, Vol. 253 , 8356–8359.

Wu, Yucheng.; Ren, Rong.; Wang, Fengtao.; Yuan, Zaoshi.; Wang, Tugen.; Hu, Xiaoye., 2008, “Preparation and characterization of Ni–Cu–P/CNTs quaternary electroless composite coating”, Materials Research Bulletin

Wang, F.; Arai, S.; Park, K. C.; Takeuchi, K.; Kim, Y. J.; Endo, M., 2006, “Synthesis of carbon nanotubes-supported nickel-phosphorus nanoparticles by an electroless process”, Vol. 44(7), Carbon, 1307-1310.

Wang, L.; Zhao, L.; Huang, G.; Yuan, X.; Zhang, B.; Zhang, J., 2000, “Composition, structure and corrosion characteristics of Ni–Fe–P and Ni–Fe–P–B alloy deposits prepared by electroless plating”, Surface and Coatings Technology, Vol. 126, 272-278

Xu, C.; Wu, G.; Liu, Z.; Wu, D.; T. T.; Meek, Q. Han, 2004, “Preparation of copper nanoparticles on carbon nanotubes by electroless plating method”, Materials Research Bulletin, Vol. 39(10), 1499-1505

Xiaofeng Song a,b, JunLei a, Zhenyu Li b, Shangyu Li b, Ce Wang，2008 “Synthesis of polyacrylonitrile/Ag core–shell nanowire by an improvedelectroless plating method” Materials Letters VOL 62 (2008) 2681–2684

XUE, Ru-jun1.; WU, Yu-cheng1., 2007, “Mechanism and Microstructure of Electroless Ni-Fe-P Plating on CNTs”, J China Univ Mining & Technol, Vol. 17, 0424–0427

Zhijie, Wu.; Shaohui, Ge.; Minghui, Zhang .; Wei, Li.; Keyi, Tao., 2009, “Synthesis of nickel nanoparticles supported on metal oxides using electroless plating: Controlling the dispersion and size of nickel nanoparticles”, Journal of Colloid and Interface Science, Vol. 330, 359–366

Zhang, W. X.,（2003）“Nanoscale Iron Particles for Environmental Remediation: An Overview,” Journal of Nanoparticle Research, Vol.5, 323-332

Zhen-guo An,; Jing-jie Zhang ,; Shun-long Pan., 2008, “Fabrication of glass/Ni–Fe–P ternary alloy core/shell composite hollow
microspheres through a modified electroless plating process”, Applied Surface Science, Vol. 255, 2219–2224.

Zhanga, C.; Linga, G. P.; He, J. H.,2003, Co–Al2O3 nanocomposites powder prepared by electroless plating, Materials Letters, Vol.58, 200– 204