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研究生:林揚盛
研究生(外文):Yang-Sheng Lin
論文名稱:光合微生物燃料電池開發之研究
論文名稱(外文):Development of Phototrophic Microbial-based Fuel Cell
指導教授:藍祺偉
學位類別:碩士
校院名稱:元智大學
系所名稱:化學工程與材料科學學系
學門:工程學門
學類:綜合工程學類
論文種類:學術論文
論文出版年:2009
畢業學年度:97
語文別:中文
論文頁數:101
中文關鍵詞:光合微生物燃料電池光合作用光照強度介電質電極改質
外文關鍵詞:Phototrophic micro-based fuel cellsphotosynthesislight intensityRhodopseudomonas palustrismodified electrodemediator
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本研究以光合細菌(Rhodopseudomonas palustris)為生物觸媒進行光合微生物燃料電池開發與研究,研究的項目包括(1)電極改質(modified electrode)之影響;(2)介電質(mediator)型態之探討及(3)光合微生物電池於黑暗下或不同光照強度進行化學異營或光合異營之電池效能比較。研究結果得知,改質電極方面,使用奈米碳管石墨板電極分析電池效能可得到最大功率密度為3.26 mW m-2,其中最大的功率輸出分別為粗糙化石墨板的7.4倍、石墨板的12.7倍、不�袗�板的108倍。以介電質Neutral red (NR)固定於石墨板電極,並且利用固定化之電極配合懸浮NR於陽極中,有最大的6.29庫倫輸出表現。探討光照影響研究發現,以葡萄糖為碳源在黑暗下進行化學異營可以擁有最高開環電壓230 mV和最低內電阻10 kΩ,在光照下進行光合異營則具有平穩的電功率輸出優點,本研究可以發現光合微生物燃料電池具有輸出平穩功率和利用光合作用增加電池壽命之效果,為具有應用價值潛力之微生物燃料電池。
In this study, the Rhodopseudomonas palustris was employed as bio-catalyst for development of Photomicrobial fuel cell (PMFC). The research focus upon (i) impact of modified electrodes on performance of biofuel cell; (ii) comparison of biofuel cell efficiency by the application of mediators and (iii) determination of biofuel cell under photohetrophic and chemohetrophic circumstance. The results demonstrated that carbon nanotube graphite of electrode presents more surface area from cyclic voltammograms analysis and generate the highest power output as compared to those graphite and rough-graphite electrodes. Application of mediator of suspended or immobilized neutral red could improved the PMFC performance. The combination of both can yield maximum coulomb. During chemohetrophic determination, PMFC had high cell performance while for photohetrophic, PMFC had stable power output. The results obtained from this study concluded the PMFC could be a promising vehicle for the requirement of energy supply and sustainable development.
第一章 緒論 1

1.1前言 1
1.2燃料電池 4
1.2.1物理化學燃料電池 4
1.2.2生物燃料電池 5
1.2.3酵素型燃料電池(Enzymatic fuel cells or Enzyme-based fuel cells) 9
1.2.4微生物型燃料電池(Microbial fuel cells) 10
1.2.5光合微生物燃料電池(Photomicrobial fuel cells) 12
1.2.6微生物燃料電池的內電阻 13
1.2.7提高微生物型燃料電池的有效方法 18
1.3研究動機與目的 20


第二章 以改質之電極探討光合微生物燃料電池效能 24

2.1前言 24
2.2理論背景 24
2.3材料與方法 26
2.3.1材料 26
2.3.2 方法 29
2.4 結果與討論 34
2.4.1電極改質之循環伏安儀分析 34
2.4.2改質電極之電子顯微分析 37
2.4.3電極改質後對光合菌微生物燃料電池的效能影響 40
2.5結論 46








第三章 介電質型態與光合微生物燃料電池影響探討 47

3.1前言 47
3.2 背景理論 47
3.2.1介電質提升電子傳導原理 47
3.2.2生物燃料電池常用之介電質型態 49
3.2.3介電質的選擇 50
3.3材料與方法 52
3.3.1材料 52
3.3.2方法 53
3.4結果與討論 55
3.4.1固定化NR測試與檢測 55
3.4.2石墨板與固定化NR電極板之輸出電流比較 61
3.5結論 70


第四章 探討光合燃料電池對於光源與碳源改變之影響 71

4.1前言 71
4.2背景理論 71
4.3材料與方法 78
4.3.1材料 78
4.3.2方法 80
4.5結論 92


第五章 總結 93

參考文獻 97

附錄 101
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