臺灣博碩士論文加值系統

Polybenzoxazine(PBZ)是新型開發之加成聚合的酚醛樹脂，具有很多廣泛的特性，可以克服許多傳統酚醛樹脂的缺點。從許多文獻中，我們得知benzoxazine (BZ)的改質，可透過導入各種不同的官能基進入到benzoxazine的分子結構來改進其性質，或者利用不同的benzoxazine單體進行混摻，可以降低聚合溫度、提昇熱穩定性。

本研究係以新型benzoxazine單體合成為研究主體，成功地合成Uracil based benzoxazine單體(簡稱UBZ)，具有可形成多點式氫鍵作用力之官能基，為一全新開發之材料。
DSC及IR分析指出於BZ中摻入UBZ，uracil形成之自身氫鍵作用力，可影響整體開環聚合之溫度，造成開環聚合溫度下降之效果。。透過TGA及抗菌性試驗，可得知，PUBZ相較於以往傳統之PBZ，除仍具有一定之熱穩定性外，uracil官能基之導入，使其有機會應用於生物相關領域，為benzoxazine之應用開拓新方向。

Polybenzoxazine is an addition polymerized phenolic resin, having a wide range of interesting features and the capability to overcome several shortcomings of conventional novolac and resole type phenolic resins. In many literatures, we learned that the properties of polybenzoxazines can be tuned by inducing different functional groups into the molecular structure of benzoxazine.
In this thesis, a new benzoxazine monomer, uracil based benzoxazine (UBZ), possessing multiple hydrogen bonding interaction sites was successfully prepared. By inducing UBZ to BZ, the self-complementary interaction within uracil would result in relatively lower ring-opening polymerization temperature. In addition, the anti -bacterial test indicated that PUBZ had the potential for biological application.

＜目錄＞

中文摘要 i
英文摘要 iii
誌謝 v
目錄 vi
表目錄 ix
圖目錄 x

第一章 緒論 1
1-1 前言 1
1-2 Benzoxazine及polybenzoxazine單體及高分子合成 3
1-3 Benzoxazine合成方法的改善 4
1-4 Polybenzoxazine(PBZ)特性 5
1-5 影響Benzoxazine聚合相關研究探討 6
1-6 Benzoxazine的改質 8
1-7 聚氧代氮代苯并環己烷 [polybenzoxazine (PBZ)]之應用 10
1-8 研究動機與目的 16
第二章 實驗內容 33
2-1 藥品 33
2-2 溶劑 34
2-3 儀器設備 35
2-4 樣品製備 36
2-4-1 Uracil based benzoxazine之合成(簡稱UBZ) 36
2-4-2 B-a type benzoxazine之合成(簡稱BZ) 37
2-4-3 UBZ與BZ的混摻 38
2-5 實驗儀器原理 38
2-5-1 核磁共振儀( NMR) 38
2-5-2 微分掃熱卡計(DSC) 40
2-5-3 熱裂解分析儀(TGA) 41
2-5-4 傅立葉轉換紅外線光譜儀(FT-IR) 44
2-5-5 旋轉塗佈機(spin coater) 45
第三章 結果與討論 52
3-1 有機合成原理探討 52
3-1-1 1-(10-Bromo-decyloxy)-4-nitro-benzene之合成 52
3-1-2 1-[10-(4-Nitro-phenoxy)-decyl]-1H-pyrimidine-2,4-dione之合成 53
3-1-3 1-[10-(4-Amino-phenoxy)-decyl]-1H-pyrimidine-2,4-dione之合成 54
3-1-4 Uracil based benzoxazine之合成 55
3-2 有機合成產物之結構鑑定 56
3-2-1 Compound1之結構鑑定 56
3-2-2 Compound2之結構鑑定 57
3-2-3 Compound3之結構鑑定 58
3-2-4 UBZ之結構鑑定 59
3-3 UBZ 與BZ混摻之DSC圖分析 61
3-4 UBZ 與BZ混摻之TGA圖分析 62
3-5 UBZ 與BZ混摻之IR圖分析 63
3-6 PUBZ 與PBZ之生物相容性試驗 64
第四章 結論 80
參考文獻 81
簡歷 90

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