臺灣博碩士論文加值系統

就電流密度、電池電壓與光電轉換效率而論，來自於Benzimidazolium salts 的N-Heterocyclic carbene-pyridine-based ruthenium 染料提供染料敏化太陽能電池表現出高成效。在AM 1.5 輻射(100 mWcm-2)下，提供了Jsc、Voc與η 數值分別為20.0 mAcm-2、730 mV 與9.69 %；這表現超越過去公認所使用的N719 染料(Jsc = 18.6 mAcm-2; Voc = 700 mV; η = 8.98 %)。

N-Heterocyclic carbene-pyridine-based ruthenium sensitizers derived from benzimidazolium salts provide dye-sensitized solar cells exhibiting superior performance in terms of their current densities, cell voltages and photoelectric conversion efficiencies. A solar cell sensitized with CBTR provided values of Jsc, Voc and η of 20.0 mAcm-2, 730 mV and 9.69 %, respectively, under AM 1.5
irradiation (100 mWcm-2); this performance exceeds that obtained using the traditional N719 dye (Jsc = 18.6 mAcm-2; Voc = 700 mV; η = 8.98 %).

摘要........................................................................................................................I
Abstract ................................................................................................................ II
目錄..................................................................................................................... III
圖目錄.................................................................................................................IV
表目錄.................................................................................................................. V
第一章 緒論......................................................................................................... 1
第二章 NHC-pyridine-based ruthenium結構的合成及其性質探討.................. 3
2-1 實驗設計................................................................................................. 3
2-2 NHC-pyridine-based ruthenium染料CBTR的合成及策略................... 5
2-3 光學性質探討......................................................................................... 7
2-4 電化學性質探討................................................................................... 10
2-5 太陽能電池元件探討........................................................................... 11
第三章 結論....................................................................................................... 13
第四章 實驗部分............................................................................................... 14
4-1 合成步驟及數據................................................................................... 14
4-2 儀器與藥品........................................................................................... 17
4-3 電化學測量........................................................................................... 18
參考文獻............................................................................................................. 19
附錄 化合物1H與13C NMR光譜及高解析質譜........................................... 22

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