水處理涵貌瑤d圍甚廣，包括工業用水、廢水的處理，雨水、河水處理變成家庭用水等。在水處理的過程與設備中往往涉及多種階段之處理，根據不同需求所需要處理的等級也不同，例如純水(RO)、去離子水(DI)、超純水等。國內釵h濾水器材製造廠商所生產的產品類別大多含有活性碳濾心，因為活性碳在水處理過程中佔有一重要角色，但是廠商在選擇使用活性碳等級時，往往不知如何正確選擇來配合產品性能，以致於會發生使用等級過高導致獲利降低、或是使用等級過低導致檢測試驗未能通過，造成產品檢驗成本增加與產品上市時間延期。
本研究針對顆粒型活性碳等級選用之問題加以探討，除了必須符合檢驗標準以確保使用安全之外，同時應用田口方法（Taguchi Method）配合氯減量檢驗標準（CNS14933）進行實驗設計，找出活性碳等級、處理流量與使用重量等三者控制因子間的參數組合，再以資料包絡分析法（Data envelopment analysis, DEA）與資料群集處理技術(Group Method of Data Handling, GMDH)確認最佳效率組合與尋求三者的關係方程式，提供廠商在設計濾水器時選擇最佳的等級活性碳與使用量，幫助廠商了解其開發產品之成本效益與壽命，進而到產品通過認證。同時將此關係式應用於一家濾水器材製造廠，以實際產品進行規劃驗證此關係式的正確性。

The category of water treatments includes industrial water, wastewater treatment, rainwater, river water into a household water treatment, and so on. The processes and equipment in water treatment often involve multiple stages of procedures, depending on level of requirements needed to be addressed, such as reverse of osmosis water (RO), deletion of ion water (DI), or ultra-pure of water. Many water treatment equipment manufacturers produce various types of products containing carbon filter because the carbon filter in water treatment processes plays an important role. However, the manufacturers who choose to use activated carbon grades often do not know how to match the product with the right choice of performance. This might result in high lead levels with lower profits, or failure to pass tests due to the use of low lead level, or too high product testing cost, or even time delay to market.
In this study, the problem of how to determine level of activated carbon particle types is explored, as long as the requirements to meet the inspection standards to ensure product safety. Application of Taguchi method along with chlorine reduction test (CNS14933) experimental designs presents to identify the activated carbon level, deal with traffic and use of weights among three control factors. Data Envelopment Analysis (DEA) and Group Method of Data Handling (GMDH) are then used to explore the satisfactory combination. Results from this study can provide better design of filters for selecting the best level when using activated carbon and help companies understand the cost-effective product development and life. Also the developed approach can help companies apply product certification. The presented relationships can also help water treatment equipment manufacturers verify if the actual product planning relationship is correct.

中文摘要.............................................. I
Abstract ............................................. II
目錄.................................................. III
圖目錄................................................ IV
表目錄................................................ V
第一章 緒論........................................... 1
1.1 研究背景...................................... 1
1.2 研究動機...................................... 2
1.3 研究目的...................................... 3
第二章 文獻探討....................................... 5
2.1 田口實驗計劃法................................ 5
2.2 資料包絡分析法................................ 6
2.3 資料群集處理技術.............................. 8
2.4 活性碳濾水器產業與市場現況.................... 9
2.5 活性碳........................................ 10
2.6 CNS 14933餘氯檢測標準......................... 16
2.6.1 標準制定................................. 16
2.6.2 標準簡介................................. 17
第三章 研究方法....................................... 18
3.1 設計實驗方法.................................. 18
3.1.1 田口實驗設計............................. 19
3.2 實驗方法與步驟................................ 21
3.2.1 實驗藥品與儀器........................... 22
3.2.2 樣品製備................................. 22
3.2.3 測試水樣製備............................. 24
3.2.4 裝置..................................... 25
3.2.5 實驗步驟................................. 27
3.3 分析方法...................................... 29
第四章 實驗結果分析................................... 31
4.1 實驗產品...................................... 31
4.2 實驗結果...................................... 33
第五章 結論與建議..................................... 40
參考文獻.............................................. 42

American Society for Testing and Materials, 2006, D4607 standard test method for determination of iodine number of activated carbon.
Bansal, R. C., J. B. Donnet and F. Stochli, 1988, Active carbon. New York: Dekker. 121-129.
Barker, T.B., 1986, Quality engineering by design: Taguchi’s philosophy. Quality Progress, Vol 19, No.12, 32-42.
Carbons, J.,2008, Activated carbon for liquid phase adsorption. www.jacobi.net
Charnes, A., Cooper, W. W. and Rhodes, E., 1978, Measuring the efficiency of decision-making units. European Journal of Operational Research, Vol 2, 429-444.
Farlow, S. J., 1981, The GMDH algorithm of Ivakhnenko. American Statistician, Vol 35, No 4, 210-215.
Farlow, S. J., 1984, The GMDH algorithm, self-organizing methods in modeling: GMDH type algorithms. Edited by Farlow, S. J. and Dekker, M., New York, 1-24.
Fisher, R.A., 1925, Statistical methods for research workers. Edinburgh: Oliver & Boyd, 1st edition.
Ivakhnenko, A. G., 1970, Heuristic self-organization in problems of engineering cybernetics, Automatica, Vol 6, 207-219.
Lewin, A. Y. and Minton, J. W., 1986, Determining organizational effectiveness: another look and an agenda for research. Management Science, Vol.32,No.5, 514-538.
Liao, H. C., 2004, A data envelopment analysis method for optimizing multi-response problem with censored data in the Taguchi method. Computers & Industrial Engineering, Vol 46, 817-835.
Mehrabian, S., Alirezaee, M. R. and Jahanshahloo, G., R., 1999, A complete efficiency ranking of decision making units in data envelopment analysis. Computational Optimization and Applications, Vol 14, 261-266.
Oh, S. K. and Pedrycz, W., 2002, The design of self-organizing polynomial neural networks, Information Sciences, Vol 141, 237-258.
丁志華，戴寶通，2001，田口實驗計畫法簡介(I)，毫微米通訊，第八卷第三期。
吳俊哲，2008，銀/活性碳複合材料備製與過濾消毒之研究，逢甲大學環境工程與科學研究所碩士論文。
林永璋，2007，高級淨水程序處理成效與廢水回收再利用之可行性研究—以大高雄地區淨水廠為例，國立中山大學環境工程研究所博士論文。
孫遜，2004，「資料包絡分析法－理論與應用」，揚智，台北。
釧等礡A2008，煤灰未燃碳由連續活化產出吸附材料之研究，國立成奶j學資源工程學系碩士論文。
雀振瓷A2006，應用批次與連續流試驗探討實驗室分離之除臭菌株對水庫中臭味物質降解之能力，國立成奶j學環境工程學系碩士論文。
彭光中，蔡瀚儀，盧俊鼎，謝志強，2009，全球市場導向的台灣水資源技術商機探索，工研院IEK，出版編號: ITRIEK-0453-S823(98)。
黃盈賓，2005，竹活性碳應用於淨水處理，工研院生態複合材料部，PP.7-15。
經濟部工業局污染防治技術服務團，1987，「工業廢水活性碳處理」，工業污染防治技術手冊之七，財團法人中國技術服務社編印。
劉春初，1998，「公共部門效率衡量—DEA與AHP之應用」，中華管理評論。Nov.1, No.2。
劉彭譽，2002，臭氧結合傳統淨水程序控制鳳山水庫原水消毒副產物生成之研究，逢甲大學環境工程與科學研究所碩士論文。
蔡志偉，2008，唐麗英，應用資料包絡分析法與自組性演算法最佳化來自實驗設計之多反應變數，品質學報 Vol. 15, No. 4。
蔡朋枝，陳旺儀，陳裕政，2009，以田口實驗設計法釐訂高溫作業環境之工程控制策略，工業安全科技，PP.36-40。
盧重興，蘇峰生，2005，奈米碳管—水中污染物質剋星，學門研究成果成幼?#63925;專欄報噵。