本文研究使TC-35/EHM-63碳纖維環氧樹脂複材預浸料，利用熱壓釜成形技術製作六種疊序的試片，疊序為 [040/M/9080/M/040/M]M (M=1,2,4,8,20,40)。組成160層之碳纖維複材積層板，積層後厚度25-27mm，成化後厚度24-25mm。疊製時輔以輥軋除氣，減少空孔殘留影響複材厚積層板品質，以確保實驗的穩定性、一致性及可靠度。並以超音波非破壞檢測輔助，檢驗複材厚積層板膠合狀況，確保複材厚積層板品質良好，進行簡支樑及懸臂樑(靜態、動態)撓曲測試，以及其他相關測試 ，觀察其機械性能，觀察複材厚積層板受拉伸模式負載及壓縮模式負載時裂紋及破壞行為。經由顯微觀察層間破壞，發現有纖維斷裂、纖維抽絲、纖維/基材界面分離、基材破裂及脫層等現象。藉此試驗，所產生的撓曲性能與疊序之間的關係如下:
1. 簡支樑撓曲測試結果顯示:(1) 撓曲強度M4其撓曲強度較強。(2) 當M值由大變小時撓曲模數會有逐漸增強趨勢。(3) 六種疊序中以M4為最佳。
2. 懸臂樑靜態與動態撓曲測試結果顯示:(1) 動態撓曲負載值大於靜態撓曲負載值。(2) 靜態撓曲負載值受疊序影響明顯，動態撓曲負載值不受疊序影響。(3) 當M值由大變小時動態撓曲能量會有逐漸增強趨勢。

誌 謝 i
摘 要 ii
ABSTRACT ii
目錄 vi
圖目錄 x
表目錄 xv
第一章 前言 1
1.1 引言 1
1.2 研究動機 2
第二章 理論與文獻回顧 4
2.1 碳纖維 4
2.1.1 碳纖維的問世與發展進程 4
2.1.2 碳纖維的分類與優異性能 6
2.1.3 碳纖維的廣泛用途與發展趨勢 9
2.2 環氧樹脂 10
2.2.1 環氧樹脂之特性 10
2.2.2 環氧樹脂的硬化反應 11
2.3 預浸材 12
2.3.1 預浸材料之定義與特性 12
2.3.2 樹脂性質影響纖維與基材之鍵結強度 13
2.3.3 纖維含浸環氧樹脂預浸料之製作 14
2.3.4 預浸材料之檢測 17
2.4 積層板原理 20
2.4.1 [C]勁度矩陣及[S]柔度矩陣 20
2.4.2 [Q]複材勁度矩陣 21
2.4.3 轉置勁度矩陣 21
2.4.4 合力與合力耦合與中心面應變和中心面曲率關係 22
2.4.5 [D]積層板彎曲勁度矩陣 23
第三章 實 驗 25
3.1 實驗流程 25
3.2 實驗材料 25
3.3 實驗設備 26
3.4 試片製作 31
3.4.1 預浸材切割 31
3.4.2 疊層製作 32
3.4.3 包裝封袋及成化 33
3.4.4 掃描式三軸量床檢測 40
3.4.5 超音波檢測 46
3.4.6 試片切割與加工 49
3.5 實驗測試 50
3.5.1 三點撓曲測試 50
3.5.2 懸臂樑靜態撓曲測試 52
3.5.3 懸臂樑動態撓曲測試 53
3.6 光學顯微鏡及掃描式電子顯微鏡觀察 54
第四章 結果與討論 55
4.1 三點撓曲測試 55
4.1.1 M1測試 55
4.1.2 M2測試 58
4.1.3 M4測試 61
4.1.4 M8測試 64
4.1.5 M20測試 67
4.1.6 M40測試 70
4.1.7 三點撓曲結果討論 73
4.2 懸臂樑靜態撓曲測試 75
4.2.1 M1測試 75
4.2.2 M2測試 79
4.2.3 M4測試 83
4.2.4 M8測試 87
4.2.5 M20測試 91
4.2.6 M40測試 95
4.2.7 懸臂樑靜態撓曲結果討論 99
4.3 懸臂樑動態撓曲測試 101
4.3.1 M1測試 101
4.3.2 M2測試 104
4.3.3 M4測試 108
4.3.4 M8測試 112
4.3.5 M20測試 116
4.3.6 M40測試 120
4.3.7 懸臂樑動態撓曲結果討論 124
4.3.8 M1有没有V型缺口測試 126
4.3.9 M40有没有V型缺口測試 129
4.4 SEM電子顯微鏡觀察 132
4.4.1 M20懸臂樑動態撓曲試片 132
4.4.2 M8三點撓曲試片 145
第五章 結論 150
參 考 文 獻 153

1. 郭文雄, 複合材料, 高立出版社(1998)。
2.郭文雄, 複合材料纖維學, 全威出版社(2002)。
3.柯澤豪, 劉顯光, 郭文雄, 複合材料入門 , 中華民國尖端材料科技學會; 1(6): 17-23(2005)。
4.Gay D. and Hoa S.V., Composite materials, design and applications, CRC Press, New York ; 7(1): 135-161(2007)。
5.Donnet J. B., Bansal R. C., Carbon Fiber, second edition, MarcelDekker inc.(1990)。
6.Goodhew P. J., Clarke A. J., and Bailey J. E. Mater. Sci. Eng. v17, p3 (1975)。
7.垣內弘, 環氧樹脂應用實務, 復漢出版社(1981)。
8.馬振基, 高分子複合材料, 正中出版社(1995)。
9.呂欣芳, 短纖維複合材料之製程與物性檢測, 逢甲大學機械工程學系碩士論文(2003)。
10.連仁聖, PAN 系氧化纖維碳化工程中牽伸率對物性及微細構造之研究, 逢甲大學機械工程學系碩士論文(2002)。
11.林永崑, 厚複材積層板壓縮破裂行為分析, 逢甲大學機械航空工程博士學位學程博士論文(2008)。
12.邱柏書, 碳纖維補強石墨塊物性分析, 逢甲大學航太與系統工程學系碩士論文(2010)。
13.游程閎, 厚複材積層板膠合狀態之超音波檢測, 逢甲大航太與系統工程學系碩士論文(2009)。
14.Graff K.F., A History of Ultrasonics, Physical Acoustics, 15, pp1-97 (1981)。
15.陳志明, 複合材料積層板及樑結構之彈性常數識別, 交通大學機械工程學系博士論文(2006)。
16.Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials,American Society for Testing and Materials 2010;ASTM D790.
17.Hou J.P., Jeronimidis G., Bending stiffness of composite plates with delamination, Compos Pt A;31(2):121-132(2000).
18.Chengye F., BenJar P. Y., Roger Cheng J.J., Energy-based analyses of delamination development in fibre-reinforced polymers under 3-point bending, Compos Sci Technol;66(13):2143-2155(2006).
19.Ryou H., Chung K., Development of viscoelastic/ rate-sensitive-plastic constitutive law for fiber-reinforced composites and its applications Part II: Numerical formulation and verification, Compos Sci Technol;69(2):292-299(2009).
20.盧威華，碳纖/環氧樹脂複合材料的撓曲破損，中山大學材料工程研究所碩士論文(1990)。
21.尤介男，三次元正交型碳/環氧樹脂複合材料之製程與破損分析，逢甲大學紡織工程研究所碩士論文(1999)。
22.Onur S., Sami A., Halil A., An elastic/plastic solution for a thermoplastic composite cantilever beam loading by bending moment, Compos Sci Technol;60(14):2739-2745(2000).
23.Gillespie J. W., JR , Wilkins D. J., Mode II Interlaminar Fracture of the Center Notch Flexural Specimen under Impact Loading, J Compos Mater;24(2):124-149(1990).
24.Adams Donald F., Adams Larry G., Tensile Impact Tests of AS4/3501-6 and S2/3501-6 Unidirectional Composites and the 3501-6 Epoxy Matrix, J Compos Mater;24(3):256-268(1990).
25.Choi H. Y., Wang H. S., Chang F. K., Effect of Laminate Configuration and Impactor''s Mass on the Initial Impact Damage of Graphite/Epoxy Composite Plates Due to Line-Loading impact, J Compos Mater;26(6):804-827(1992).
26.Strait L.H., Karasek M.L., Amateau M.F., Effects of Stacking Sequence on the Impact Resistance of Carbon Fiber Reinforced Thermoplastic Toughened Epoxy Laminates, J Compos Mater;26(12):1725-1740(1992).
27.Lee D. G., Cheon S. S., Impact Characteristics of Glass Fiber Composites with Respect to Fiber Volume Fraction, J Compos Mater;35(1):27-56(2001).
28.Hong H., Baozhong S., Hanjian S., Bohong G., A Comparative Study of the Impact Response of 3D Textile Composites and Aluminum Plates, J Compos Mater;44(5):593-619(2010).
29.Mohammadi S., Moosavi Khandan A.A., 3D Multi Delamination/Fracture Analysis of Composites Subjected to Impact Loadings, J Compos Mater;41(12):1459-1475(2007).
30.Lim T. S., Lee C. S., Lee D. G., Failure Modes of Foam Core Sandwich Beams under Static and Impact Loads, J Compos Mater;38(18):1639-1662(2004).
31.Reyes G., Static and Low Velocity Impact Behavior of Composite Sandwich Panels with an Aluminum Foam Core, J Compos Mater; 42(16):1659-1670(2008).
32.Mahmoudi N., Hebbar A., Zenasni R. , Lousdad A., Effect of Impact Directions, Fiber Orientation, and Temperature on Composite Material Strength, J Compos Mater;43(16):1713-1727(2009).
33.Arguelles A., Fernandez-Canteli A., Vina J., Garcia M.A., Evolution of the Impact Strength of Carbon Fiber-reinforced PEI Following Exposure to Mechanical, Hygrothermal and Hygrothermomechanical Aging, J Compos Mater;41(19):2337-2346(2007).
34.Zuleyha A., Ramazan K., Onur S., Dynamic Characteristics of Laminated Woven E-Glass-Epoxy Composite Plates Subjected to Low velocity Heavy Mass Impact, J Compos Mater;36(21):2421-2442(2002).
35.Mesut U., Memduh K., Dynamic Response of Laminated Composites Subjected to Low-velocity Impact, J Compos Mater;41(24):2877-2896(2007).
36.Dewowski B. J., Sue H. J., Morphology and Compression-After- Impact Strength Relationship in Interleaved Toughened Composites, Polym Compos;24(1):158-170(2003).
37.Kessler A., Bledzki , Rzej K., Low Velocity Impact Behavior of Glass Epoxy Cross-Ply Laminates With Different Fiber Treatments, Polym Compos;20(2):269-278(1999).
38.Prakaipetch P., Nandika A., Witold B., Mechanical Properties of Glass Fiber Composites Withan Epoxy Resin Modified by a Liquid Crystalline Epoxy, Polym Compos;23(4):564-573(2002).
39.Lihua L.v., Baozhong S., Yiping Q., Bohong G., Energy Absorptions and Failure Modes of 3D Orthogonal Hybrid Woven Composite Struck by Flat-Ended Rod, Polym Compos;27(4):410-416(2006).
40.Tsotsis T. K., Interlayer Toughening of Composite Materials, Polym Compos;30(1):70-86(2009).
41.Rhodes M.d., Williams J.G., Starnes J. J., Low-Velocity Impact Damage in Graphite-Fiber Reinforced Epoxy Laminates, Polym Compos;2(1):36-44(1981).
42.Kau H. T., A Study of the Impact Behavior of Chopped Fiber Reinforced Composite, Polym Compos;11(5):253-264(1990).
43.Hufenbach W., Marques Ibraim F., Langkamp A., Bohm R., Hornig A., Charpy Impact tests on composite structures – An experimental and numerical investigation, Compos Sci Technol;68(12):2391-2400(2008).
44.Wang X., Hu B., Feng Y., Liang F., Mo J., Xiong J., Qiu Y., Low velocity Impact properties of 3D woven basalt/aramidhybrid composites, Compos Sci Technol;68(2):444-450(2008).
45.Sandrine P., Christophe B., Alain B., Barrau J. J., Impact and compression after Impact experimental study of a composite laminate with a cork thermal shield, Compos Sci Technol;67(15-16):3286-3299(2007).
46.Li S., Reid S.R., Zou Z., Modelling damage of multiple delaminations and transverse matrix cracking in laminated composites due to low velocity lateral Impact, Compos Sci Technol;66(6):827-836(2006).
47.Lopes C.S., Seresta O., Coquet Y., Gurdal Z., Camanho P.P., Thuis B., Low-velocity Impact damage on dispersed stacking sequence laminates.Part I: Experiments, Compos Sci Technol;69(7-8):926-936(2009).
48.Pozuelo M., Carreno F., Ruano O.A., Delamination effect on the Impact toughness of an ultrahigh carbon–mild steel laminate composite, Compos Sci Technol;66(15):2671-2676(2006).
49.Foo C.C., Chai G.B., Seah L.K., A model to predict low-velocity Impact response and damage in sandwich composites, Compos Sci Technol;68(6):1348-1356(2008).
50.Alessandro P., Ivan C., Claudio M., Experimental optimization of the Impact energy absorption of epoxy–carbon laminates through controlled delamination, Compos Sci Technol;68(13):2653-2662(2008).
51.Gupta J. S., Allix O., Boucard P.A., Fanget A., Hereil P.L., Fracture prediction of a 3D C/C material under Impact, Compos Sci Technol;65(3-4):375-386(2005).
52.Sevkat E., Liaw B., Delale F., Basavaraju B. Raju, Drop-weight Impact of plain-woven hybrid glass–graphite/ toughened epoxy composites, Compos Pt A;40(8):1090-1110(2009).
53.郭學舉，複合材料曲板衝擊破壞強度之探討，台灣大學造船及海洋工程學研究所碩士論文(2000)。
54.Twardowskl T.E., Lin S.E., Geil P.H., Curing in thick composite laminates: experiment and simulation, J Compos Mater; 27(3): 216-250(1993).
55.Hojjati M., Hoa S.V., Curing simulation of thick thermosetting composites, Compos Manuf; 5(3): 159-169(1994).
56.Young W.B., Compacting pressure and cure cycle for processing of thick composite laminates, Compos Sci Technol; 54(3): 299-306(1995).
57.Young W.B., Resin flow analysis in the consolidation of multi-directional laminated composites, Polym Compos; 16(3): 250-257(1995).
58.Young W.B., Consolidation and cure simulations for laminated composites, Polym Compos; 17(1): 142-148(1996).
59.Chang M.H., Chen C.L., Young W.B., Optimal design of the cure cycle for consolidation of thick composite laminates, Polym Compos; 17(5): 743-750(1996).
60.Antonucci V., Giordano M., Imparato S.I., Nicolais L., Analysis of heat transfer in autoclave technology, Polym Compos; 22(5): 613-620(2001).
61.Antonucci V., Giordano M., Imparato S.I., Nicolais L., Autoclave manufacturing of thick composites, Polym Compos; 23(5): 902-910(2002).
62.Shin D.D., Hahn H.T., Thermal control system for thick composite laminates based on forecasting, Polym Compos; 25(1): 37-48(2004).
63.Shin D.D., Hahn H.T., Compacting of thick composites: simulation and experiment, Polym Compos; 25(1): 49-59(2004).
64.Xiangqiao Y., Consolidation simulation of composite laminates: Formulation and validation verification, Polym Compos; 26(6): 813-822(2005).
65.Springer G.S., Tsai S.W., Thermal conductivities of unidirectional materials, J Compos Mater; 1(2): 166-173(1967).
66.Lee W.I., Loos A.C., Springer G.S., Heat of reaction, degree of cure, and viscosity of Hercules 3501-6 resin, J Compos Mater; 16(6): 510-520(1982).
67.Loos A.C., Springer G.S., Curing of epoxy matrix composites, J Compos Mater; 17(2): 135-169(1983).
68.Gutowski T.G., Morigaki T., Cai Z., The consolidation of laminate composites, J Compos Mater; 21(2): 172-188(1987).
69.Gutowski T.G., Cai Z., Bauer S., Boucher D., Kingery J., Wineman S., Consolidation experiments for laminate composites, J Compos Mater; 21(7): 650-669(1987).
70.Dave R., Kardos J.L., Dudukovic M.P., A model for resin flow during composite processing Part 1: General mathematical development, Polym Compos; 8(1): 29-38(1987).
71.Dave R., Kardos J.L., Dudukovic M.P., A model for resin flow during composite processing Part 2: Numerical analysis for unidirectional graphite/epoxy laminates, Polym Compos; 8(2): 123-132(1987).
72.Kim C., Teng H., Tucker C.L., White S.R., The continuous curing process for thermoset polymer composites Part 1: modeling and demonstration, J Compos Mater; 29(9): 1222-1253(1995).
73.White S.R., Kim Y.K., Staged curing of composite materials, Compos Pt A; 27(3): 219-227(1996).
74.Loos A.C., MacRae J.D., A process simulation model for the manufacture of a blade-stiffened panel by the resin film infusion process, Compos Sci Technol; 56(3): 273-289 (1996).
75.Smith G.D., Poursartip A., A comparison of two resin flow models for laminate processing, J Compos Mater; 27(17): 1695-1711(1997).
76.Blest D.C., Mckees, Zulkifl A.K., Marshall P., Curing simulation by autoclave resin infusion, Compos Sci Technol; 59(16): 2297-2313(1999).