本研究是以鄰-苯二酚，間-苯二酚及對-苯二酚與脂肪族雙胺進行合成製備苯並噁嗪，透過FT-IR 檢測其官能基並證明苯並噁嗪成功地合成出來。透過FT-IR 檢測累進1 小時的加熱開環特性吸收峰，亦證實了加熱開環交聯的過程是正常無誤的。根據DSC 的檢測圖表示，由於結構中含有aminomethylol group ，所以在低溫130 ℃ 左右時，會放出小幅度的放熱峰，且各系列的苯並噁嗪在短鏈段時Tp 是最為早的，另外在mBZ 系列中，因內含的反應中間體過多，所以Tp 峰值較為複雜。在TGA 檢測圖顯示，耐熱性方面，oBZ 系列、mBZ 系列、pBZ 系列，影響上不會特別的明顯。最後成型方面，oBZ 、mBZ 系列無法順利形成塊材，而是產生深色粉狀，而pBZ 系列方面，可成功行成塊材，但當溶劑從溶液中逐漸取出時，樣品會隨之而逐漸固化，最後剩餘少部分溶劑時，會因此產生氣泡破壞塊材完整性。

This study is synthesised benzoxazine prepared by benzenediols and aliphatic diamine. FT-IR detects the functional groups and proves the successful synthesis of benzoxazine. FT-IR detection of characteristic absorption peak of progression through the 1 hour heat, also confirmed that the heating process of the open-ring cross-linking is correct. By the DSC graph of testing, the structure contains aminomethylol group, so the temperature around 130 ℃, it will found a slight exothermic peak, and the series of benzoxazine in the short chain is the most early period of time Tp. In the mBZ series, because the reaction intermediates containing too much, Tp the peak is more complex. Detected in the TGA diagram shows, in terms of fire, oBZ series, mBZ series, pBZ series, will not particularly affect the apparent. Finally, molding by oBZ, mBZ series can not successfully form a block, these were be the dark powder, and pBZ series, it can successfully form a block, but gradually removing the solvent from the solution, the samples will be performed gradually curing, the last remaining small part of the solvent, the resulting bubbles will destroy the integrity of bulk materials.

總目錄
摘要 I
Abstract II
致謝 IV
總目錄 V
圖目錄 VIII
表目錄 XI
第一章　研究計畫之背景 1
1-1　前言 1
1-2　酚醛樹脂的介紹 2
1-3　聚苯並噁嗪的介紹 4
1-3-1　玻璃轉移溫度 5
1-3-2　熱膨脹係數 6
1-3-3　機械性質 6
1-4　研究動機 7
第二章　原理與文獻回顧 8
2-1　聚苯並噁嗪介紹 8
2-1-1　苯並噁嗪文獻回顧 8
2-1-2　苯並噁嗪的反應聚合機制 9
2-2　苯並噁嗪單體的開發 11
2-3　聚苯並噁嗪於鏈段高分子型態上的研究 16
2-4　聚苯並噁嗪於摻合上之研究 20
2-4-1　奈米矽酸鹽（Polyhedral Oligomeric Silsesquioxanes, POSS） 20
2-4-2　蒙脫土（Montmorillonite, MMT） 21
2-4-3　奈米碳管（CNT） 22
2-4-4　碳纖維（Carbon Fiber） 22
2-4-5　其它 23
2-5　聚苯並噁嗪未來之展望與發展 23
2-6　研究目標 24
第三章　實驗流程與性質測試 25
3-1　實驗藥品與檢測儀器 25
3-1-1　實驗藥品 25
3-1-2 檢測儀器 27
3-2 實驗流程 28
3-3　實驗儀器檢測說明 31
第四章　結果與討論 37
4-1　傅立葉轉換紅外線光譜儀鑑定與分析的結果 37
4-2　熱性質分析 39
4-2-1　微差掃描熱卡計（DSC）分析的結果 39
4-2-2　熱重分析儀（TGA）分析的結果 40
4-3　熱機械性質分析 41
第五章　結論與展望 66
參考文獻 67

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