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研究生:邱渝喆
研究生(外文):Chiou, Yu Jhe
論文名稱:微波輔助方法製備奈米觸媒墨水於噴印金屬化之應用
論文名稱(外文):Microwave-Assisted Synthesis of Nano-Catalyst Ink To The Inkjet Printing Technology Apply To The Metallization Pattern
指導教授:葛明德葛明德引用關係
指導教授(外文):Ge, Ming De
口試委員:張章平胡文華楊勝俊曾俊傑
口試委員(外文):Jang, Jang PingHu, Wen HuaYang, Sheng JiunTzeng, Jiun Jie
口試日期:2012-05-16
學位類別:碩士
校院名稱:國防大學理工學院
系所名稱:化學工程碩士班
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2012
畢業學年度:100
語文別:中文
論文頁數:86
中文關鍵詞:微波法鈀金屬觸媒墨水噴墨列印
外文關鍵詞:MicrowaveElectrolessinkjet printingNIPAAm
相關次數:
  • 被引用被引用:0
  • 點閱點閱:213
  • 評分評分:
  • 下載下載:11
  • 收藏至我的研究室書目清單書目收藏:0
本研究使用微波加熱器輔助進行自由基聚合反應,合成出具有還原與分散貴金屬奈米粒子之特性之高分子。實驗以苯乙烯(Styrene)及聚異丙基丙烯醯胺(NIPAAm)為單體,進行自由基聚合反應製備高分子,合成出之寡分子具有硫酸根基團(SO42-),不需額外添加還原劑與分散劑的情況下自身還原(self-reduction)出貴金屬奈米粒子並均勻分散至溶液中。本研究探討改變反應試劑苯乙烯與聚異丙基丙烯醯胺之比例、微波功率、微波時間等條件之效應。實驗的結果利用FT-IR、NMR、GPC、XRD、SEM、TEM、LUM分析其性質。依實驗結果證實使用微波加熱可大幅減少聚合時間,且此方式製作之鈀金屬觸媒墨水相較於傳統方式合成之鈀金屬觸媒墨水,具有相同之觸媒特性,如反應活性、穩定性、附著力。可將此奈米粒子應用於噴墨列印,於基材上製備設計之金屬導線。
A novel method, microwave irradiation synthesis, is proposed for the preparation of thermo-sensitive poly(St-co-NIPAAm) which can be used for the production of ink-jet printing ink. This study is about changing the microwave work and the microwave
time. The copolymer is synthesized from the monomer Styrene and N-isopropyl-
acrylamide. It has Sulfate group(SO42-) that can induce redox reaction with the noblemetallic particles. The use of microwave irradiation can greatly shorten the reaction time required for oligomer synthesis, say, from several hours to several minutes, in comparison with the water-bath heating method. Chemical groups, surface morphologies and particle sizes of the polymer-metal nanocomposites werecharacterized by FT-IR, NMR, LUM, SEM and TEM. The synthesized water-basednanocomposites used as ink solutions were directly printed onto various substratesurfaces, and followed by a typical electroless plating technique to form metallic wires.

誌謝 ii
摘要 iii
Abstact iv
目錄 v
圖目錄 vii
表目錄 x
1.前言 1
2.文獻回顧 3
2.1 微波基本原理與特性 3
2.2 智慧高分子 7
2.3 噴墨印刷技術 10
2.4無電電鍍技術 17
2.5 研究動機 19
3.實驗 20
3.1實驗藥品 20
3.2 實驗設備 21
3.3 實驗分析儀器及其測量原理 22
3.4 實驗流程 31
3.4.1 傳統加熱法製備溫敏型共聚物 31
3.4.2 微波加熱法製備溫敏型共聚物 31
3.4.3 製備溫度敏感性奈米貴金屬鈀觸媒 34
3.4.4噴墨列印輸出圖形 35
3.4.5金屬化處理 39
4.結果與討論 40
4.1溫度敏感性共聚物之合成與檢測 40
4.1.1微波參數探討 40
4.1.2傳統法與微波法製備之溫敏性共聚物性質分析 43
4.2溫度敏感型觸媒粒徑及分散性比較 51
4.3結合噴墨列印技術製備金屬化圖型 58
5.結論 65
6.參考文獻 66
自傳 73


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