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研究生:鄭婷尹
研究生(外文):Ting-YinCheng
論文名稱:三價鑭系金屬配位聚合物的合成、結構鑑定與磁性行為
論文名稱(外文):Syntheses, Crystal Structures and Magnetic Properties of Lanthanide-Based Coordination Polymers
指導教授:許桂芳
指導教授(外文):Kuei-Fang Hsu
學位類別:碩士
校院名稱:國立成功大學
系所名稱:化學系碩博士班
學門:自然科學學門
學類:化學學類
論文種類:學術論文
論文出版年:2012
畢業學年度:100
語文別:中文
論文頁數:99
中文關鍵詞:水熱/溶劑熱法鑭金屬有機配位聚合物
外文關鍵詞:solvothermallanthanide
相關次數:
  • 被引用被引用:0
  • 點閱點閱:113
  • 評分評分:
  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
利用水熱/溶劑熱法,我們成功的合成出一系列鑭金屬有機配位聚合物。我們實驗得到五個新穎的鑭系金屬化合物。化合物先經由X-光單晶繞射儀鑑定出它們的結構,接著由元素分析儀與X-光粉末繞射儀確定化合物純度,再以紅外線光譜儀分析特定官能基,最後利用超導磁性量子干涉儀探討其磁性行為。
Five new lanthanide coordination polymers have been prepared under the mild solvothermal conditions.The five compounds belong to two new three-dimensional (3D) structural groups.The assembly of heterometallic 3d-4f ions and organic ligands, have successfully constructed two series of metal-organic frameworks. Single-crystal structures, elemental analyses, Infrared records, and magnetic behavior were characterized for these compounds.
摘要 I
Abstract IV
致謝 V
目錄 VI
圖目錄 VIII
表目錄 X
第一章 緒論 1
1.1 研究動機 1
1.2 鑭系金屬磁性研究發展 2
1.3 研究目標與成果 8
第二章 化合物1-3之合成、鑑定與結果討論 9
2.1 合成條件 12
2.2 單晶X光繞射分析 (Single Crystal X-ray Diffraction Analysis) 15
2.3 結果與討論 18
2.3.1晶體結構解析 19
2.3.2 粉末X光繞射分析 (Powder X-ray Diffraction Analysis)與熱重/熱差分析(Differential Thermal/ Thermogravimetric Analysis, DT/TGA) 31
2.3.3 磁性測量與討論 36
第三章 化合物4-5之合成、鑑定與討論 46
3.1 合成條件 47
3.2 單晶X光繞射分析 (Single Crystal X-ray Diffraction Analysis) 49
3.3 結果與討論 51
3.3.1晶體結構解析 51
3.3.2 粉末X光繞射分析 (Powder X-ray Diffraction Analysis) 62
3.3.3 磁性測量與討論 63
第四章 結論 66
參考文獻 68
附錄 71


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