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研究生:陳佳鋒
研究生(外文):Jia-Fong Chen
論文名稱:以氧化水熱法製備二氧化鈦之研究
論文名稱(外文):Study of Titanium Dioxide Prepared by Oxidation-Hydrothermal Method
指導教授:林育賢林育賢引用關係
指導教授(外文):Yu-Shyan Lin
學位類別:碩士
校院名稱:國立東華大學
系所名稱:材料科學與工程學系
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:2012
畢業學年度:100
語文別:中文
論文頁數:101
中文關鍵詞:氧化水熱法二氧化鈦
外文關鍵詞:Oxidation-hydrothermal methodTitanium dioxide
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本實驗是使用氧化水熱法將鈦金屬板浸置在不同溫度的過氧化氫溶液,並控制反應時間和熱處理溫度來製備具有多孔性結構的TiO2。並期待應用在染劑敏化太陽能電池上。
首先我們設定各種參數條件去成長擁有奈米尺度的多孔性TiO2,利用掃描式電子顯微鏡、場發射掃描式電子顯微鏡、X-ray 繞射分析儀、及顯微拉曼光譜儀等儀器分析在不同參數底下TiO2 表面形貌與結構,取各參數條件下分析之結果,並探討此分析結果之原因。
In this thesis, titanium dioxide were prepared by oxidation-hydrothermal method that titanium plate immersed in various temperature hydrogen peroxide (H2O2) solution and controlled reaction time and heat treating temperature .The prepared porous titanium dioxide were applied for the photoanodes of dye-sensitized solar cell (DSSC) .
First, we set various parameter conditions to grow nanostructured titanium dioxide, then analyze titanium dioxide surface and microstructure by Scanning Electron Microscopy (SEM)、 Field Emission Scanning Electron Microscopy (FE-SEM) 、Micro-Raman spectroscopy 、X-Ray
Diffraction (XRD), then get analyze results of each parameter conditions and discuss the reasons of causing such analyze results.
摘要 I
Abstract III
目錄 V
表目錄 VII
圖目錄 VIII
第一章 緒論 1
1-1前言 1
1-2太陽能電池簡介 2
1-3染料敏化太陽能電池 4
1-3-1 染料敏化太陽能電池發展過程 4
1-3-2 染料敏化太陽能電池結構介紹與工作原理 5
1-3-3影響染料敏化太陽能電池光電轉換效率之因素 6
1-3-4 染料敏化太陽能電池之工作電極 7
1-3-5 氧化水熱法 (Oxidation-hydrothermal method) 11
1-4二氧化鈦的基本性質介紹 11
第二章 實驗方法與製備過程 15
2-1 儀器設備 15
2-2 藥品耗材 15
2-3 二氧化鈦製備 16
2-3-1 實驗設備 17
2-4 儀器介紹 18
2-4-1 掃瞄式電子顯微鏡 (Scanning Electron Microscope, SEM) 18
2-4-2 場發射掃描式電子顯微鏡 (Field Emission-Scanning Electron Microscopy ) 19
2-4-3 顯微拉曼光譜儀 (Micro-Raman Spectroscopy) 20
2-4-4 X光繞射分析儀 (X-Ray Diffraction, XRD ) 20
第三章 實驗結果與討論 23
3-1 掃描式電子顯微鏡分析 23
3-2 顯微拉曼光譜儀分析 25
3-3 X-ray繞射分析 26
第四章 結論及未來工作 27
參考文獻 29
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