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研究生:蔡佳吟
研究生(外文):Cai, Jia-Yin
論文名稱:銀錫及銅錫焊料中鈦添加量對不鏽鋼及玻璃接合機構與機械性質影響
論文名稱(外文):Effect of Ti Additive of Ag-Sn and Cu-Sn Fillers on Phase Formation Mechanism and Mechanical Properties for Stainless Steel/Glass Joint
指導教授:林健正林健正引用關係
指導教授(外文):Lin, Chien-Cheng
學位類別:碩士
校院名稱:國立交通大學
系所名稱:照明與能源光電研究所
學門:工程學門
學類:綜合工程學類
論文種類:學術論文
論文出版年:2013
畢業學年度:101
語文別:中文
論文頁數:78
中文關鍵詞:接合焊料
外文關鍵詞:Tijointfiller
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本研究主要是利用自備金屬焊料Ag-Sn-Ti及Cu-Sn-Ti在750°C下持溫1小時接合304不鏽鋼及Pyrex玻璃,運用於太陽能熱水器真空集熱管。並對接合後的試片利用SEM(EDS)對介面微觀結構分析及利用剪應力與氦氣測漏儀分析其機械性質。
利用Ag-Sn-Ti接合後焊料內部皆以Ag3Sn及Sn(O)相為主,沒有添加Ti時,不鏽鋼側及玻璃兩側皆沒有反應層產生。添加Ti後則產生Ti6Sn5及Ti2Sn3的相,且與不鏽鋼中的Fe反應形成Fe2TiSn相;以及部分Sn固溶入不鏽鋼基材中形成FeSn2相。利用Cu-Sn-Ti接合後焊料內部已Cu6Sn5、Cu3Sn及Sn(O)相為主,沒有添加Ti時焊料與不鏽鋼及玻璃兩側皆沒有反應層產生。添加Ti後,焊料中Ti、Sn與Fe反應形成Fe2TiSn相,在不鏽鋼側介面處也形成Fe2TiSn反應層;此外Cu、Sn固溶入不鏽鋼內形成FeCu2Sn。
對試片剪應力分析,根據ISO_13124:201122的測試標準量測結果19Ag-76Sn-5Ti、18Ag-72Sn-10Ti、19Cu-76Sn-5Ti及18Cu-72Sn-10Ti接合之試片皆斷裂在玻璃側,其最大應力平均值分別為4.89MPa、4.31MPa、3.50MPa及2.60MPa。再利用氦氣測漏儀量測期氣密性後,Ag-Sn-Ti系統中可發現添加5%Ti的氣密性為1.1×10-4 mbar•1/s較添加10%Ti的氣密性1.2×10-8 mbar•1/s來的差,可判斷出Ag-Sn-Ti系統中Fe2TiSn相的量對接合效果之影響。Cu-Sn-Ti系統中添加5%Ti的氣密性為4.6×10-5mbar•1/s 較添加10%Ti的氣密性3.3×10-7mbar•1/s 來的差。可判斷出在Cu-Sn-Ti系統中Fe2TiSn相的量及反應層厚度增加可使氣密性效果更為良好。


Joining of 304 Stainless Steel with Pyrex Glass using Ag–Sn and Cu–Sn fillers was fabricated at 750°C for 1 hr. The microstructure of the joints were characterized using scanning electron microscopy (SEM). In addition, universal testing machine and Helium leakage tests were used to analyze the mechanical properties of the soldering specimens.
With no Ti addition into the Ag–Sn filler, the joint contained Ag3Sn and Sn(O) was observed between 304 Stainless steel and Pyrex glass. With adding 5%Ti and 10%Ti, respectiveily into the Ag–Sn filler, the joint comprised of Ag3Sn, Sn(O), Ti6Sn5, Ti2Sn3 and Fe2TiSn, indicating that Fe would diffuse into the Ag-Sn-Ti filler. The FeSn2 phase was also observed in the 304 Stainless steel. It was believed that the affinity of Fe-Sn was stronger than that of Fe-Ti.
With no Ti addition into the Cu–Sn filler, the primary joint contained Cu6Sn5, Cu3Sn and Sn(O) phases was observed between 304 Stainless steel and Pyrex glass. With adding 5%Ti and 10% Ti into the Cu–Sn filler, the morphology of Fe2TiSn could be a layer or globular, respectiveily, nearby the 304 stainless steel. Besides, the joint comprised of Cu6Sn5, Fe2TiSn and Sn(O) phases. A two-phase FeCu2Sn+ (Fe,Cr) was also found beyond the Fe2TiSn layer.
Duing the test of bonding strength, all specimens were broken in the Pyrex glass, indicating that the bonding between substrates were excellent. In Helium leakage tests, the steel/18Ag-72Sn-10Ti/glass joint (1.2×10-8 mbar•1/s) was better than the steel/19Ag-76Sn-5Ti/glass joint (1.1×10-4 mbar•1/s) because the amount of Fe2TiSn phase is increased in Ag-Sn-Ti filler. Additionally, it was also found that 10% Ti additive in the Cu-Sn-Ti filler presented a lower leaking rate (3.3×10-7mbar•1/s).

目錄
摘要 I
Abstract III
致謝 V
目錄 VI
表目錄 IX
圖目錄 X
Chapter1前言 1
Chapter2文獻回顧 3
2-1太陽能熱水器 3
2-1-1太陽能熱水器的簡介 3
2-2 Pyrex玻璃 5
2-3 304不鏽鋼 5
2-4 金屬與玻璃接合技術 6
2-5 真空氣密性量測技術 8
2-5-1 氦氣測漏儀原理及簡介 9
2-6 機械性質量測 10
Chapter3實驗步驟與方法 12
3-1 金屬粉末漿料製備 12
3-2 接合試片製備 13
3-3 SEM試片製備 13
3-4 微觀分析儀器 14
3-4-1掃描式電子顯微鏡(SEM/EDS) 14
3-4-2氦氣測漏儀 14
3-4-3 剪應力測試 15
Chapter 4 結果與討論 16
4-1 Ag-Sn-Ti金屬焊料接合玻璃/玻璃與玻璃/不鏽鋼之微觀結構 16
4-1-1 20Ag-80Sn金屬焊料接合玻璃/玻璃的微觀結構 16
4-1-2 20Ag-80Sn金屬焊料接合玻璃/不鏽鋼的微觀結構 16
4-1-3 19Ag-76Sn-5Ti金屬焊料接合玻璃/玻璃的微觀結構 17
4-1-4 19Ag-76Sn-5Ti金屬焊料接合玻璃/不鏽鋼的微觀結構 18
4-1-5 18Ag-72Sn-10Ti金屬焊料接合玻璃/玻璃的微觀結構 19
4-1-6 18Ag-72Sn10Ti金屬焊料接合玻璃/不鏽鋼的微觀結構 19
4-2 Cu-Sn-Ti金屬焊料接合玻璃/玻璃與玻璃/不鏽鋼之微觀結構 20
4-2-1 20Cu-80Sn金屬焊料接合玻璃/玻璃的微觀結構 20
4-2-2 20Cu-80Sn金屬焊料接合玻璃/不鏽鋼的微觀結構 21
4-2-3 19Cu-76Sn-5Ti金屬焊料接合玻璃/玻璃的微觀結構 22
4-2-4 19Cu-76Sn-5Ti金屬焊料接合玻璃/不鏽鋼後的微觀結構 22
4-2-5 18Cu-72Sn-10Ti金屬焊料接合玻璃/玻璃的微觀結構 23
4-2-6 18Cu-72Sn-10Ti金屬焊料接合玻璃/不鏽鋼的微觀結構 23
4-3 金屬焊料接合玻璃/玻璃與玻璃/不鏽鋼之生成機構 24
4-3-1 20Ag-80Sn金屬焊料接合玻璃/玻璃及玻璃/不鏽鋼生成機構 24
4-3-2 18Ag-72Sn-10Ti金屬焊料接合玻璃/玻璃及玻璃/不鏽鋼生成機構 25
4-3-3 20Cu-80Sn金屬焊料接合玻璃/玻璃及玻璃/不鏽鋼生成機構 26
4-3-4 18Cu-72Sn-10Ti金屬焊料接合玻璃/玻璃及玻璃/不鏽鋼生成機構 27
4-4 機械性質量測 28
4-4-1 剪應力量測 28
4-4-2 氣密性量測 29
Chapter5結論 32
References 35

1. 吳國光, 張育誠, “ 太陽能熱水器的優缺點剖析,” 能源報導, 33-36 (2010).
2. 許志雄,王木琴,許蕙如 “玻璃-排列不規則固體 ”,科學發展,406期, 6~13頁,2006年10月。
3. Hans Bach, Norbert Neuroth “Schott Technical Glasses Physical and technical properties.”(1998)
4. Mathews “A Corning executive gave the following account to Mitford M.”American Speech, Vol. 32, No. 4. p.290.(1957)
5. LLC “The History of Pyrex Glassware.”World Kitchen
6. 黃振賢,機械材料,文京圖書,民國79年
7. Zhang Li Shujie Li "Joining SiC-based materials to themselves and metals," Powder Metallurgy Technology. 22 [2] (2004)
8. 陳奕呈 "鈦-鎳-鈦箔層接合固態氧化物燃料電池中316L 不鏽鋼與釔安定氧化鋯之介面反應," 碩士論文,交通大學. (2010)
9. 劉承維 "鈦-鎳-鈦箔片接合碳化矽與Kovar之介面反應," 碩士論文,交通大學. (2011)
10. 顏怡文 蘇建瑋 "以銀銅鈦活性填料接合固態氧化物燃料電池不鏽鋼雙極板與鎳釔安定氧化鋯陶瓷陽極之介面反應與時效研究," 碩士論文,台灣科技大學. (2007)
11. 王亦翰 林志曄 馬廣仁教授“散熱器-銅之擴散接合研究 ”
12. 張銀祐 "真空系統與真空技術," 明道大學. (2010)
13. Yiwang Bao, Haibin Zhang and Yanchun Zhou "A simple method for measuring tensile and shear bond strength of ceramic-ceramic and metal-ceramic joining," Materials Research Innovations. 6 [5] 277-280 (2002)
14. 海寧四季旺太陽能工業有限公司 “分體平板式太陽能熱水器(SJK-2000/1000/82-FPCA)”
15. 張克勤, 鐘光民,李清安 “成功的再生能源運用-太陽能熱水器,”科學發展.446(2012)
16. 深圳東方太陽能科技有限公司 “全玻璃真空管太陽能熱水器”
17. 陳明君 “太陽熱能產業發展新趨勢,”工業技術研究院(2008)
18. 神態太陽能有限公司 “承壓式太陽能入水氣”
19. 常州美迪克能源科技有限公司 "納米技術太陽能真空集熱管”
20. 生科環境 “真空太陽能集熱管是怎樣運作”
21. "Fine ceramics (advanced ceramics, advanced technical ceramics) — Test method for interfacial bond strength of ceramic materials," ISO 13124:2011(E).
22. 林晁賢 “銀基金屬薄片接合固態氧化燃料電池中氧化鋯與不鏽鋼之介面微觀結構分析”碩士論文, 交通大學(2012)
23. United States Patent, No.5120374, Jun, 9, 1992
24. Donald R. Askeland "The science and engineering of materials 4th edition," Thomson learning Inc., 232-250. 19 (2005)
25. The Landolt-Börnstein Database , 2 Binary Systems:Ag-Sn.
26. Fucheng Yin, Jean-Claude Tedenac, Franck Gascoin “thermodynamic assessment of the Sn-Ti system , monatshefte fur chemie chemical monthly” Computer Coupling of Phase Diagrams and Thermochemistry 31, 370–379 (2007)
27. V. Vuorinen • H. Q. Dong • T. Laurila “Effect of Ti on the interfacial reaction between Sn and Cu” Mater Electron 23:68–74(2012)
28. A. M. Molodets, S. S. Nabatov “Thermodynamic Potentials, Diagram of State, and Phase Transitions of Tin on Shock Compression” High Temperature, Volume 38, Issue 5, pp 715-721 ,September–October 2000
29. 蔡映麟 “鉛錫系無鉛銲錫合金之熱物性質研究”博士論文,成功大學(2004)
30. The Landolt-Börnstein Database , 2 Binary Systems:Ti-Sn.
31. Y. G. Lee and J. G. Duh“ Phase Analysis in the Solder Joint of Sn-Cu Solder/IMCs/Cu Substrate” Materials Characterization Volume 42, Issues 2–3, 3 February 1999, Pages 143–160
32. D.R. Flnders, E.G. Jacobs, and R.F. Pinizzotto “Activation Energies of Intermetallic Growth of Sn-Ag Eutectic Solder on Copper Substrates.”Journal of Electronic Materials, Volume 26, Issue 7, 883-887, July 1997
33. Takao Kozakai, Tomokazu Moritani and Minoru Doi ” Formation of Ti2FeSn Compound and Phase Equilibria at the Ti-Fe Side of Ti-Fe-Sn Ternary System”
34. Kejun Zeng,Roger Stierman, Tz-Cheng Chiu, and Darvin Edwards “Kirkendall void formation in eutectic SnPb solder joints on bare Cu and its effect on joint reliability” Journal of Applied Physics 97, 024508 (2005)
35. K. Zapfe "LEAK DETECTION," Deutsches Elektronen-Synchrotron DESY, Hamburg, Germany. (2007)
36. Wang Wei Li, Zhang Xiao Mei, Li Liu Hui &; Wei Bing Bo “Dual solidification mechanisms of liquid ternary Fe-Cu-Sn alloy” SCIENCE CHINA
37. V. Raghavan “Cu-Fe-Sn (Copper-Iron-Tin)” Journal of Phase Equilibria and Diffusion Vol. 30 No. 4 2009
38. 李秋雯”軋延銅箔-錫界面之反應行為研究”碩士論文, 成功大學(2007)

39. T.B. Massalaki, “Binary Alloy Phase Diagrams”,Willoam W.Scott, Vol, pp.965(1986)

40. Frederick N. Rhines, Ph.D. “Phase Diagrams in Metallurgy Their Development and Application” 85-86

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