本研究利用化學誘發相分離法製備具有孔洞互穿結構的環氧樹脂薄膜，實驗中以雙酚A型的環氧樹脂(D.E.R.331)溶入二異丁酮(diisobutyl ketone, DIBK)中，利用2,4,6-三(二甲胺基甲基)苯酚(2,4,6-tris-(dimethylaminomethyl)phenol, DMP-30)作為硬化劑，於硬化反應的過程中，誘發高分子與溶劑溶解度下降而引發相分離，再將溶劑去除以製備出多孔性高分子薄膜，即為化學誘發相分離法(CIPS)。由機械性質分析中得知，多孔性環氧樹脂鋰電解質隔離膜之壓縮彈性模數為0.1至0.7GPa。再將形成網狀結構的環氧樹脂高分子薄膜進行膨潤度測試，將其浸泡不同濃度之過氯酸鋰電解液，膨潤度約介在2至59 %之間，取決於環氧樹脂薄膜的交聯型態。以1M過氯酸鋰之Ethylene carbonate (EC)/ Propylene carbonate (PC)/ Diethyl carbonate (DEC)製備出環氧樹脂鋰電解質薄膜之鋰離子導電度可達1.5 x10-2 S/cm (20℃)，且可達5.3x10-2 S/cm (70℃)。

Porous epoxy networks were prepared from epoxy resin, D.E.R. 331, cured with tertiary amine: 2,4,6-tris-(dimethylaminomethyl) phenol (DMP-30), in the diisobutyl ketone (DIBK). After removing the solvent, epoxy thermosets with interconnected channels can be formed via chemical induced phase separation, CIPS. It was found that the compression modulus of the epoxy membranes was about 0.7~2.0 GPa. The epoxy networks were further impregnated with different lithium ionic electrolyte liquids. The swelling ratio of epoxy resin membranes was from 2% to 59%, which was majorly dependent on the morphology of the epoxy networks. The lithium ionic conductivity of the epoxy electrolyte membranes prepared in the mixture of lithium perchlorate with ethylene carbonate (EC), propylene carbonate (PC) and diethyl carbonate (DEC) could reach 1.5 x10-2 S/cm at 20℃, and 5.3x10-2 S/cm at 70℃.

目 錄

摘要 i
ABSTRACT ii
誌謝 iii
目錄 v
表目錄 viii
圖目錄 xi
第一章 緒論 1
1.1前言 1
1.2研究動機與目的 2
第二章 相關理論與文獻回顧 4
2.1 環氧樹脂之簡介 4
2.2 薄膜之簡介 6
2.3 高分子薄膜結構之分類 7
2.4 高分子薄膜之製備 9
2.5 高分子溶液熱力學平衡 11
2.6 Flory-Huggins theory 12
2.7 相分離過程的形式和命名 13
2.7.1 化學誘發相分離（CIPS） 13
2.7.1.1 化學誘發相分離應用於製備多孔性薄膜 15
2.8 高分子離子活化能 16
2.9 含氟高分子 17
2.10 化學誘發相分離法之相關文獻 18
2.11 三級胺催化環氧樹脂之相關文獻 24
2.12 薄膜添加電解液(鹽類是LiClO4)之相關文獻 26
第三章 實驗方法 30
3.1 實驗藥品 30
3.2 實驗儀器 34
3.3 實驗流程及步驟 37
3.3.1 實驗流程 37
3.3.2 高分子薄膜之合成 38
3.4 高分子電解液膨潤(率)作用 41
3.5 傅立葉式紅外線吸收光譜儀(FT-IR) 42
3.6 掃瞄式電子顯微鏡(SEM) 43
3.7 熱重分析儀(TGA) 46
3.8 微分掃描熱卡計(DSC) 46
3.9 離子導電度之量測 46
3.10 壓力彈性鬆弛測定儀 48
第四章 結果與討論 49
4.1 聚合反應程度之評估 49
4.2 薄膜型態之探討 50
4.2.1 薄膜內部之型態 50
4.2.2 薄膜表面之型態 51
4.3 薄膜之膨潤程度分析 53
4.4 濕薄膜之熱性質分析 58
4.5 濕薄膜之導電性質分析 61
4.6 計算離子活化能 65
4.7 濕薄膜之機械性質分析 67
4.8 濕薄膜之M及F系列比較 68
4.9 高氧化穩定性鋰鹽之探討 68
4.10 電解液配方對鋰離子之影響 69
第五章 結論 96
未來工作 97
符號說明 98
參考文獻 99
附錄 108
附錄A M-24~M-40(FM-28~FM-40)之成膜形貌 108
附錄B 環氧樹脂薄膜M與F系列之SEM圖 109
附錄C 環氧樹脂M及F系列薄膜表面及截面孔徑尺寸分佈 113
附錄D 環氧樹脂M及F系列薄膜浸泡1.0M LiClO4/EC/PC(1:1)及1.0M LiClO4/EC/PC/DEC(1:2:2)在不同溫度變化之離子導電度比較圖 115

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