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研究生:江亞承
研究生(外文):Ya-Cheng Jiang
論文名稱:低溫型三元系熔融鹽電解沉積鍍鉬之研究
論文名稱(外文):The study of electrodeposited Molybdenum from low temperature molten salt of DMSO2-ZnCl2-MoCl5
指導教授:楊肇政楊肇政引用關係
指導教授(外文):Chao-Chen Yang
學位類別:碩士
校院名稱:國立雲林科技大學
系所名稱:化學工程與材料工程系碩士班
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:2013
畢業學年度:101
語文別:中文
論文頁數:135
中文關鍵詞:熔融鹽低溫型電解沉積氯化鋅五氯化鉬二甲基砜
外文關鍵詞:MoCl5ZnClDMSO2electrodepositionMolybdenummolten saltlow temperature
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本研究係以探討低溫型三元系DMSO2-ZnCl2-MoCl5融熔鹽電解質浴以不同電解型式電解鍍鉬,以製備具耐腐蝕性之含鉬鍍層為目的。本實驗所選用之工作電極為SS304不鏽鋼、參考電極為Zn/ZnCl2、對極為金屬鉬圓柱。
In this study, the low temperature ternary (DMSO2-ZnCl2-MoCl5) molten salt system for electrodepositing Mo by different electrolytic types was selected in order to obtain Mo layer which can resist corrosion as purpose.
一、 緒論 1
1.1 前言 1
1.2 電化學系統 3
1.3 電化學之相關參數說明 5
1.4 熔融鹽之定義 7
1.5 熔融鹽之電化學行為 13
1.6 循環伏安法(Cycle voltammetry) 15
1.7 熔融鹽輸送性質探討 17
1.8 耐腐蝕測試-塔弗極化曲線 20
1.9 研究動機與目的 26
二、 文獻回顧 27
2.1 不鏽鋼表面處理技術 27
2.2 定電流電鍍與定電位電鍍 31
2.3 脈衝電鍍 (plused electrodeposition) 32
2.4 金屬沉積機構 (mechanism of metal deposition) 34
2.5 鹽浴組成(DMSO2-ZnCl2) 38
2.6 電解沉積鉬之技術發展 42
三、 實驗方法與步驟 53
3.1 實驗藥品與設備 53
3.2 實驗架構 57
四、 結果與討論 69
4.1 三元系(DMSO2-ZnCl2-MoCl5)熔融鹽輸送性質 69
4.2 不同電解型式之電解沉積鉬鍍層 79
4.3 三元系(DMSO2-ZnCl2-MoCl5)熔融鹽鍍鉬層厚度分析 110
4.4 耐腐蝕測試-塔弗極化曲線 118
四、 結論 124
五、 未來展望 131
六、 參考文獻 130
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