本研究將親水性二氧化矽，利用溶膠凝膠法，將表面改質形成三甲基矽氧烷，製備成疏水性奈米二氧化矽，並將之摻混於含氟丙烯酸酯等油相單體中，藉由奈米二氧化矽製造粗糙度，氟提供薄膜低表面自由能，形成蓮花效應之表面結構，製備具有疏水性、疏油性的含氟丙烯酸系列奈米複材薄膜。利用FT-IR、1H-NMR鑑定奈米二氧化矽結構；並探討變因於摻混二氧化矽含量多寡及稀釋成不同的濃度，藉由高速旋轉塗佈，將所製備出薄膜測試其親疏水性質、可見光穿透率以及薄膜表面性質、粗糙度、耐熱性鑑定。

In this study, the fluoroacrylate nanocomposite films with super hydro-oleophobic property will be prepared by importing fluorocarbon functional group into the side chain of acrylic ester. These modified copolymers maintain the acrylate characteristics, and effectively improve the chemical resistance, weather resistance, stain resistance, and hydro-oleophobic property. Besides, hydrophobic silica will be prepared by modifying different nanoparticles of silica with silane coupling agent. This hydrophobic silica will then be mixed uniformly with fluoroacrylate monomers to increase the surface roughness, and to prepare the super-hydrophobic, oleophobic, and self-cleaning film.

中文摘要------------------------------------------------------------------------I
英文摘要-----------------------------------------------------------------------II
目錄-------------------------------------------------------------------------III
表目錄--------------------------------------------------------------------------V
圖目錄------------------------------------------------------------------------VII
第一章 前言---------------------------------------------------------------------1
第二章 理論及文獻回顧-------------------------------------------------------------3
2-1 蓮花效應簡介-----------------------------------------------------------------3
2-2 氟碳樹脂簡介-----------------------------------------------------------------4
2-3 接觸角之物理意義--------------------------------------------------------------8
2-4 溶膠凝膠法簡介--------------------------------------------------------------11
2-5 二氧化矽改質----------------------------------------------------------------12
2-5.1 表面物理改質方法-----------------------------------------------------------12
2-5.2 表面化學改質方法-----------------------------------------------------------12
2-5.3 改質劑-------------------------------------------------------------------13
2-6 疏水性薄膜製備方法與文獻探討---------------------------------------------------15
第三章 實驗方法與分析設備---------------------------------------------------------36
3-1實驗材料及藥品---------------------------------------------------------------36
3-2 實驗設備-------------------------------------------------------------------39
3-3 實驗步驟-------------------------------------------------------------------40
3-3.1 疏水性二氧化矽之製備-------------------------------------------------------40
3-3.2 疏水性二氧化矽之製備流程圖--------------------------------------------------42
3-3.3 含氟丙烯酸酯疏水薄膜之製備--------------------------------------------------43
3-3.4 含氟丙烯酸酯疏水薄膜之製備流程圖---------------------------------------------45
3-4實驗測試項目-----------------------------------------------------------------46
3-4.1接觸角量測----------------------------------------------------------------46
3-4.2透光度測試----------------------------------------------------------------46
3-4.3粒徑分析儀測試-------------------------------------------------------------46
3-4.4 FTIR測試----------------------------------------------------------------46
3-4.5 1H-NMR測試--------------------------------------------------------------47
3-4.6 EDX分析-----------------------------------------------------------------47
3-4.7 AFM分析-----------------------------------------------------------------47
3-4.8 TGA分析-----------------------------------------------------------------47
第四章 實驗結果與討論------------------------------------------------------------48
4-1 紅外光譜儀FT-IR分析---------------------------------------------------------49
4-2 1H-NMR實驗結果-------------------------------------------------------------51
4-3 粒徑分佈測試----------------------------------------------------------------55
4-4 EDX分析-------------------------------------------------------------------60
4-5 可見光穿透度實驗結果---------------------------------------------------------62
4-6 接觸角實驗結果--------------------------------------------------------------68
4-7 TGA分析-------------------------------------------------------------------76
4-8 AFM分析-------------------------------------------------------------------78
4-9 SEM分析-------------------------------------------------------------------83
第五章 結論--------------------------------------------------------------------84
參考文獻-----------------------------------------------------------------------86

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