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研究生:蕭宏民
研究生(外文):Hung-Min Hsiao
論文名稱:製備碘化二氧化鈦固定式觸媒光降解水中雙酚A之研究
論文名稱(外文):Preparation of Granular Catalysts with Iodine Doped Titanium Dioxide to Photodegrade Aqueous Bisphenol A
指導教授:郭昭吟郭昭吟引用關係
指導教授(外文):Chao-Yin Kuo
口試委員:郭昭吟席行正賴進興曾若鳴
口試委員(外文):Chao-Yin KuoHsing-Cheng HsiChin-Hsing LaiJo-Ming Tseng
口試日期:2014-06-03
學位類別:碩士
校院名稱:國立雲林科技大學
系所名稱:環境與安全衛生工程系
學門:工程學門
學類:環境工程學類
論文種類:學術論文
論文出版年:2014
畢業學年度:102
語文別:中文
論文頁數:123
中文關鍵詞:碘化二氧化鈦固定化雙酚A太陽光
外文關鍵詞:Iodine doped titanium dioxideImmobilizationBisphenol ASunlight
相關次數:
  • 被引用被引用:1
  • 點閱點閱:290
  • 評分評分:
  • 下載下載:12
  • 收藏至我的研究室書目清單書目收藏:0
本研究製備不同碘添加莫耳比之碘化二氧化鈦(0.1 IT、0.25 IT、0.5 IT、0.75 IT、1.0 IT)固定式光觸媒,結合連續流之管柱反應器,探討不同光源下對雙酚A光催化降解之效果。碘化二氧化鈦之物化特性分析藉由電子顯微鏡、X光繞射光譜儀、吸收波長分析以及官能基鑑定,顯示製備碘化二氧化鈦之基本特性用以推估反應機制。於人工光源之紫外光(365 nm)及可見光(410 nm)光催化實驗結果顯示,碘化二氧化鈦(I/Ti 莫耳比為0.5%, 0.5 IT)之雙酚A去除率分別為99.7及86%,皆優於原二氧化鈦觸媒。其中0.5 IT觸媒於中午(上午11:30 – 12:37)太陽光下之光催化去除效果可達100%,顯示碘化二氧化鈦觸媒能有效利用太陽光之能量,進一步提升光催化之活性。在碘化二氧化鈦觸媒之反應機制推導發現,觸媒添加碘能夠使其作為電子接受者,抑制電子及電洞之重組,達到提升光催化活性之佐證。此外,研究也進行了觸媒十重複實驗,結果顯示0.5 IT觸媒於人工光源或太陽光下,皆維持良好之去除效果,具有重複再利用之可行性。
A high photoactivity of iodine doped titanium dioxide (I-doped TiO2) photocatalysts was synthesized to degrade aqueous bisphenol A (BPA) under visible light(410 nm), ultraviolet light(365 nm) and sunlight has been investigated. The prepared I-doped TiO2 were characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD), UV-visible absorption spectroscopy, and Fourier transform infrared(FTIR) to indicate the mechanism of reaction. The degradation effect of aqueous BPA using I-doped titanium dioxide (I/T = 0.5 mole %) were 86 and 99.7 % under two irradiations of visible and UV light. Similarly, the effects of degradation BPA was 100% under sunlight irradiation. I doped TiO2 with surface dominant I–O–I and I–O–Ti structures, and that act as a electron scavenger capable of inhibiting the rapid recombination of electron–hole pairs. The Recycling test was maintained effectively after ten repeated experiments, which indicate the stability and reusability.
中文摘要 i
ABSTRACT ii
目錄 iii
圖目錄 vii
表目錄 x
第一章 緒論 1
1-1 研究源起 1
1-2 研究目的 2
1-3 研究流程 3
第二章 文獻回顧 4
2-1 環境荷爾蒙 4
2-1-1 環境荷爾蒙概述 4
2-1-2 雙酚A概論 6
2-1-3 雙酚A生物毒性研究之相關文獻 10
2-1-4 雙酚A處理技術相關研究 11
2-2 光催化反應 13
2-2-1 二氧化鈦光觸媒 13
2-2-2 光催化反應概述 16
2-2-3 改質光觸媒相關文獻 17
2-2-3-1碘化物改質之二氧化鈦相關文獻 17
2-2-3-2 含其他非金屬元素之二氧化鈦相關文獻 20
2-2-3-3 固定式光觸媒之相關文獻 23
第三章 實驗材料與方法 26
3-1 實驗架構 26
3-2 實驗藥品與設備 27
3-2-1 光催化反應裝置 27
3-2-2 實驗藥品 28
3-2-3 實驗儀器 29
3-3 實驗分析 32
3-3-1 光觸媒物性分析 32
3-3-2 水樣分析儀器 37
3-4 實驗方法 39
3-4-1 IT固定式光觸媒製備 39
3-4-2 光催化反應實驗 41
3-4-2-1 背景實驗 41
3-4-2-2 光催化實驗 45
3-5 樣品檢測之品保與品管(QA/QC) 51
3-5-1 檢量線製備 51
3-5-2 品質管制圖建立 52
3-5-3 方法偵測極限 54
第四章 結果與討論 56
4-1 光觸媒物性特性分析 56
4-1-1 光觸媒表面影像拍攝之SEM分析 56
4-1-2 光觸媒晶相結構鑑定XRD分析 58
4-1-3 光觸媒吸收波長及能隙之UV-Visible分析 61
4-1-4 光觸媒之表面官能基鑑定FTIR圖 64
4-2 背景實驗 66
4-2-1 光觸媒暗吸附實驗 66
4-2-2 雙酚A直接光解實驗 67
4-3 光催化實驗 68
4-3-1紫外光照射之光催化實驗 68
4-3-2可見光照射之光催化實驗 69
4-3-3不同人工光源之光催化效果 70
4-3-4太陽光照射之光催化實驗 71
4-4反應速率常數推估 74
4-4-1 擬一階反應模式模擬 74
4-4-2 擬二階反應模式模擬 78
4-5 長時間礦化實驗 82
4-5-1 紫外光照射之礦化實驗 82
4-5-2 可見光照射之礦化實驗 84
4-5-3 太陽光照射之礦化實驗 85
4-6 十重複耐久性實驗 87
4-6-1 紫外光照射之十重複耐久性實驗 87
4-6-2 可見光照射之十重複耐久性實驗 88
4-6-3 太陽光照射之十二重複耐久性實驗 89
4-7 碘化二氧化鈦反應機制推估 90
第五章、結論與建議 93
5-1 結論 93
5-2 建議 94
參考文獻 95


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