臺灣博碩士論文加值系統

能力試驗係驗證一個特定測量過程的方法。能力試驗藉由實驗室間比對來判定各個實驗室執行特定試驗或檢測的能力，並監控實驗室的持續能力。粒料篩分析係用來評估粒徑分佈，以確定是否符合設計及生產控制需求，並驗證規格。本文採用ISO 13528所介紹的統計方法，以進行粒料篩分析試驗的數據分析。此外，根據實驗室在小於75 m含量、細度模數（Fineness Modulus，FM）、過篩率試驗項目分析結果，探討實驗室的能力試驗異常情況，比對參與實驗室的整體表現。
整體而言，在樣品均勻性檢查部分，檢查結果皆良好。至於在實驗室間能力試驗表現的比對部分，在小於75 m含量、細度模數、No. 200過篩率這三個試驗項目，參加實驗室異常的比例都較高。此外，其他試驗項目實驗室間Z值（z scores）異常的比例均大於實驗室內Z值異常的比例。

A proficiency test (PT) is simply a method to validate a particular measurement process. By interlaboratory comparisons, PT is used to determine the performance of individual laboratories for specific tests or measurements, and to monitor the continuing performance of laboratories. The sieve analysis of fine and coarse aggregates is used to assess the particle size distribution in order to determine compliance with design, production control requirements, and verification specifications. In this study, the statistical methods introduced by ISO 13528 were adopted in data analysis of proficiency testing for sieve analysis of fine and coarse aggregates. According to the analysis results in test items, such as ‘the amount of material finer than 75 μm’, ‘Fineness Modulus (FM)’ and ‘Percent passing No. 200’, the anomalies of proficiency testing were discussed, and the overall performance of the test items from participant laboratories were compared.
Overall, the examination results were fine in the homogeneity checks of samples. As for the interlaboratory comparison of proficiency testing performance, the anomaly proportions from participant laboratories were higher in the three test items (i.e. ‘the amount of material finer than 75 μm’, ‘FM’, and ‘Percent passing No. 200’). Moreover, the anomaly proportions of Z-score were higher among laboratories than those within individual laboratories.

摘要 ................................................................................................................................... I
Abstract ............................................................................................................................. II
目錄 ................................................................................................................................ III
表目錄 .............................................................................................................................. V
圖目錄 ............................................................................................................................ VI
第一章 緒論 .................................................................................................................... 1
1.1研究動機 ............................................................................................................ 1
1.2研究目的 ............................................................................................................ 2
1.3研究範圍 ............................................................................................................ 2
第二章 文獻回顧 ............................................................................................................ 4
2.1粒料種類與性質 ................................................................................................ 4
2.2能力試驗計畫 .................................................................................................... 9
2.3能力試驗執行機構認證規範 ........................................................................... 11
2.4能力試驗之統計方法 ...................................................................................... 12
2.4.1設定值之決定 ............................................................................................... 14
2.4.2表現統計量之計算 ....................................................................................... 15
2.4.3表現評估 ....................................................................................................... 17
第三章 試驗計畫 .......................................................................................................... 19
3.1能力試驗項目 .................................................................................................. 19
3.2計畫時程 .......................................................................................................... 19
3.3能力比對實驗室 .............................................................................................. 21
3.4樣品設計 .......................................................................................................... 24
3.5樣品來源及樣品製作方法 .............................................................................. 24
3.6均勻性試驗方法與規範 .................................................................................. 25
3.7樣品分送（傳遞） .......................................................................................... 26
3.8能力試驗測試時程 .......................................................................................... 26
3.9樣品均勻性測試結果 ...................................................................................... 26
3.10統計資料數據分析說明 ................................................................................ 31
第四章 參與實驗室整體表現 ...................................................................................... 32
4.1參與實驗室整體表現與摘要結果 .................................................................. 32
IV
4.2實驗室異常結果摘錄 ...................................................................................... 51
4.3實驗室異常結果說明 ...................................................................................... 53
4.4實驗室異常結果分析 ...................................................................................... 54
第五章 結論與建議 ...................................................................................................... 56
5.1結論 .................................................................................................................. 56
5.2建議 .................................................................................................................. 56
參考文獻 ........................................................................................................................ 58

1. ISO/IEC 17043: 2010符合性評鑑–能力試驗的一般要求，財團法人全國認證基金會。
2. ISO/IEC 17043 Conformity assessment — General requirements for proficiency testing, 2010.
3. Somayaji, S., Civil engineering materials, Prentice Hall, Upper Siddle River, New Jersey, 2001.
4. ASTM C125-15, Standard Terminology Relating to Concrete and Concrete Aggregates, ASTM International, West Conshohocken, PA, 2015.
5. ASTM D8-13b, Standard Terminology Relating to Materials for Roads and Pavements, ASTM International, West Conshohocken, PA, 2013.
6. 湯兆緯、陳冠宏、張朝順編譯，「土木材料」，高立圖書公司，民國91年9月出版。
7. ASTM C136/C136M-14, Standard Test Method for Sieve Analysis of Fine and Coarse Aggregates, ASTM International, West Conshohocken, PA, 2014.
8. ISO 13528 Statistical methods for use in proficiency testing by interlaboratory comparisons.
9. 林巧雲，「用在實驗室間比對的能力試驗的統計方法的研究-以鋼筋混凝土用鋼筋之能力試驗為例」，中華大學應用統計學系碩士論文，2011。
10. 蔡雅雯，「能力試驗在臨床實驗室的應用與發展」，輔英科技大學醫事技術系碩士論文，2010。
11. 廖光磊，「我國螺絲實驗室能力試驗之研究」，國立臺灣科技大學材料科技研究所碩士論文，2008。
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12. CNS 491 A3010，粒料內小於試驗篩75 m CNS 386材料含量試驗法。
13. ASTM C117-13, Standard Test Method for Materials Finer than 75-μm (No. 200) Sieve in Mineral Aggregates by Washing, ASTM International, West Conshohocken, PA, 2013.
14. AASHTO T 11, Materials Finer than No. 200 Sieve by Washing.
15. CNS 486 A3005，粗細粒料篩析法。
16. AASHTO T 27, Sieve Analysis of Fine and Coarse Aggregate.
17. CNS 10989 A3209，現場粒料樣品減量為試驗樣品取樣法。
18. ASTM D3665-12, Standard Practice for Random Sampling of Construction Materials, ASTM International, West Conshohocken, PA, 2012.