臺灣博碩士論文加值系統

本研究使用脫脂、鹼處理方式獲取稻殼纖維，並以處理完成之稻殼纖維為基材，吸附銀離子於稻殼纖維上，應用於水中抗菌。銀離子可以吸附在細菌的表面，穿透細胞膜進入細胞體內，與細菌體內蛋白酶中的巰氫基產生反應，造成蛋白質凝固，使細菌的蛋白酶因巰氫基的喪失而失去活性，進而影響細胞的分裂過程，使細胞喪失分裂增殖能力而死亡。研究結果顯示，稻殼纖維其離子交換容量為320±4 μmol/g ，且對銀離子的飽和吸附量為38.16 mg/g (353 μmol/g)，稻殼纖維在未吸附銀離子之前並無殺菌效果而在吸附銀離子之後，殺菌效果大幅提升。含銀量0.19 mg的0.005 g稻殼纖維兩小時內即可完全滅菌初始含菌量2.35×105 CFU/ml，效果顯著。

In this study, the rice husk fibers after defatting and base treatment were adopted as the base materials for adsorbing silver ions. Silver ions adsorbed on the surface of rice husk fibers could be released and penetrate the cell membranes of bacteria, making it loss of activity. The results show that rice husk fibers had ion exchange capacity of 320 ± 4 μmol/g and adsorbed silver ions amount of 38.16 mg/g (353μmol/g). After silver ion adsorption, the anti-bacterial activity of rice husk fibers was improved significantly. The amount of 0.19 mg silver ions on 0.005 g rice husk fibers could completely sterilize 20 ml of water with an initial bacterial count of 2.35×105 CFU/ml within two hours .

誌謝 ............................I
中文摘要 ............................II
英文摘要 ............................III
目次 ............................IV
表目次 ............................VI
圖目次 ............................VII
第一章 緒論 ....................1
第二章 文獻回顧 ....................3
2.1農業廢棄物吸附汙染物之文獻 ....3
2.2抗菌水處理 ....................3
2.3銀離子於水中抗菌之優點、應用與機制......8
2.4銀/複合抗菌材料之抗菌機制及應用.....9
第三章 實驗方法 ....................13
3.1實驗材料 ....................13
3.2分析儀器 ....................13
3.3稻殼纖維之製備....................14
3.3.1脫脂 ....................14
3.3.2鹼處理 ................... 14
3.4稻殼纖維定性之分析..................17
3.4.1官能基分析 ...................17
3.4.2比表面積分析 ...................17
3.4.3離子交換容量 ...................17
3.4.4 SEM分析.......................17
3.5批次銀離子吸附....................17
3.5.1批次吸附 ...................17
3.5.2銀離子定量 ...................18
3.5.3吸附等溫曲線...................18
3.6抗菌纖維之製備與定性分析...........18
3.6.1抗菌纖維之製備..................18
3.6.2 SEM分析.......................18
3.6.3 TEM分析.......................18
3.7抗菌實驗..........................18
3.7.1菌液培養........................18
3.7.2批次抗菌實驗 ....................20
第四章 結果與討論......................21
4.1稻殼纖維性質分析 ..............21
4.1.1官能基分析 ......................21
4.1.2比表面積分析與離子交換容量結果 ......21
4.2抗菌纖維性質分析.....................21
4.2.1抗菌纖維SEM分析結果................21
4.2.2抗菌纖維TEM分析結果 ..............21
4.3 批次吸附結果……………………………………………………………21
4.3.1 批次吸附曲線………………………………………………………21
4.3.2 吸附等溫曲線.....................21
4.4抗菌結果 .....................26
4.4.1纖維抗菌結果 .....................26
第五章 結論 .....................33
參考文獻 .............................34

1.宮欽浩, 製備含銀/銅廢棄物吸附材於水中滅菌應用, 碩士論文,國立中興大學化學工程學系 ,台中,台灣.(2014)


2.E. N. E. Qada, S. J. Allen, G. M. Walker, Adsorption of basic dyes from aqueous solution onto activated carbons, Chemical
Engineering Science , 135 (2008) 174.

3.U. Kumar, M. Bandyopadhyay, Sorption of cadmium from aqueous solution using pretreated rice husk, Bioresource Technology , 97 (2006) 104.

4.Z. Reddad, C. Gerente, Y. Andres, M. C. Ralet, J. F. Thibault, P. L. Cloirec, Ni(Ⅱ) and Cu(Ⅱ) binding properties of native and modified sugar beet pulp. Carbohydrate Polymers, 49 (2002) 23.

5.A. Saeed, M. W. Akhter, M. Iqbal, Removal and recovery of heavy metals from aqueous solution using papaya wood as a new biosorbent. Separation and Purification Technology, 45 (2005) 25.

6.B. H. Hameed, D. K. Mahmoud, A. L. Ahmad, Sorption of basic dye from aqueous solution by pomelo (Citrus grandis) peel in a batch system, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 316 (2008) 78.

7.M. T. Uddin, M. A. Islam, S. Mahmud, M. Rukanuzzaman, Adsorptive removal of methylene blue by tea waste, Journal of Hazardous Materials, 164 (2009) 53.

8.G. Annadurai, R. S. Juang, D. J. Lee, Use of cellulose-based wastes for adsorption of dyes from aqueous solutions, Journal of Hazardous Materials, B92 (2002) 263.

9.Y. S. Ho, W. T. Chiu, C. C. Wang, Regression analysis for the sorption isotherms of basic dyes on sugarcane dust, Bioresource Technology, 96 (2005) 1285.

10.M. A. M. Salleh, D. K. Mahmoud,W. A. W. A. Karim, A. Idris, Cationic and anionic dye adsorption by agricultural solid wastes : A comprehensive review, Desalination, 280 (2011) 1.

11.V. Vadivelan, K. V. Kumar, Equilibrium, kinetics, mechanism and process design for sorption of methylene blue onto rice husk, Journal of Colloid and Interface Science, 286 (2005) 90.

12.F. A. Pavan, A. C. Mazzocato, Y. Gushikem, Removal of methylene blue from aqueous solutions by adsorption using yellow passion fruit peel as adsorbent, Bioresource Technology, 99 (2008) 3162.

13.M. Dogan, H. Abak , M. Alkan, Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters, Journal of Hazardous Materials, 164 (2009) 172.

14.R. K. Xu, S. C. Xiao, J. H. Yuan, A. Z. Zhao, Adsorption of methyl violet from aqueous solutions by the biochars derived from crop residues, Bioresource Technology, 102 (2011) 10293.

15.V. M. Vucurovic R. N. Razmovski, M. N. Tekic, Methylene blue (cationic dye) adsorption onto sugar beet pulp: Equilibrium isotherm and kinetic studies, Journal of the Taiwan Institute of Chemical Engineers, 43 (2012) 108.

16.Nasernejad, T.E.Zedeh, B.B.Pour, M.Bygi, A.Zamani, Comparison for biosorption modeling of heavy metals Cr(III), Cu(II), Zn(II) adsorption from wastewater by carrot residues, Process Biochemistry , 40 (2005) 1319.

17.S.F. Montanher, E.A. Oliveira, M.C. Rollemberg, Removal of metal ions from aqueous solutions by sorption onto rice bran, Journal of Hazardous Materials, B117 (2005) 207.

18.H.B.Asberry, C.Y. Kuo, C.H.Gung, E.D.Conte, S.Y.Suen, Characterization of water bamboo husk biosorbents and their application in heavy metal ion trapping, Microchemical Journal ,113 (2014) 59

19.J.F.Li, Y.Huang, Y.Ding, Z.L.Yang, S.B.Li, X.S.Zhou, F.R.Fan, W.Zhang, Z.Y.Zhou, D.Y.Wu, B.Ren, Z.L.Wang, Z.Q.Tian, Shell-isolated nanoparticle-enhanced Raman spectroscopy, NATURE, 18 (2010) 464.

20.E. A .Bryant, G. P.Fulton, ,C. Budd, , Disinfection Alternatives for Safe Drink Water, Van Nostrand Reinhold, (1992).

21.Tchobanoglous, G. Burton (eds.) ,Wastewater Engineering: Treatment, Disposal and Reuse, McGraw-Hill, (1991).

22.G. J. Tortora, B. R. Funke, C. L. Case, Microbiology an Introduction, Pearson Benjamin Cummings, (2004).

23.楊雯涵,新型奈米銀殺菌濾材去除大腸桿菌之研究,碩士論文,私立逢甲大學環境工程與科學學系研究所,台中,台灣.(2012)

24.黃鈺茹, 黃登福,自來水中氯化消毒副產物之飲用安全性,自來水會刊, 第3期 (2007) 23.

25.A.D.Russell, D.Sc, F.R.C.Path, S.Pharm, W.B.Hugo, Antimicrobial activity and action of silver, Progress in Medicinal Chemistry, 351 (1994) 31.

26.S. Shrivastava, T. Bera, A. Roy, G. Singh, P. Ramachandrarao, D.Dash, ,Characterization of enhanced antibacterial effects of novel silver nanoparticles, Nanotechnol., 18 (2007) 1.

27.Y. S. E. Lin, R. D.Vidic, J. E. Stout, V. L.Yu, Legionella in water distribution systems, Journal of AWWA, 90 (1998) 112.

28.S.J.Park, Y.S.Jang, Preparation and characterization of activated carbon fibers supported with silver metal for antibacterial behavior, Journal of Colloid Interface science, 261 (2003) 238.

29.S. L. Percival, J. S. Knapp, R.. Edyvean, D. S. Wales , Biofilm development on stainless steel in mains water, Water Research , 32 (1998) 243.

30.S. Zhang, R. Fu, D. Wu, W. Xu, Q. Ye, Z. Chen, Preparation and characterization of antibacterial silver-dispersed activated carbon aerogels, Carbon, 42 (2004) 3029

31.T. Dang, D. Lam, S. Reid, E. Wang, Design of colloidal silver disinfection for a public swimming pool with solar heating, University of Guelph, Proceedings of the ENGG 3100: Design III projects, 23 (2007) 178.

32.G. McDonnell, A. D. Russell, Antiseptics and disinfectants: activity, action, and resistance, Clinical Microbiology Reviews, 12 (1999) 147.

33.H.Ortiz-Ibarra, N. Casillas, V. S. Maximiliano, B. S. Refugio, T.V. Wencel, D. C. Sergio, G. Salazar, Surface characterization of electrodeposited silver on activated carbon for bactericidal purposes, Journal of Colloid and Interface Science, 314 (2007) 562.

34.J.N. Cutler, N. Chen, D.T. Jiang, G.P. Demopoulos, Y. Jia and J.W. Rowson, The Nature of Arsenic in Uranium Mill Tailings by X-Ray Absorption Spectroscopy, Journal of Physics , 107 (2003) 337.

35.A.B.G. Lansdown, Silver I: its antibacterial properties and mechanism of action, Journal of wound care,4 (2002) 11.

36.H. L. Pape, F. S. Serena, P. Contini, C. Devillers, A. Maftah, P. Leprat, Involvement of reactive oxygen species in the bactericidal activity of activated carbon fibre supporting silver: Bactericidal activity of ACF(Ag) mediated by ROS, Journal of Inorganic Biochemistry, 98 (2004) 1054.

37.A.Oya, T. Wakahara, S. Yoshida, Preparation of pitch-based antibacterial activated carbon fiber, Carbon, 31 (1993) 124.

38.S. Miyanaga, A. Hiwara, H. Yasuda, Preparation and high bacteriostatic action ultrafine silver particles, Science and Technology of Advanced Materials , 3 (2002) 103.

39.D. l. Rosa-Gómez, M. T. Olguín, D. Alcántara, Bactericides of coliform microorganisms from wastewater using silver-clinoptilolite rich tuffs, Applied Clay Science, 40 (2008) 45.

40.P. Jain, T. Pradeep, Potential of silver nanoparticle-coated polyurethane foam as an antibacterial water filter, Biotechnology and Bioengineering , 90 (2005) 59.

41.S. Daniele Lantagne Alethia Environmental, Investigation of the Potters for Peace Colloidal Silver Impregnated Ceramic Filter, (2001).

42.S. Lin, R. Huang, Y. Cheng, J. Liu, L.T. Lau, M. R. Wiesner, Silver nanoparticle-alginate composite beads for point-of-use drinking water

43.D. V. Quang, P. B. Sarawade, S. J. Jeon, S. H. Kim, J.K. Kim, Y. G. Chai, H. T. Kim , Effective water disinfection using silver nanoparticle containing silica beads, Applied Surface Science, 266 (2013) 280.

44.H. N. Mthombeni, L. M. Monyatsi, S. O. Maurice, N. B. M. Maggie, Breakthrough analysis for water disinfection using silver nanoparticles coated resin beads in fixed-bed column , Journal of Hazardous Materials, 217 (2012) 133.

45.林茄豪,製備高分子/植物廢棄物顆粒混合基材薄膜於陽離子染料的吸附應用, 碩士論文,國立中興大學化學工程學系 ,台中,台灣.(2013)

46.黨鈺銘, 聚苯乙烯/脫脂米糠顆粒混合基材薄膜之製備與其染料吸附應用, 碩士論文,國立中興大學化學工程學系 ,台中,台灣.(2013)

47.謝宗樺, 自稻殼提取半纖維素並製備木寡糖, 碩士論文,國立雲林科技大學化學工程與材料工程系 ,雲林,台灣.(2014)

48.蘇瑋婷, 由脫脂米糠提取分離級半纖維素, 碩士論文,國立雲林科技大學化學工程與材料工程系 ,雲林,台灣.(2014)