臺灣博碩士論文加值系統

此研究以旋轉塗佈技術備製大面積非連續堆積單層二氧化矽膠體晶體/ETPTA高分子複合材料於聚對苯二甲酸乙二醇酯(PET)高分子基板表面，後利用活性離子蝕刻其複合材料，以製備具不同尺寸之乳突狀結構陣列於PET高分子基材，其仿蛾眼乳突狀結構，可降低寬廣波長範圍之入射光反射率，並提高入射光穿透率。此外，此仿蛾眼乳突狀結構可以增加基材表面粗糙度，後經氟化物改質，可降低其表面能，以製備具自潔能力之超疏水且抗反射塗佈於PET高分子基材。

This study reports a scalable spin-coating technology for fabricating monolayer non-close-packed silica colloidal crystal/polyethoxylated trimethylol-propane triacrylate composites on polyethylene terephthalate (PET) substrates. We further demonstrate that the colloidal monolayers can be used as structural templates to pattern moth-eye inspired nipple arrays directly on PET substrates. The resulting nipple arrays exhibit broadband antireflective and superhydrophobic properties after surface modification

目錄
中文摘要 i
Abstract ii
目錄 iii
示意圖目錄 v
圖目錄 vi
第一章 緒論 1
1.1 前言 1
1.2 研究動機 2
1.3 研究目的與方法 3
1.4 研究架構與流程 4
第二章 文獻回顧 8
2.1 二氧化矽粒子合成 8
2.2 抗反射膜相關文獻 11
2.3 光子晶體相關文獻 15
2.4 超疏水材料相關文獻 22
2.4.1 蓮葉效應 (Lotus Effect) 22
第三章 實驗 26
3.1 實驗儀器設備 26
3.2 實驗藥品 27
3.3 實驗步驟 30
第四章 實驗結果與討論 34
4.1 旋轉塗佈技術 34
4.2 仿蛾眼結構塗佈之製備 37
4.2.1 薄膜影像與結構分析 38
4.2.2 薄膜影像及光學性質分析 43
4.3 具不同尺寸仿蛾眼結構塗佈薄膜之製備 49
4.3.1 具仿蛾眼結構塗佈薄膜 (200奈米二氧化矽膠體所製備)結構分析 50
4.3.2 具仿蛾眼結構塗佈薄膜 (200奈米二氧化矽膠體所製備)之影像與光學性質分析 52
4.3.3 具仿蛾眼結構塗佈薄膜 (320奈米二氧化矽膠體所製備)之結構分析 58
4.3.4 具仿蛾眼結構塗佈薄膜 (320奈米二氧化矽膠體所製備)之影像與光學性質分析 60
4.3.5 具不同尺寸仿蛾眼結構塗佈薄膜之光學性值比較 65
4.4 仿蛾眼結構塗佈之疏水性質與自潔能力 68
4.4.1 具仿蛾眼結構塗佈薄膜 (200奈米二氧化矽膠體所製備)之疏水性質 69
4.4.2 具仿蛾眼結構塗佈薄膜 (250奈米二氧化矽膠體所製備)之疏水性質 72
4.4.3 具仿蛾眼結構塗佈薄膜 (320奈米二氧化矽膠體所製備)之疏水性質 75
第五章 結論 82
第六章 參考文獻 83

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