跳到主要內容

臺灣博碩士論文加值系統

(44.213.63.130) 您好!臺灣時間:2023/01/29 10:13
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果 :::

詳目顯示

: 
twitterline
研究生:錢世亮
研究生(外文):Shih-Liang Chien
論文名稱:指叉式電極調控膠體小球其增強拉曼光譜之研究
論文名稱(外文):Study of enhanced Raman spectrum by controlling colloidal nanospheres on Interdigital electrode
指導教授:蔡明善黃正良黃正良引用關係
指導教授(外文):Ming-Shan TsaiCheng-Liang Huang
學位類別:碩士
校院名稱:國立嘉義大學
系所名稱:電子物理學系光電暨固態電子研究所
學門:工程學門
學類:電資工程學類
論文種類:學術論文
畢業學年度:103
語文別:中文
中文關鍵詞:拉曼散射表面電漿指叉式電極二氧化矽膠體小球
外文關鍵詞:Raman scatteringSurface plasmonInterdigital electrodeSiO2 nanospheres
相關次數:
  • 被引用被引用:2
  • 點閱點閱:105
  • 評分評分:
  • 下載下載:10
  • 收藏至我的研究室書目清單書目收藏:0
於指叉式電極研究不同濃度樣品溶液其表面增強拉曼散射的調控。將二氧化矽膠體小球及十面體銀奈米粒子加入4-胺基苯硫酚(4-Aminothiophenol, 4-ATP)溶液中作為樣品,指叉式電極的水平側向電場會將帶有負電的膠體小球聚集在正電極,此聚集現象使表面吸附4-ATP分子的銀粒子靠得更近,導致SERS訊號增強。本實驗控制的三種銀粒子濃度分別為0.82x10-5, 1.64x10-5, and 8.2x10-5 M,隨著濃度越高,收集到的SERS訊號越強。而將粒徑200 nm的膠體小球改為350 nm則會因為較劇烈的散射導致訊號減弱。
Manipulation of surface enhanced Raman scattering (SERS) by changing the concentration of mixture solution through interdigital electrodes is investigated. Sample is prepared by adding plastic SiO2 nanospheres and decahedral Ag nanoparticles in the 4-aminothiophenol (4-ATP) aqueous solution. Negatively charged nanospheres are gathered on positive electrode by applying horizontal electric field. The gathering of nanospheres made the Ag nanoparticles tagged by 4-ATP molecule near, and it results the SERS signal increased. Three concentrations of Ag nanoparticles 0.82x10-5, 1.64x10-5, and 8.2x10-5 M are added in this experiment. The more the concentration of Ag nanoparticles adds, the larger the SERS signal obtains. The SERS signal is decreased by changing the size of nanospheres from 200 to 350 nm as a result of strong scattering for size of 350 nm.
摘要 I
Abstract II
致謝 III
目錄 IV
圖目錄 VI
表目錄 VIII
第一章 緒論 1
1-1 前言 1
1-2 SERS增強拉曼光譜之特性與應用 2
1-3 文獻回顧及研究動機 3
第二章 相關理論 6
2-1 拉曼光譜 6
2-2 金屬奈米粒子的表面電漿共振理論 12
2-3 電磁場增強機制(Electromagnetic enhancement mechanism) 13
2-4 化學增強機制(Chemical enhancement mechanism) 15
2-5 SERS理論 17
第三章 樣品製作及實驗架設 19
3-1 二氧化矽膠體小球之合成 19
3-1.1 實驗藥品 19
3-1.2 實驗儀器 19
3-1.3 二氧化矽膠體小球合成反應 19
3-1.4 二氧化矽膠體小球合成步驟 21
3-2 奈米銀粒子之合成 23
3-3 黃光微影製程 24
3-4 實驗樣品 27
3-4.1 樣品溶液配製 27
3-4.2 樣品組裝 29
3-5 拉曼系統架設 29
第四章 實驗結果與討論 33
4-1 奈米銀與4-ATP染料在不同比例下的增強拉曼光譜 33
4-2 膠體小球調控拉曼影像(Raman image) 38
4-3 奈米銀粒子聚集機制 40
4-4 膠體小球所扮演的角色 41
第五章 結論 48
參考文獻 49
1. Rajinder Singh, Phys. Perspect. 4, 399 (2000)
2. M. Fleischmann, P. J. Hendra, and A. J. McQuillan, Chem. Phys. Lett. 26, 163 (1974)
3. E. Burstein and H. Kawamura, “Inelastic Light Scattering ”, Pergamon Press (1980)
4. J. T. Golab, J. R. Sprague, K. T. Carron, G. C. Schatz and R. P. Van Duyne, J. Chem. Phys. 88, 7942 (1988)
5. 林鼎晸、朱仁佑、張祐嘉、汪天仁、蔡枝松、葉吉甪、王俊凱/工研院材化所, “SERS的產業應用”, 工業材料雜誌261期 (2008)
6. Dan Zhu, Zhuyuan Wang, Shenfei Zong, Hui Chen, Xin Wu, Yuwei Pei, Peng Chen, Xueqin Ma and Yiping Cui, Nanoscale 6, 8155 (2014)
7. Yanxiao Li and Zhanfang Ma, Nanotechnology 24, 275605 (2013)
8. V. Canpean and S. Astilean, Spectrochimica Acta A 96, 862 (2012)
9. Ping Xu, Leilei Kang, Nathan H. Mack, Kirk S. Schanze, Xijiang Han and Hsing-Lin Wang, Scientific Reports 3, 2997 (2013)
10. John R. Ferraro, Kazuo Nakamoto and Chris W. Brown, “Introductory Raman Spectroscopy”, 2nd edition, Academic Press (2002)
11. Katrin Kneipp, Harald Kneipp, Irving Itzkan, Ramachandra R Dasari and Michael S Feld, J. Phys.: Condens. Matter 14, 597 (2002)
12. C. N. Banwell, “Fundamental of Molecular Spectroscopy”, 2nd edition, McGraw-Hill (1972)
13. R. W. Wood, Phlios. Mag. 4, 396 (1902)
14. R. H. Rotchie, Phys. Rev. B 106, 874 (1957)
15. A. V. Zayats, I. I. Smolyaninov and A. A. Maradudin, Phys. Reports 408, 131 (2005)
16. Eugene Hecht, “Optics”, 4th edition, Addison Wesley (2001)
17. B. Sepúlveda, Y. Alacerdyan, J. Alegret, M.Käll and P. Johansson, Optics Express 16(8), 5609 (2008)
18. 蕭鈞元, “銀奈米粒子形成過程中即時偵測光譜的表面電漿效應”, 國立嘉義大學光電暨固態電子研究所碩士論文 (2004)
19. 邱國斌、蔡定平, “金屬表面電漿簡介”, 物理雙月刊(廿八卷二期), 472 (2006)
20. 吳民耀、劉威志, “表面電漿子理論與模擬”, 物理雙月刊(廿八卷二期), 486 (2006)
21. C. Bohren and D. Huffman, “Absorption and Scattering of light by Small Particles”, Wiley (1983)
22. George C. Schatz, Matthew A Young and Richard P. Van Duyne, Appl. Phys. 103, 19 (2006)
23. Paul L. Stiles, Jon A. Dieringer, Nilam C. Shah and Richard P. Van Duyne, Annu. Rev. Anal. Chem. 1, 601 (2008)
24. Alan Campion and Patanjali Kambhampati, Chem. Soc. Rev. 27, 241 (1998)
25. Masatoshi Osawa, Naoki Matsuda, Katsumasa Yoshii and Isamu Uchida, J. Phys. Chem. 98, 12702 (1994)
26. Alan Campion, J. E. Ivanecky III, C. M. Child and Michelle Foster, J. Am. Chem. SOC. 117, 11807 (1995)
27. David P. Fromm, Arvind Sundaramurthy, Anika Kinkhabwala, P. James Schuck, Gordon S. Kino and W. E. Moerner, J. Chem. Phys. 124, 061101 (2006)
28. Nam-Jung Kim, J. Phys. Chem. C 114, 13979 (2010)
29. Won- Hwa Park and Zee Hwan Kim, Nano Lett. 10, 4040 (2010)
30. Francisco Avila, David J. Fernandez, Juan F. Arenas, Juan C. Otero and Juan Soto, Chem. Commun. 47, 4210 (2011)
31. Libin Yang, Xin Jiang, Weidong Ruan, Bing Zhao, Weiqing Xu and John R. Lombardi, J. Phys. Chem. C 122, 20095 (2008)
32. Xiaotian Wang, Wensheng Shi, Guangwei She and Lixuan Mu, J. Am. Chem. 133, 16518 (2011)
33. Martin Moskovits, J. Raman Spectrosc. 36, 485 (2005)
34. Werner Stöber and Arthur Fink, J. Colloid Interface Sci. 26, 62 (1968)
35. 林世宏, “利用更序類碗狀電場做成廣視角液晶顯示器”, 國立嘉義大學光電暨固態電子研究所碩士論文 (2007)
36. Li-Chen Yang, Yen-Sang Lai, Chin-Ming Tsai, Yi-Ting Kong, Cheng-I Lee and Cheng-Liang Huang, J. Phys. Chem. C 116, 24292 (2012)
37. Lian-sheng JIAO, Zhijuan WANG, Li NIU, Jing SHEN, Tian-yan YOU and Shao-jun DONG, J. Solid State Electrochem. 10, 886 (2006)
38. Kazumasa Uetsuki, Prabhat Verma, Taka-aki Yano, Yuika Saito, Taro Ichimura and Satoshi Kawata, J. Phys. Chem. C 114, 7515 (2010)
39. Jian Ye, James Andell Hutchison, Hiroshi Uji-i, Johan Hofkens, Liesbet Lagae, Guido Maes, Gustaaf Borghs and Pol Van Dorpe, Nanoscale 4, 1606 (2012)
40. Yi-Fan Huang, De-Yin Wu, Hong-Ping Zhu, Liu-Bin Zhao, Guo-Kun Liu, Bin Ren and Zhong-Qun Tian, Phys. Chem. Chem. Phys. 14, 8485 (2012)
41. Han-Kyu Choi, Hyun Kyong Shon, Hyunung Yu, Tae Geol Lee and Zee Hwan Kim, J. Phys. Chem. Lett. 4, 1079 (2013)
42. Liu-Bin Zhao, Meng Zhang, Yi-Fan Huang, Christopher T. Williams, De-Yin Wu, Bin Ren and Zhong-Qun Tian, J. Phys. Chem. Lett. 5, 1259 (2013)
連結至畢業學校之論文網頁點我開啟連結
註: 此連結為研究生畢業學校所提供,不一定有電子全文可供下載,若連結有誤,請點選上方之〝勘誤回報〞功能,我們會盡快修正,謝謝!
QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top