跳到主要內容

臺灣博碩士論文加值系統

(34.226.244.254) 您好!臺灣時間:2021/08/03 04:14
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果 :::

詳目顯示

我願授權國圖
: 
twitterline
研究生:劉倡宜
研究生(外文):Chang-Yi Liu
論文名稱:碲化鉍合金薄膜熱電元件的開發
論文名稱(外文):Development of Bismuth Telluride Alloy Thin Film Thermoelectric Devices
指導教授:廖洺漢
指導教授(外文):Ming-Han Liao
口試委員:陳敏璋李敏鴻
口試委員(外文):Miin-Jang ChenMin-Hung Lee
口試日期:2015-06-08
學位類別:碩士
校院名稱:國立臺灣大學
系所名稱:機械工程學研究所
學門:工程學門
學類:機械工程學類
論文種類:學術論文
論文出版年:2015
畢業學年度:103
語文別:中文
論文頁數:62
中文關鍵詞:熱電元件碲化鉍合金席貝克效應
外文關鍵詞:thermoelectric deviceBismuth Telluride Alloyseebeck coefficient
相關次數:
  • 被引用被引用:2
  • 點閱點閱:230
  • 評分評分:
  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
本論文中利用磁控濺鍍沉積技術(Magnetron sputtering deposition)製備整合碲硒化鉍(Bi2.0Te2.7Se0.3)與碲銻化鉍(Bi0.4Te3.0Sb1.6)的薄膜式熱電元件。首先探討熱電材料的厚度改變之影響。當碲硒化鉍與碲銻化鉍薄膜的厚度為100nm時,Seebeck係數分別是-24.61uV/K與536.29uV/K。當碲硒化鉍與碲銻化鉍薄膜的厚度為50nm時,Seebeck係數分別是-30.03uV/K與844.37uV/K。很明顯的當熱電薄膜厚度由100nm改變至50nm時Seebeck係數會有明顯的提升,這是因為位能障散射(potential barrier scattering)效應所導致。接下來整合碲硒化鉍與碲銻化鉍薄膜製備薄膜式熱電元件,在本實驗中製備出來的薄膜熱電元件每度溫差下可提供0.24461毫伏。

In this thesis, we used magnetron sputtering deposition technique to deposit the thin film thermoelectric device that integrates Bi2.0Te2.7Se0.3 into Bi0.4Te3.0Sb1.6 thin film. At first, we discuss the different thickness effect on thermoelectric materials. When thickness of Bi2.0Te2.7Se0.3 and Bi0.4Te3.0Sb1.6 is 100nm, Seebeck coefficient is -24.61uV/K and 536.29uV/K respectively. When thickness of Bi2.0Te2.7Se0.3 and Bi0.4Te3.0Sb1.6 is 50nm, Seebeck coefficient is -30.03uV/K and 844.37uV/K respectively. As thermoelectric membrane thickness obviously change from 100nm to 50nm, Seebeck coefficient increases due to potential barrier scattering. Secondly, we use Bi2.0Te2.7Se0.3 and Bi0.4Te3.0Sb1.6 membrane to fabricate thin film thermoelectric device.

口試委員審定書 I
摘要 II
Abstract III
目錄 IV
圖目錄 VI
表目錄 VII
第一章 緒論 1
1.1 前言 1
1.2 研究背景與動機 2
第二章 文獻回顧與理論基礎 3
2.1 熱電原理 3
2.1.1 Seebeck效應 3
2.1.2 Peltier效應 4
2.1.3 Thomson效應 6
2.2 熱電優值(Figure of Merit) 7
2.2.1 Seebeck係數和導電率之間的矛盾 9
2.2.2 熱傳導係數與導電率之間的矛盾 10
2.3 熱電材料種類 11
2.3.1 碲化鉍(Bismuth telluride) 12
2.3.2 碲化鉛(Lead telluride) 13
2.3.3 矽鍺(silicon germanium)合金 14
2.3.4 方鈷礦(skutterudite) 14
2.3.5 半赫斯勒(Half-Heusler)合金 15
2.3.6 Zn4Sb3合金 16
2.4 熱電轉換效率 17
2.4.1 熱電發電器(Thermoelectric generators) 18
2.4.2 熱電致冷器(Thermoelectric Cooler) 18
2.5 熱電發展與現況 19
2.5.1 熱電歷史 19
2.5.2 1996年~2011年熱電材料的發展 21
2.5.3 近年熱電材料發展 28
2.6 真空理論 31
2.7 電漿 32
2.8 薄膜成長機制 33
第三章 實驗方法與步驟 36
3.1 碲化鉍薄膜 36
3.1.1 分子束磊晶成長法(molecular beam epitaxy,MBE) 36
3.1.2 磁控濺鍍法(magnetron sputtering) 36
3.1.3 蒸鍍法(evaporation) 37
3.1.4 電化學沉積法(electrochemically deposition) 37
3.1.5 有機金屬化學氣相沉積(metal organic chemical vapor deposition,MOCVD) 37
3.2 薄膜熱電元件製備 38
第四章 實驗結果與討論 42
參考文獻 45


[1]E. Altenkirch, “Physikalische Zeitschrift”, 10, 560–580(1909)
[2]Paz Vaqueiro, Anthony V. Powell,“ Recent developments in nanostructured materials for high-performance thermoelectrics”, Journal of Materials Chemistry , 20, 9577-9584(2010)
[3]Zhi-Gang Chena, Guang Han, Lei Yang, Lina Cheng, Jin Zoua, “Nanostructured thermoelectric materials: Current research and future challenge”, Progress in Natural Science: Materials International, 20, 535-549(2012)
[4]A.J.Minnich, M.S.Dresselhaus, Z. F. Ren and G. Chen, “Bulk nanostructured thermoelectric materials: current research and future prospects”, Energy & Environmental Science, 2, 466-479(2009)
[5]A.F.Ioffe, “Semiconductor Thermoelements and Thermoelectric Cooling”, Infosearch, London(1957)
[6]H.J.Goldsmid, R.W.Douglas,“The use of semiconductors in thermoelectric refrigeration”, British Journal of Applied physics, 5, 386-390(1954)
[7]L.D.Hicks, and M.S.Dresselhaus, “Thermoelectric figure of merit of a one-dimensional conductor”, Phys. Rev. B, 47, 16631(1993)
[8]G.A. Slack, in: M. Rowe (Ed.), CRC Handbook of Thermo- electrics, CRC Press, Boca Raton, FL(1995)
[9]L.D.Hicks, T.C.Harman, X.Sun, M.S.Dresselhaus, “Experimental study of the effect of quantum-well structures on the thermoelectric figure of merit”, Phys. Rev. B, 53, R10493(1996)
[10]B.C.Sales, D.Mandrus, R.K.Williams, “Filled Skutterudite Antimonides:A New Class of Thermoelectric Materials”, Science, 272, 1325(1996)
[11]Q. Shen, L. Chen, T. Goto, T. Hirai, J. Yang, G. P. Meisner,C. Uher, “Effects of partial substitution of Ni by Pd on the thermoelectric properties of ZrNiSn-based half-Heusler compounds”, Appl. Phys. Lett, 79, 4165(2001)
[12]T. C. Harman, P. J. Taylor, M. P. Walsh, and B. E. LaForge,“Quantum Dot Superlattice Thermoelectric Materials and Devices”,Science, 297, 2229(2002)
[13]K. F. Hsu ,“Cubic AgnPbmSbnTem+2n:bulk thermoelectric materials with high figure of merit”, Science, 303, 818-821(2004)
[14]Xinfeng Tang, Qingjie Zhang, Lidong Chen, Takashi Goto, Toshio Hirai,“Synthesis and thermoelectric properties of p-type- and n-type-filled skutterudite RyMxCo4−xSb12(R:Ce,Ba,Y;M:Fe,Ni)”, Journal of Applied physics, 97, 093712(2005)
[15]Y.Z.Pei, L.D.Chen, W.Zhang, X.Shi, S.Q.Bai, X.Y.Zhao, Z.G.Mei, X.Y.Li, “Synthesis and thermoelectric properties of KyCo4Sb12” , Appl. Phys. Lett, 89, 221107(2006)
[16]Heng Wang, Jing-Feng Li, Ce-Wen Nan, Min Zhou, Weishu Liu, Bo-Ping Zhang, Takuji Kita, “High-performance Ag0.8Pb18+xSbTe20 thermoelectric bulk materials fabricated by mechanical alloying and spark plasma sintering” , Appl. Phys. Lett,88, 092104(2006)
[17]S.R.Culp, S.J.Poon, N.Hickman, T.M.Tritt, J.Blumm, “Effect of substitutions on the thermoelectric figure of merit of half-Heusler phases at 800 °C” , Appl. Phys. Lett., 88, 042106(2006)
[18]J.Androulakis, K.F.Hsu, R.Pcionek, H.Kong, C.Uher, J.J.Dangelo, “Nanostructuring and high thermoelectricefficiency in p-type Ag(Pb1-ySny)mSbTe2+m” , Advanced Materials, 181170-1173(2006)
[19]P.F.R.Poudeu, J.D.Angelo, A.D.Downey, J.L.Short,T.P. Hogan, M.G.Kanatzidis, “High thermoelectric figure ofmerit and nanostructuring in bulk p-type Na1-xPbmSbyTem+2” , Angewandte Chemie, International Edition , 45, 3835-3839(2006)
[20]Bed Poudel, Qing Hao, Yi Ma, Yucheng Lan, Austin Minnich, Bo Yu, Xiao Yan, Dezhi Wang, Andrew Muto, Daryoosh Vashaee, Xiaoyuan Chen, Junming Liu, Mildred S.Dresselhaus, Gang Chen, Zhifeng Ren, “High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys” , Science, 320, 634(2008)
[21]X.W.Wang, H.Lee, Y.C.Lan, G.H.Zhu, G.Joshi, D.Z.Wang, J.Yang, A.J.Muto, M.Y.Tang, J.Klatsky, S.Song, M.S.Dresselhaus,G.Chen, Z.F.Ren,“Enhanced thermoelec-
tric figure of merit in nanostructured n-type silicon germanium bulk alloy” , Appl. Phys. Lett, 93, 193121(2008)
[22]Heng Wang, Jing-Feng Li, Minmin Zou, Tao Sui, “Synthesis and transport property of AgSbTe2 as a promising thermoelectric compound” , Appl. Phys. Lett, 93, 202106(2008)
[23]A.I.Boukai, Y.Bunimovich, J.Tahir-Kheli, J.-K. Yu,W.A. Goddard III, J.R. Heath, , “Silicon nanowires as efficient thermoelectric materials” , Nature, 45, 1168–171(2008)
[24]Wenjie Xie, Xinfeng Tang, Yonggao Yan, Qingjie Zhang, Terry M. Tritt, “Unique nanostructures and enhanced thermoelectric performance of melt-spun BiSbTe alloys” , Appl. Phys. Lett, 94, 102111 (2009).
[25]Y.Q.Cao, X.B.Zhao, T.J.Zhu, X.B.Zhang and J.P.Tu, “Syntheses and thermoelectric properties of Bi2Te3/Sb2Te3 bulk nanocomposites with laminated nanostructure” , Appl. Phys. Lett, 92, 143106(2008)
[26]Han Li, Xinfeng Tang, Qingjie Zhang, Ctirad Uher, “High performance InxCeyCo4Sb12 thermoelectric materials with in situ forming nanostructured InSb phase” , Appl. Phys. Lett, 94, 102114(2009).
[27]Li-Dong Zhao, Bo-Ping Zhang, Wei-Shu Liu, Jing-Feng Li, “Effect of mixed grain sizes on thermoelectric performance of Bi2Te3 compound”, J. Appl. Phys, 105, 023704(2009)
[28]Pierre F. P. Poudeu, Aurelie Gueguen, Chun-I Wu, Tim Hogan, Mercouri G. Kanatzidis, “High Figure of Merit in Nanostructured n-Type KPbmSbTem+2 Thermoelectric Materials” , Chem. Mater, 22, 1046(2010)
[29]T.He, J.Chen, H.D.Rosenfeld, M.A.Subramanian, “Thermoelectric properties of indium-filled skutterudites”, Chemistry of Materials, 18, 759-762(2006)
[30]W.S.Liu, B.P.Zhang, L.D.Zhao, J.F.Li, “Improvement ofthermoelectric performance of CoSb3-xTex skutterudite compounds by additional substitution of IVB-group elements for Sb”, Chemistry of Materials, 20, 7526-7531(2008)
[31]W.Zhao, P.Wei, Q.Zhang, C.Dong, L.Liu, X.Tang, “Enhanced thermoelectric performance in barium and indium double-filled skutterudite bulk materials via orbital hybridization induced by indium filler”, Journal of the American Chemical Society, 131, 3713-3720(2009)
[32]H.Li, X.F.Tang, X.L.Su, Q.J.Zhang, “Preparation and thermoelectric properties of high-performance Sb additional Yb0.2Co4Sb12+y bulk materials with nanostructure”, Applied Physics Letters , 92 , 202114(2008)
[33]H.Li, X.F.Tang, Q.J.Zhang, C.Uher, “Rapid preparation method of bulk nanostructured Yb0.3Co4Sb12+y compounds and their improved thermoelectric performance”, Applied Physics Letters , 93, 202114(2008)
[34]Y.Z.Pei, J.Yang, L.D.Chen, W.Zhang, J.R.Salvador, J.H.Yang, “Improving thermoelectric performance of caged compounds through light-element filling”, Applied Physics Letters, 95, 042101(2009)
[35]X.Shi, J.Yang, J.R.Salvador, M.Chi, J.Y.Cho, H.Wang, et al., “Multiple-filled skutterudites: High thermoelectric figure of merit through separately optimizing electrical and thermal transports”, Journal of the American Chemical Society, 133, 7837-7846(2011)
[36]L.D.Hicks, T.C.Harman, X.Sun, M.S.Dresselhaus, “Experimental study of the effect of quantum-well structures on the thermoelectric figure of merit”, Physical Review, B 53 , R10493(1996)
[37]A.I.Hochbaum, R.Chen, R.D.Delgado, W.Liang, E.C.Garnett, M.Najarian, et al., “Enhanced thermoelectric performance of rough silicon nanowires”, Nature 451 ,163-U165(2008)
[38]Y.Ma, Q.Hao, B.Poudel, Y.Lan, B.Yu, D.Wang, et al., “Enhanced thermoelectric figure-of-merit in p-type nanostructured bismuth antimony tellurium alloys made from elemental chunks”, Nano Letters , 8, 2580-2584 (2008)
[39]Y.Lan, B.Poudel, Y.Ma, D.Wang, M.S.Dresselhaus, G.Chen, et al., “Structure study of bulk nanograined thermoelectric bismuth antimony telluride”, Nano Letters ,9 , 1419-1422(2009)
[40]X.Yan, B.Poudel, Y.Ma, W.S.Liu, G.Joshi, H.Wang, et al., “Experimental studies on anisotropic thermoelectric properties and structures of n-Type Bi2Te2.7Se0.3”, Nano Letters ,10 , 3373-3378(2010)
[41]W.Xie, J.He, H.J.Kang, X.Tang, S.Zhu, M.Laver, et al., “Identifying the specific nanostructures responsible for the high thermoelectric performance of (Bi, Sb)2Te3 nanocomposites”, Nano Letters ,10 , 3283-3289(2010)
[42]Y.Q.Cao, X.B.Zhao, T.J.Zhu, X.B.Zhang, J.P.Tu, “Syntheses and thermoelectric properties of Bi2Te3/Sb2Te3 bulk nanocomposites with laminated nanostructure”, Applied Physics Letters , 92, 143106(2008)
[43]X.B.Zhao, S.H.Yang, Y.Q.Cao, J.L.Mi, Q.Zhang, T.J.Zhu, “Synthesis of nanocomposites with improved thermoelectric properties”, Journal of Electronic Materials , 38, 1017-1024(2009)
[44]S.Fan, J.Zhao, J.Guo, Q.Yan, J.Ma, H.H.Hng, “p-type Bi0.4Sb1.6Te3 nanocomposites with enhanced figure of merit”, Applied Physics Letters , 96, 182104(2010)
[45]J.Androulakis, K.F.Hsu, R.Pcionek, H.Kong, C.Uher, J.J.Dangelo, et al., “Nanostructuring and High Thermoelectric Efficiency in p-Type Ag(Pb1 – ySny)mSbTe2 + m”, Advanced Materials , 18, 1170-1173(2006)
[46]B.A. Cook, M.J. Kramer, J.L. Harringa, M.K. Han, D.Y. Chung, M.G. Kanatzidis, “Analysis of nanostructuring in high figure of merit Ag1-xPbmSbTe2+m thermoelectric materials”, Advanced Functional Materials , 19, 1254-1259(2009)
[47]J.R.Sootsman, H.Kong, C.Uher, J.J. D’Angelo, C.I.Wu, T.P. Hogan, et al., “Large enhancements in the thermoelectric power factor of bulk PbTe at high temperature by synergistic nanostructuring”, Angewandte Chemie, International Edition ,47 , 8618-8622(2008)
[48]J.R. Sootsman, J. He, V.P. Dravid, S. Ballikaya, D. Vermeulen, C. Uher, et al., “Microstructure and thermoelectric properties of mechanically tobust PbTe–Si eutectic composites”, Chemistry of Materials , 22 , 869-875(2010)
[49]P.F.P. Poudeu, J. D’Angelo, H. Kong, A. Downey, J.L. Short, R. Pcionek, et al., “Nanostructures versus solid solutions: low lattice thermal conductivity and enhanced thermoelectric figure of merit in Pb9.6Sb0.2Te10-xSex bulk materials”, Journal of the American Chemical Society ,128 , 14347-14355(2006)
[50]J. Androulakis, C.H. Lin, H.J. Kong, C. Uher, C.I. Wu, T. Hogan, et al., “ Spinodal decomposition and nucleation and growth as a means to bulk nanostructured thermoelectrics: enhanced performance in Pb1-xSnxTePbS”, Journal of the American Chemical Society, 129 , 9780-9788(2007)
[51]G. Joshi, H. Lee, Y. Lan, X. Wang, G. Zhu, D. Wang et al., “Enhanced thermoelectric figure-of-merit in nanostructured p-type silicon germanium bulk alloys”, Nano Letters, 84, 670-4674(2008)
[52]X.W. Wang, H. Lee, Y.C. Lan, G.H. Zhu, G. Joshi, D.Z. Wang, et al., “Enhanced thermoelectric figure of merit in nanostructured n-type silicon germanium bulk alloy”, Applied Physics Letters, 93, 193121(2008)
[53]J.S. Rhyee, K.H. Lee, S.M. Lee, E. Cho, S.I. Kim, E. Lee, et al., “Peierls distortion as a route to high thermoelectric performance in In4Se3- crystals”, Nature, 459, 965-968(2009)
[54]J.S.Rhyee, K.Ahn, K.H.Lee, H.S.Ji, J.-H.Shim, “Enhancement of the thermoelectric figure-of-merit in a wide temperature range in In4Se3-xCl0.03 bulk crystals”, Advanced Materials, 23, 2191-2194(2011)
[55]T.H.Zou, X.Y.Qin, D.Li, B.J.Ren, G.L.Sun, Y.C.Dou, Y.Y Li, L.L.Li, J.Zhang, H.X.Xin,“Enhanced thermoelectric performance via carrier energy filtering effectin β-Zn4Sb3 alloy bulk embedded with (Bi2Te3)0.2(Sb2Te3)0.8”, J. Appl. Phys, 115, 053710(2014)
[56]Satya N. Guin, Arindom Chatterjee,Kanishka Biswas,“Enhanced thermoelectric performance in p-type AgSbSe2 by Cd-doping”, RSC Adv, 4, 11811(2014)
[57]Jian Zhang,Xiaoying Qin, Di Li, Hongxing Xin, Cunjun Song, Liangliang Li, Xiaoguang Zhu, Zhaoming Wang, Guanglei Guo, Ling Wang,“Enhanced thermoelectric performance of CuGaTe2 based composites incorporated with nanophase Cu2Se”, J. Mater. Chem. A, 2, 2891(2014)
[58]Tulashi Dahal, Qing Jie, Giri Joshi, Shuo Chen, Chuanfei Guo, Yucheng Lan,Zhifeng Ren,“Thermoelectric property enhancement in Yb-doped n-type skutterudites YbxCo4Sb12”, Acta Materialia, 75, 316–321(2014)
[59]Tian-Ran Wei, Heng Wang, Zachary M. Gibbs, Chao-Feng Wu,G. Jeffrey Snyderb and Jing-Feng Li,“Thermoelectric properties of Sn-doped p-type Cu3SbSe4: a compound with large effective mass and small band gap”, J. Mater. Chem., A, 2,13527(2014)
[60]Shaowei Song, Jueling Wang, Bo Xu, Xiaobo Lei, Hongchuan Jiang, Yingrong Jin, Qinyong Zhang, Zhifeng Ren, “Thermoelectric properties of n-type Bi2Te2.7Se0.3 with addition of nano-ZnO:Al particles” , Mater. Res. Express, 1, 035901(2014)
[61]Yinglu Tang, Yuting Qiu,Lili Xi,b Xun Shi, Wenqing Zhang,Lidong Chen, Ssu-Ming Tseng,Sinn-wen Chen, G. Jeffrey Snyder,“Phase diagram of In–Co–Sb system and thermoelectric properties of In-containing skutterudites”, Energy Environ. Sci, 7, 812(2014)
[62]Yemao Han , Zhen Chen, Caini Xin, Yanzhong Pei, Min Zhou, Rongjin Huang, Laifeng Li,“Improved thermoelectric performance of Nb-doped lead selenide”, Journal of Alloys and Compounds , 600, 91–95(2014)
[63]Xueli Du, Fengshi Cai, Xuewei Wang,“Enhanced thermoelectric performance of chloride doped bismuth sulfide prepared by mechanical alloying and spark plasma sintering”, Journal of Alloys and Compounds , 587 , 6–9(2014)
[64]A.U. Khan, N.V. Vlachos, E. Hatzikraniotis, G.S. Polymeris, Ch.B. Lioutas, E.C. Stefanaki, K.M. Paraskevopoulos, I. Giapintzakis, Th. Kyratsi, “Thermoelectric properties of highly efficient Bi-doped Mg2Si1-x-ySnxGey materials”, Acta Materialia , 77, 43–53(2014)
[65]Xu Lu , Donald T. Morelli , Yi Xia , Fei Zhou , Vidvuds Ozolins , Hang Chi , Xiaoyuan Zhou , and Ctirad Uher ,“High Performance Thermoelectricity in Earth-Abundant Compounds Based on Natural Mineral Tetrahedrites”, Adv. Energy Mater., 3, 342–348(2013)
[66]S. Battiston, S. Fiameni, M. Saleemi, S. Boldrini, A. Famengo, F. Agresti, M. Stingaciu, M.S. Toprak, M. Fabrizio, S. Barison,“Synthesis and Characterization of Al-Doped Mg¬2Si Thermoelectric Materials”, Journal of Electronic Materials, 42, 1956-1959(2013)
[67]Li-Dong Zhao, Shiqiang Hao, Shih-Han Lo, Chun-I Wu, Xiaoyuan Zhou, Yeseul Lee, Hao Li, Kanishka Biswas, Timothy P. Hogan, Ctirad Uher, C. Wolverton, Vinayak P. Dravid, and Mercouri G. Kanatzidis,“High Thermoelectric Performance via Hierarchical Compositionally Alloyed Nanostructures” , J. Am. Chem. Soc., 135, 7364−7370(2013)
[68]Jianhui Li , Qing Tan , Jing-Feng Li , Da-Wei Liu , Fu Li , Zong-Yue Li , Minmin Zou , and Ke Wang,“BiSbTe-Based Nanocomposites with High ZT : The Effect of SiC Nanodispersion on Thermoelectric Properties”, Adv. Funct. Mater., 23, 4317–4323(2013)
[69]Huili Liu , Xun Yuan , Ping Lu , Xun Shi , Fangfang Xu , Ying He , Yunshan Tang , Shengqiang Bai , Wenqing Zhang , Lidong Chen , Yue Lin , Lei Shi , He Lin , Xingyu Gao , Xingmin Zhang , Hang Chi , and Ctirad Uher,“Ultrahigh Thermoelectric Performance by Electron and Phonon Critical Scattering in Cu2Se 1-xIx”, Adv. Mater., 25, 6607–6612(2013)
[70]Yan-Ling Pei, Jiaqing He, Jing-Feng Li, Fu Li, Qijun Liu, Wei Pan, Celine Barreteau, David Berardan, Nita Dragoe and Li-Dong Zhao ,“High thermoelectric performance of oxyselenides: intrinsically low thermal conductivity of Ca-doped BiCuSeO”,NPG Asia Materials, 5, e47 (2013)
[71]Jianhui Li, Qing Tan, Jing-Feng Li ,“Synthesis and property evaluation of CuFeS2-x as earth-abundant and environmentally-friendly thermoelectric materials”, Journal of Alloys and Compounds , 551, 143–149(2013)
[72]Satya N. Guin, Arindom Chatterjee, Devendra Singh Negi, Ranjan Datta and Kanishka Biswas, “High thermoelectric performance in tellurium free p-type AgSbSe2” ,Energy Environ. Sci., 6, 2603–2608 (2013)
[73]A.U. Khan, N. Vlachos and Th. Kyratsi,“High thermoelectric figure of merit of Mg2Si0.55Sn0.4Ge0.05 materials doped with Bi and Sb” , Scripta Materialia , 69 , 606–609(2013)
[74]P K Rawat, B Paul and P Banerji, “Thermoelectric properties of PbSe0.5Te0.5: x (PbI2) with endotaxial nanostructures: a promising n-type thermoelectric material”, Nanotechnology, 24, 215401(2013)
[75]Li-Dong Zhao,Jiaqing He, Shiqiang Hao, Chun-I Wu, Timothy P. Hogan, C. Wolverton,Vinayak P.Dravid, Mercouri G. Kanatzidis,“Raising the Thermoelectric Performance of p‑Type PbS with Endotaxial Nanostructuring and Valence-Band Offset Engineering Using CdS and ZnS”, J. Am. Chem. Soc, 134, 16327−16336(2012)
[76]Eun Kyung Lee, Liang Yin, Yongjin Lee, Jong Woon Lee, Sang Jin Lee, Junho Lee, Seung Nam Cha, Dongmok Whang, Gyeong S. Hwang, Kedar Hippalgaonkar, Arun Majumdar, Choongho Yu, Byoung Lyong Choi, Jong Min Kim, Kinam Kim, “Large Thermoelectric Figure-of-Merits from SiGe Nanowires by Simultaneously Measuring Electrical and Thermal Transport Properties”, Nano Lett., 12, 2918−2923(2012)
[77]Chia-Jyi Liu, Hsin -Chang Lai, Yen-Liang Liu, Liang-Ru Chen ,“High thermoelectric figure-of-merit in p-type nanostructured (Bi,Sb)2Te3 fabricated via hydrothermal synthesis and evacuated-and-encapsulated sintering”, J. Mater. Chem, 22, 4825(2012)
[78]Yanzhong Pei, Aaron D.LaLonde, Nicholas A. Heinz , and G. Jeffrey Snyder ,“High Thermoelectric Figure of Merit in PbTe Alloys Demonstrated in PbTe–CdTe”, Adv. Energy Mater, 2, 670–675(2012)
[79]Zhengliang Du, Tiejun Zhu, Xinbing Zhao ,“Enhanced thermoelectric properties of Mg2Si0.58Sn0.42 compounds by Bi doping”, Materials Letters, 66, 76–78 (2012)
[80]Theerayuth Plirdpring, Ken Kurosaki, Atsuko Kosuga, Tristan Day, Samad Firdosy, Vilupanur Ravi, G. Jeffrey Snyder, Adul Harnwunggmoung, Tohru Sugahara, Yuji Ohishi, Hiroaki Muta, Shinsuke Yamanaka,“Chalcopyrite CuGaTe2:A High-Effi ciency Bulk Thermoelectric Material”, Adv. Mater, 24, 3622–3626(2012)
[81]Fu Li, Jing-Feng Li, Li-Dong Zhao, Kai Xiang, Yong Liu, Bo-Ping Zhang, Yuan-Hua Lin,Ce-Wen Nana, Hong-Min Zhu, “Polycrystalline BiCuSeO oxide as a potential thermoelectric material”, Energy Environ. Sci., 5, 7188(2012)
[82]Jing Li, Jiehe Sui, Yanling Pei, Celine Barreteau, David Berardan, Nita Dragoe, Wei Cai, Jiaqing He, Li-Dong Zhao ,“A high thermoelectric figure of merit ZT > 1 in Ba heavily doped BiCuSeO oxyselenides”, Energy Environ. Sci., 5, 8543(2012)
[83]Ajay Soni, Zhao Yanyuan, Yu Ligen, Michael Khor Khiam Aik, Mildred S. Dresselhaus, Qihua Xiong,“Enhanced Thermoelectric Properties of Solution Grown Bi2Te3-xSex Nanoplatelet Composites”, Nano Lett., 12, 1203-1209(2012)
[84]Qian Zhang, Feng Cao, Weishu Liu, Kevin Lukas, Bo Yu, Shuo Chen, Cyril Opeil, David Broido, Gang Chen, Zhifeng Ren,“Heavy Doping and Band Engineering by Potassium to Improve the Thermoelectric Figure of Merit in p-Type PbTe, PbSe, and PbTe1-ySey”, J. Am. Chem. Soc, 134, 10031-10038(2012)
[85]D.G. Cahill, S.K. Watson, R.O. Pohl, “Lower limit to the thermal-conductivity of disordered crystals”, Physical Review, B46,6131-6140(1992)
[86]C.Chiritescu, D.G.Cahill, N.Nguyen, D.Johnson, A.Bodapati, P.Keblinski, et al., “Ultralow thermal conductivity in dis ordered, layered WSe2 crystals”, Science (New York, NY), 315, 351-353(2007)
[87]Kengo Kishimoto ,Tsuyoshi Koyanagi,“Preparation of sintered degenerate n-type PbTe with a small grain size and its thermoelectric properties”, Journal of Applied Physics, 95, 2544(2002)
[88]ShanyuWang, Han Li, Ruiming Lu, Gang Zheng ,Xinfeng Tang,“Metal nanoparticle decorated n-type Bi2Te3-based materials with enhanced thermoelectric performances” , Nanotechnology, 24, 285702(2013)
[89]Jing-Feng Li, Wei-Shu Liu, Li-Dong Zhao, Min Zhou,“High-performance nanostructured thermoelectric materials” , NPG Asia Mater., 2(4), 152-158(2010)
[90]Naoki Shutoh, Shinya Sakurada,“Thermoelectric properties of the Tix(Zr0.5Hf0.5)1-xNiSn half-Heusler compounds”, Journal of Alloys and Compounds, 389, 204-208(2005)
[91]Weishu Liu, Xiao Yan, Gang Chen, Zhifeng Ren,“Recent advances in thermoelectric nanocomposites” , Nano Energy , 1, 42-56(2012)
[92]H.S.Dow, M.W.Oh, B. S. Kim, S. D. Park, H. W. Lee, D. M. Wee,“First-Principles Calculations on Electronic Structure of PbTe” , International Conference on Thermoelectrics(ICT), 26th, 90 – 93(2007)
[93]Seong-Gon Kim, I.I.Mazin , D.J.Singh ,“First-principles study of Zn-Sb thermoelectrics” , Phys. Rev. B 57, 6199(1998)
[94]Yunki Kim, Sunglae Cho, Antonio DiVenere, George K. L. Wong, J. B. Ketterson,“Composition-dependent layered structure and transport properties in BiTe thin films” , PHYSICAL REVIEW ,B 63, 155306(2001)
[95]R.Venkatasubramanian, T.Colpitts, E.Watko, M.Lamvik, N. E1-Masry,“MOCVD of Bi2Te3, Sb2Te3 and their superlattice structures for thin-film thermoelectric applications” , ournal of Co,stal Growth,170, 817-821(1997)
[96]M.Takashiri, T.Shirakawa, K.Miyazaki, H.Tsukamoto,“Fabrication and characterization of bismuth–telluride-based alloy thin film thermoelectric generators by flash evaporation method” , Sensors and Actuators A, 138, 329-334(2007)
[97]Kyoung-Won Cho, Il-Ho Kim ,“Thermoelectric properties of the flash-evaporated n-type Bi2Te2.4Se0.6 thin films” , Materials Letters, 59, 966-970(2005)
[98]D.Bourgault, C.Giroud Garampon, N.Caillault, L.Carbone, J.A. Aymami,“Thermoelectric properties of n-type Bi2Te2.7Se0.3 and p-type Bi0.5Sb1.5Te3 thinfilms deposited by direct current magnetron sputtering”, Thin Solid Films, 516, 8579-8583(2008)
[99] 王亞帆碩士論文,“能障散射效應對Bi0.5Sb1.5Te3薄膜熱電性質影響之研究”,國立清華大學材料所 廖建能教授(2007)
[100]Yang Zhou, Liangliang Li, Qing Tan, Jing-Feng Li,“Thermoelectric properties of Pb-doped bismuth telluride thin films deposited by magnetron sputtering” , Journal of Alloys and Compounds, 590, 362-367(2014)
[101] Junqiang Song, Qin Yao, Ting Wu, Xun Shi, Lidong Chen ,“Microstructures and thermoelectric properties of p-type BixSb2−xTe3 thin films with various compositions ” , Electronic Materials Letters, 9, 709-713(2003)
[102] B.Y. Yoo, C.-K. Huang, J.R. Lim, J. Herman, M.A. Ryan, J.-P. Fleurial, N.V. Myung,“Electrochemically deposited thermoelectric n-type Bi2Te3 thin films” , Electrochimica Acta, 50, 4371-4377(2005)
[103] E.J.X.Pang, S.J.Pickering, A.Chan, K.H.Wong, P.L.Lau,“N-type thermoelectric recycled carbon fibre sheet with electrochemically deposited Bi2Te3” , Journal of Solid State Chemistry,193,147-153(2012)


QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top
無相關期刊
 
無相關點閱論文