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研究生:姜星宇
研究生(外文):Hsing-Yu Chiang
論文名稱:雙重組製程應用於固態氧化物燃料電池系統之設計與評估
論文名稱(外文):Design and Evaluation of Bi-Reforming Process Based Solid Oxide Fuel Cell Systems
指導教授:鄭智成鄭智成引用關係
口試委員:楊重光王國彬錢義隆
口試日期:2016-07-20
學位類別:碩士
校院名稱:國立臺北科技大學
系所名稱:化學工程研究所
學門:工程學門
學類:化學工程學類
論文種類:學術論文
畢業學年度:104
語文別:中文
中文關鍵詞:濕式重組;乾式重組;雙重組製程;固態氧化物燃料電池 ; 綠色能源科技
外文關鍵詞:et reforming; Dry reforming; Bi-reforming process; SOFC; Green energy technology
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燃料電池為現今重要替代能源之一,其中固態氧化物燃料電池(SOFC)因能量效率較高而具有發展潛力。SOFC通常需要配合預重組器提供其燃料來源,然而,傳統濕式預重組器的SOFC系統不但容易因內部重組影響電池效能與穩定性,還會產生二氧化碳造成環境汙染。為了避免內部重組與改善電池性能,本研究應用雙重組(濕式重組(SR)與乾式重組(DR))製程於固態氧化物燃料電池電力系統,並提出不同的設計架構。由於碳沉積的限制,各種架構分別具有最佳操作條件(回流比與進料比)。研究中針對所設計出的最適化系統就其電效率值與二氧化碳排放因子進行評估。結果顯示,串聯式預雙重組SR- DR-SOFC (Case B)為最佳設計架構。相較於傳統濕式預重組器的SOFC系統,此系統於同樣產生120kW的前提下,具有下列三方面優勢 : (1) 燃料進料量(甲烷)減少約24%;(2) 系統電效率值提升約30 %;(3) 系統整體二氧化碳排放因子降低約23%。此外,若於SOFC進料處進行除水將能額外增加10%的電效率值。因此,預雙重組器SOFC系統是對燃料電池效能提升及環境污染降低方面都相當具有價值的綠色能源技術。
Fuel cell is one of the most important technologies for alternative energy. Among the fuel cells, solid oxide fuel cell (SOFC) becomes a promising technology because of its higher energy efficiency. SOFC typically requires a pre-reformer for its fuel supply. However, in the traditional wet pre-reforming SOFC system, inevitable internal reforming not only affects the cell effectiveness and durability, but also causes environmental pollution due to carbon dioxide emission. To avoid internal reforming and improve the cell performance, this study applies the bi-reforming (steam reforming (SR) and dry reforming (DR)) process to SOFC system and proposes various design configurations. For each configuration, the corresponding operating conditions (recycle ratio and feed ratio) are optimized while taking the constraint of carbon deposition into account.Then, the optimal systems are evaluated by the electric efficiency and the emission fator of carbon dioxide. The results show that the series configuration with SR preceding DR (Case B) achieves the best performance. Compared with the traditional wet pre-reforming based SOFC system, this system has three predominant advantages (on the condition of producing 120kW): (1) reduce the feed of fuel (methane) about 24%; (2) improve the electric efficiency about 30%; (3) decrease the system emission factor of carbon dioxide about 23%. In addition, it is found that the system electric efficiency can be further increased by 10% when the water is removed from the SOFC inlet stream. Therefore, we can conclude that the novel bi-reforming based SOFC system is a valuable green energy technology in the light of improving fuel cell effectiveness and reducing environmental pollution.
摘要 I
ABSTRACT III
致謝 V
目錄 VI
表目錄 IX
圖目錄 X
第1章 緒論 1
1.1 前言 1
1.2 文獻回顧 2
1.3 研究動機與目的 5
1.4 章節組織 6
第2章 燃料電池系統 7
2.1 燃料電池簡化架構 7
2.2 預重組器(pre-reforming) 8
2.2.1 溼式重組製程(Steam Reforming , SR) 9
2.2.2 乾式重組製程(Dry Reforming , DR) 11
2.2.3 複合重組製程 12
2.3 燃料電池 13
2.3.1 燃料電池技術 14
2.3.2 燃料電池的種類與比較 15
2.3.3 固態氧化物燃料電池(SOFC)結構介紹 19
2.3.4 SOFC運作原理 22
2.4 尾燃器 24
第3章 SOFC電力系統之模擬 25
3.1 電力系統之元件原理與模擬 26
3.1.1 預重組器 27
3.1.2 SOFC 27
3.1.3 尾燃器 29
3.1.4 熱交換器 29
3.1.5 其他相關處理器 30
3.2 SOFC系統之模式 31
3.2.1 電池之相關經驗式 31
3.2.2 燃料使用率 34
3.2.3 相關變數定義 35
3.2.4 系統評估方法 37
第4章 SOFC電力系統之架構設計與結果分析 40
4.1 參數設定 40
4.2 傳統濕式預重組SOFC電力系統(Case A) 42
4.2.1 結果分析 43
4.3 串聯式預雙重組SR-DR-SOFC電力系統(Case B) 45
4.3.1 Case B 燃料轉化率結果分析 47
4.3.2 Case B 電效率結果分析 48
4.3.3 Case B CO2排放因子結果分析 50
4.4 串聯式預雙重組DR-SR-SOFC電力系統(Case C) 51
4.4.1 Case C 燃料轉化率結果分析 53
4.4.2 Case C 電效率結果分析 54
4.4.3 Case C CO2排放因子結果分析 57

4.5 並聯式預雙重組SR/DR-SOFC電力系統(Case D) 58
4.5.1 Case D 燃料轉化率結果分析 60
4.5.2 Case D 電效率結果分析 63
4.5.3 Case D CO2排放因子結果分析 68
4.6 最適化結果分析與比較 71
第5章 SOFC電力系統之除水效益 78
5.1 除水傳統濕式預重組SOFC電力系統 78
5.1.1 Dewatering Case A 電效率結果分析 80
5.1.2 Dewatering Case A with RR(AG) 電效率結果分析 81
5.2 除水DR-SR-SOFC with RT(SR) 電力系統 84
5.2.1 Dewatering Case C with RT(SR)電效率結果分析 85
5.3 除水DR-SR-SOFC with RT(SOFC) 電力系統 87
5.3.1 Dewatering Case C with RT(SOFC)電效率結果分析 88
5.4 除水SR/DR-SOFC with RT(SR) 電力系統 91
5.4.1 Dewatering Case D with RT(SR)電效率結果分析 91
5.5 除水SR/DR-SOFC with RT(SOFC) 電力系統 95
5.5.1 Dewatering Case D with RT(SOFC)電效率結果分析 96
5.6 最適化結果分析與比較 99
第6章 結論與未來展望 101
6.1 結論 101
6.2 未來展望 102
符號彙編 103
參考文獻 107
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