臺灣博碩士論文加值系統

自鎳氫電池開發後，由於其具有高電化學性能與安全性、較佳的環境相容性，以及溫度範圍大、生命週期長與自放電率低等特性，鎳氫電池大量取代鎳鎘電池佔據充電電池市場。近年來伴隨著電動車之發展，鎳氫電池大量被使用，亦產生大量廢棄物。
本研究以物質流佈為架構理論，利用物質平衡之觀點，藉由進出口、製造、廢棄及市場流動等相關資料蒐集，建構2014年臺灣地區鎳氫電池之稀有資源物質流佈。最後比較鎳氫電池回收現況與稀有資源儲備制度，以建立鎳氫電池循環再利用管理策略。
結果顯示2014年臺灣地區鎳氫電池進口量為239公噸、出口量為18公噸、產業製造量為779公噸、營業量為760公噸及廢棄量為245公噸。經文獻蒐集法得知，廢鎳氫電池中含有鎳、鈷、錳、鈦、鑭、鈰、釤、釹及鐠等稀有資源，本研究於未考慮回收成本情況下，約有9千萬之回收產值。因此針對鎳氫電池進行回收不僅可以減少污染，亦能減緩資源日益短缺之壓力。

Nickel-metal hydride battery have replaced nickel cadmium battery and occupied the rechargeable battery market, due to its high electrochemical performance, safety, better environmental compatibility, temperature range, long life cycle and low self-discharge characteristics.
This study using material flow for the theoretical basic and mass balance. Analysis the import and export, manufacturing, market trading and waste data to establish the rare resources flow of NiMH battery in 2014 in Taiwan. Finally, comparing recycle status, reserve system and establishing NiMH battery recycling strategies and management system.
The results show that Taiwan imported 239 tons of NiMH battery in 2014 and exported 18 tons of NiMH battery. There are 779 tons of NiMH battery was manufactured, the turnover of NiMH battery in 2014 was 760 tons, and waste reached 245 tons. We learned from literature review that rare resource materials such as nickel, cobalt, manganese, titanium, lanthanum, cerium, samarium, neodymium and praseodymium are present in waste NiMH battery. About 90 million potential output value can be recycled in the NiMH battery in no-cost cases. For this reason, recycling NiMH battery can not only reduce pollution, but also slow down the shortage of resource.

摘要 i
ABSTRACT ii
誌謝 iv
目錄 v
表目錄 vii
圖目錄 viii
第一章 前言 1
1.1研究動機 1
1.2研究目的 2
1.3研究流程與範疇 2
第二章 文獻回顧 5
2.1鎳氫電池產品趨勢 5
2.1.1鎳氫電池產品特性與組成 5
2.1.2國外鎳氫電池產品現況 8
2.1.3國內鎳氫電池產品現況 9
2.2廢鎳氫電池再生處理現況 10
2.2.1廢鎳氫電池稀有資源析出方法 11
2.2.2國外廢鎳氫電池再生處理現況 15
2.2.3國內廢鎳氫電池再生處理現況 18
2.3稀有資源應用剖析 20
2.3.1稀有資源之範疇界定與分布 21
2.3.2國外稀有資源之應用 26
2.3.3國內稀有資源之應用 28
2.4物質流分析理論基礎 30
2.4.1物質流分析定義 30
2.4.2物質流佈分析演進與分類 33
2.4.3國內外物質流佈分析應用研究 35
第三章 研究方法與步驟 38
3.1研究內容與流程 38
3.2物質流佈分析流程與步驟 38
3.2.1物質流流程與步驟 39
3.2.2物質流資料蒐集及模式架構 40
3.3資源化潛勢計算 42
3.3.1文獻蒐集法 42
3.3.2資源化潛勢計算 42
第四章 結果與討論 43
4.1鎳氫電池流佈分析 43
4.1.1進出口量分析 43
4.1.2產業製造量與營業量分析 46
4.1.3廢棄量分析 47
4.2廢鎳氫電池資源化潛勢 49
4.2.1鎳氫電池資源分析 50
4.2.2廢鎳氫電池資源循環潛勢 53
4.2.3廢鎳氫電池產值分析 53
4.3廢鎳氫電池流佈之整合分析 56
4.3.1鎳氫電池物質流分析 57
4.3.2鎳氫電池稀有資源流佈 58
4.3.3綜合評析 59
4.4鎳氫電池資源循環整合 60
4.4.1鎳氫電池回收管理現況比較 60
4.4.2稀有資源儲備制度分析 64
4.4.3鎳氫電池循環再利用管理策略 84
第五章 結論與建議 86
5.1結論 86
5.2建議 87
參考文獻 88

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