臺灣博碩士論文加值系統

為提高室內採光度，減少燈具使用，並使室外景觀得以引入室内空間，多數大型建築常以大面積之連續横向玻璃開窗替代原本各式窄窗。然而，除可見光外，紫外光與近紅外光對玻璃亦具高穿透性，而紫外光輻射可致使皮膚老化、產生皺紋與黑色素，近紅外光可穿透玻璃至建築內部，形成溫室效應，導致空調設備所需耗能增加。此研究以玻璃為基板，大面積連續性刮刀塗佈彈性光子晶體於其上，使所組合而成的智能調光玻璃可以選擇性繞射對人體有害的紫外光及近紅外光，且可因應室內外溫差選擇性繞射近紅外光，夏季時，玻璃可阻擋大部分近紅外光減少室內溫室效應所造成的空調所需損耗；冬季時，玻璃夾層間之乙醇會因Kelvin方程式傾向凝結於多孔性薄膜孔洞中，使近紅外光可穿透玻璃至室內並提高室內溫度，同時保持可見光之高穿透率。此外，其奈米光子晶體結構可以表面改質以具自潔能力，可減少清洗玻璃之費用。

A simple, roll-to-roll compatible doctor blade coating technology for producing three-dimensional highly ordered macroporous polymer membranes is developed. The research describes an invention in using the prepared macroporous polymer films as photonic crystals for large area, low cost, and no energy consumption self-adjusting smart glasses, which are useful for energy control in glazed buildings. This invention is inspired by the heat pipe technology. When the air cavities are filled with a solvent which has the same refractive index as that of the polymer, the macroporous polymer films become completely transparent due to the index matching. When the solvent trapped in the cavities is evaporated by in-situ heating, the sample color changes back to brilliant color. Therefore, once the amount of solvent trapped in the macroporous films can be automatically controlled by difference between indoor and outdoor temperature, the device can make macroporous film self-adjust light transmission. Moreover, the glass surface exhibits superhydrophobic and self-cleaning properties after surface modification.

中文摘要 i
Abstract ii
示意圖目錄 vi
圖目錄 vii
第一章 緒論 1
1.1 前言 1
1.2 研究動機 2
1.3 研究目的與方法 3
1.4 研究架構與流程 4
第二章 文獻回顧 8
2.1 二氧化矽粒子合成 8
2.2 光子晶體相關文獻 9
2.2.1 由上至下製程(Bottom-Up Fabrications) 10
2.2.2 由下至上製程(Top-Down Fabrications) 12
2.3 智能調光玻璃相關文獻 14
2.3.1 被動式動力系統 (Passive dynamical systems) 14
2.3.2 主動式動力系統 (Active dynamical systems) 17
2.4 刮刀塗佈相關文獻 22
2.5 超疏水材料相關文獻 25
第三章 實驗 28
3.1 實驗儀器設備 28
3.2 實驗藥品 29
3.3 實驗步驟 32
3.3.1 製備200奈米二氧化矽膠體粒子 32
3.3.2 製備470奈米二氧化矽膠體粒子 32
3.3.3 製備二氧化矽膠體晶體/ETPTA單體懸浮液 33
3.3.4 刮刀塗佈製備二氧化矽膠體晶體/ETPTA高分子複合材料 33
3.3.5 製備多孔性高分子薄膜 34
3.3.6 製備超疏水多孔性高分子薄膜 34
3.3.7 組裝可繞射紫外光並可調節近紅外光入射之智能玻璃 35
3.4 實驗特性分析 35
3.4.1 活性氧離子蝕刻 35
3.4.2 樣品光學性質之量測 36
3.4.3 組裝後裝置光學性質之量測 36
3.4.4 靜態接觸角、前近接觸角，後退接觸角之量測 36
3.4.5 樣品表面結構之觀測 37
第四章 實驗結果與討論 38
4.1 刮刀塗佈技術 38
4.2 抗近紅外光多孔性高分子薄膜之製備 40
4.2.1 結構影像與分析 41
4.2.2 薄膜光學性質分析 43
4.3 調光裝置調控近紅外光分析 45
4.3.1 裝置光學性質之分析 46
4.3.2 不同量乙醇置入裝置之繞射波長影響 47
4.3.3 裝置填入乙醇之可逆性測試 49
4.4 不同環境溫度對調光裝置之繞射波長影響 50
4.4.1 可繞射近紅外光玻璃之調光機制 50
4.4.2 低環境溫度下智能裝置光學性質 52
4.4.3 高環境溫度下智能裝置光學性質 55
4.5 酒水混合液置入裝置之繞射波長影響 58
4.6 不同光強度對裝置繞射波長之影響 59
4.7 具抗紫外光及抗近紅外光之多孔性高分子薄膜之調光玻璃製備 61
4.7.1 抗紫外光及近紅外光複合玻璃影像與結構分析 62
4.7.2 抗紫外光及近紅外光複合玻璃光學性質分析 65
4.8 具超疏水自潔功能多孔性薄膜之製備 67
4.8.1 薄膜影像與結構分析 68
4.8.2 薄膜靜態水滴接觸角之量測與分析 70
第五章 結論 75
第六章 參考文獻 76

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