本研究以大規模連續性捲揚式刮刀塗佈自組裝技術製備多孔性乙氧基化三羥甲基丙烷三丙烯酸酯(ETPTA)高分子薄膜，於規則排列多孔性薄膜之孔洞內塗佈不同的胺基，形成多孔性胺基/ETPTA高分子複合薄膜，由光學測量及布拉格定律計算其理論值可知，此三維規則排列之多孔性光子晶體可以繞射特定波長的光，實驗驗證二氧化碳會與胺基產生化學反應，並吸附於多孔性薄膜之孔洞中，使繞射之入射光產生紅移現象，證實此多孔性高分子複合薄膜可用於二氧化碳偵測。

Our research reports a scalable and roll-to-roll doctor blade coating technology for self-assembly macroporous ethoxylated trimethylolpropane triacrylate (ETPTA) films. The pores of macroporous films can be coated by chemicals with amine groups to create macroporous composite films. The optical measurements and theoretical predications reveal the as-prepared macroporous photonic crystals exhibit optical diffraction by the three-dimensional ordered based on the Bragg’s diffractive theory. The study demonstrates that CO2 can adsorb on the walls of macroporous films, leading to the redshift of the optical stop bands. The composite macroporous films can use for CO2 detection.

中文摘要i
Abstract ii
目錄 iii
圖目錄 vi
流程圖目錄 viii
表目錄 viii
第一章 緒論 1
1.1 前言 1
1.2 研究動機 2
1.3 研究目的與方法 2
1.4 研究架構與流程 3
第二章 文獻回顧 7
2.1 二氧化矽粒子之合成 7
2.2 光子晶體之概述與製程 8
2.2.1 光子晶體之源起 8
2.2.2 光子晶體之製程 10
2.3 多孔性光子晶體薄膜 16
2.3.1 反蛋白石結構 16
2.3.2 光子晶體感測器 18
2.4 二氧化碳之捕捉 20
2.4.1 二氧化碳之捕捉方法 20
2.4.2 二氧化碳之捕捉反應 22
第三章 實驗方法 25
3.1 實驗儀器與設備 25
3.2 實驗藥品與氣體 27
3.3 實驗步驟 31
3.3.1 製備二氧化矽膠體粒子 31
3.3.2 表面改質之方法 31
3.3.3 製備二氧化矽光子晶體與乙氧基化三羥甲基丙烷三丙烯酸酯高分子複合薄膜 32
3.3.4 製備多孔性乙氧基化三羥甲基丙烷三丙烯酸酯高分子薄膜33
3.3.5 製備二乙烯三胺/乙醇混合液、五亞乙基六胺/乙醇混合液33
3.3.6 製備二乙烯三胺/ETPTA、五亞乙基六胺/ETPTA之多孔性高分子複合薄膜 33
3.3.7 樣品表面結構之分析 34
3.3.8 使用紫外光-可見光-近紅外光光譜儀測量二氧化碳氣體吸附35
第四章 結果與討論 36
4.1 二氧化矽膠體晶體之粒徑結果分析 36
4.2 二氧化矽光子晶體/高分子薄膜之製備 38
4.3 多孔性高分子薄膜之製備 40
4.4 高分子薄膜、二氧化矽/高分子複合薄膜、多孔性高分子薄膜之光學分析 42
4.5 多孔性胺基/高分子複合薄膜之製備 44
4.5.1 多孔性二乙烯三胺/ETPTA之高分子複合薄膜 44
4.5.2 多孔性五亞乙基六胺/ETPTA之高分子複合薄膜 45
4.5.3 二氧化矽/高分子複合薄膜、多孔性高分子薄膜、胺基/多孔性高分子薄膜之光學分析 46
4.5.4 多孔性複合薄膜之化學結構分析 47
4.6 多孔性複合薄膜用於二氧化碳之吸附 49
4.6.1 ETPTA多孔性高分子薄膜之二氧化碳吸附光譜圖 49
4.6.2 同濃度之二乙烯三胺/ETPTA和五亞乙基六胺/ETPTA多孔性複合薄膜之二氧化碳感測光譜圖 50
4.6.3 不同濃度之五亞乙基六胺/ETPTA多孔性複合薄膜之二氧化碳吸附光譜圖 56
4.6.4 不同水蒸氣壓之五亞乙基六胺/ETPTA多孔性複合薄膜之二氧化碳感測光譜圖 58
4.6.5 重複性測試 59
第五章 結論 61
參考文獻 62

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