臺灣博碩士論文加值系統

本研究首先部份蒐集並篩選含介金屬相的多元合金，並探討介金屬相的結構，頻率及成相行為。接著探討以BCC相強化多元合金的可能性。我們在FCC多元合金中添加不同量的Ga元素，透過調控添加元素含量以及時效溫度與時間，改變合金中之BCC析出相的尺寸、體積分率與形貌。期能強化FCC型多元合金但仍維持一定的伸長量。研究結果顯示，在600°C、700°C的時效確實能產生大量BCC析出物，造成顯著強化。在適當條件下可達到不錯的機械性質組合。

First part in this study we collect and filter the multicomponent alloys which has formed intermetallic compounds. And discuss the structure, formed frequency and behavior of the intermetallic compound. Second part we study on the possibility of enhance multicomponent alloys with BCC phase. We try to change the size, volume fraction and morphology of the BCC precipitates. By add variable gallium to FCC type multicomponent alloy, and control the aging temperature or aging time. Expect the elongation of FCC type multicomponent alloy will be maintain, and also get obviously strength improved. According to our research, alloy will get significantly hardening by precipitate massive needle shaped BCC phase at aging temperature 600°C and 700°C. Some alloys will obtain great mechanical properties with appropriate heat treatment.

誌謝 i
摘要 ii
Abstract iii
目錄 iv
圖目錄 vi
表目錄 xi
壹、前言 1
貳、文獻回顧 2
2.1 多元合金 2
2.2 多元合金內的四大效應 3
2.3 多晶材料強化機制 8
2.4 析出硬化機制 18
2.5 非契合型、契合型析出硬化 20
2.6 析出硬化型多元合金之金相、結構及機械性質 22
2.7 Al變量多元合金系統 27
2.8合金回顧 32
2.9 BCC相之衍生結構 40
参、研究動機及實驗步驟 46
3.1 研究動機 46
3.2 實驗設計與流程 47
3.3合金製備 50
3.4 熱處理 50
3.5 拉伸試片製備 50
3.6 相與微結構分析 51
3.7 硬度量測 53
3.8 拉伸試驗 54
第三章參考文獻 56
肆、多元合金中介金屬相之統計分析 57
4.1多元合金中的介金屬相 57
4.2 含介金屬相多元合金列表 58
4.3介金屬相之結構與頻率統計 73
4.4 介金屬相種類與元素種類的關係 75
第四章參考文獻 80
伍、以BCC相強化多元合金 84
5.1 簡介 84
5.2鑄造態金相分析 97
5.3 1100°C固溶處理後金相分析 91
5.4 各合金不同時效條件的硬度分析 95
5.5 部份選定合金時效一天後的微結構與機械性質 100
5.6透過調整製程改善機械性質 118
陸、結論 128
柒、未來研究方向 130

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