臺灣博碩士論文加值系統

整合設計出一系列以雙吡啶基吡咯的有機無機混成染料DPP105、DPP107、DPP108、DPP109，保留有機染料的Donor-π-Acceptor 電子傳遞概念，比較加入推電子基的純有機染料，再加上利用無機光敏材料與金屬配位前後傳遞電子的差異，藉此探討此概念對於新型染料的效率及性質影響，期許此新穎概念在未來能成為染料設計新方向。

we use the dipyridylpyrroleas tridentate ligand core which can chelate to metal such as ruthenium to form organic and inorganic hybrid complex, for the first time in donor-π-acceptor (D–π-A) template. Since, this template retains the D–π-A concept, it will be helpful to explore the concept of the new dye by comparing the performance of pure dye with hybrid organic and inorganic metal complex sensitizer. Perhaps this concept can become a new way of dye design in the future and help guide structural tuning.

目錄
中文摘要…………………………………………………………………………i
英文摘要……………………………………………………………………...…ii
謝誌……….………………………………………………………………….…iii
目錄…….………………………………………………………………….……iv
圖目錄.…………………………………………………………………….……vi
表目錄.…………………………………………………………………….…..viii
一、緒論 1
1-1 前言 1
1-2 太陽能電池簡介 3
1-3太陽能電池發展 5
1-4太陽能電池種類 7
1-4-1矽元素太陽能電池 7
1-4-2化合物太陽能電池 8
1-4-3有機太陽能電池 8
1-5染料敏化太陽能電池 9
1-6染料敏化太陽能電池基本組成 9
1-6-1半導體工作電極 ( Working Electrode ) 10
1-6-2染料 ( Dyes ) 10
1-6-3電解質 ( Electrolyte ) 10
1-6-4對電極 ( Counterelectrodes ) 11
1-7 染料敏化太陽能電池工作原理10,11 11
1-8染料敏化太陽能電池相關參數 12
1-8-1 短路電流 ( Short-Circuit Current, Jsc) 13
1-8-2 開路電壓 ( Open-Circuit Voltage, Voc) 13
1-8-3 填充因子 ( Fill Factor, FF) 13
1-8-4 轉換效率 ( Conversion Efficiency, η) 13
1-9文獻回顧 14
1-9-1 釕金屬光敏染料文獻 14
1-9-2金屬配位光敏染料文獻 15
1-9-3 不同金屬之化合物文獻 18
1-10設計理念 22
1-10-1 設計發想及動機 22
1-10-2 合成及結構探討 24
二、合成與實驗討論 27
2-1 合成探討 27
2-2 光物理性質探討 37
2-3 未來展望 37
2-4實驗步驟 38
三、材料與儀器 50
3-1 實驗儀器 50
3-1-1 核磁共振光譜儀(Nuclear Magnetic Resonance Spectroscopy) 50
3-1-2 紫外光/可見光光譜儀(UV / Vis Spectrophotometer) 50
3-1-3 高解析度質譜儀(High Resolution Mass Spectropeter) 50
3-2 藥品來源 50
參考文獻 51

(1) Chapin, D. M.; Fuller, C. S.; Pearson, G. L. Journal of Applied Physics 1954, 25, 676.
(2) O'Regan, B.; Gratzel, M. Nature 1991, 353, 737.
(3) Sariciftci, N. S.; Smilowitz, L.; Heeger, A. J.; Wudl, F. Science 1992, 258, 1474.
(4) Oster, G.; Bellin, J. S.; Kimball, R. W.; Schrader, M. E. Journal of the American Chemical Society 1959, 81, 5095.
(5) Chaberek, S.; Shepp, A.; Allen, R. J. The Journal of Physical Chemistry 1965, 69, 641.
(6) Nazeeruddin, M. K.; De Angelis, F.; Fantacci, S.; Selloni, A.; Viscardi, G.; Liska, P.; Ito, S.; Takeru, B.; Grätzel, M. Journal of the American Chemical Society 2005, 127, 16835.
(7) Nazeeruddin, M. K.; Péchy, P.; Renouard, T.; Zakeeruddin, S. M.; Humphry-Baker, R.; Comte, P.; Liska, P.; Cevey, L.; Costa, E.; Shklover, V.; Spiccia, L.; Deacon, G. B.; Bignozzi, C. A.; Grätzel, M. Journal of the American Chemical Society 2001, 123, 1613.
(8) Nusbaumer, H.; Zakeeruddin, S. M.; Moser, J.-E.; Grätzel, M. Chemistry – A European Journal 2003, 9, 3756.
(9) Zhang, Q.; Myers, D.; Lan, J.; Jenekhe, S. A.; Cao, G. Physical Chemistry Chemical Physics 2012, 14, 14982.
(10) Durrant, J. R.; Haque, S. A. Nat Mater 2003, 2, 362.
(11) Reynal, A.; Palomares, E. European Journal of Inorganic Chemistry 2011, 2011, 4509.
(12) Anderson, S.; Constable, E. C.; Dare-Edwards, M. P.; Goodenough, J. B.; Hamnett, A.; Seddon, K. R.; Wright, R. D. Nature 1979, 280, 571.
(13) Desilvestro, J.; Graetzel, M.; Kavan, L.; Moser, J.; Augustynski, J. Journal of the American Chemical Society 1985, 107, 2988.
(14) Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.; Mueller, E.; Liska, P.; Vlachopoulos, N.; Graetzel, M. Journal of the American Chemical Society 1993, 115, 6382.
(15) K. Nazeeruddin, M.; Pechy, P.; Gratzel, M. Chemical Communications 1997, 1705.
(16) Campbell, W. M.; Jolley, K. W.; Wagner, P.; Wagner, K.; Walsh, P. J.; Gordon, K. C.; Schmidt-Mende, L.; Nazeeruddin, M. K.; Wang, Q.; Grätzel, M.; Officer, D. L. The Journal of Physical Chemistry C 2007, 111, 11760.
(17) Tang, Y.; Wang, Y.; Li, X.; Ågren, H.; Zhu, W.-H.; Xie, Y. ACS Applied Materials & Interfaces 2015, 7, 27976.
(18) Hewat, T. E.; Yellowlees, L. J.; Robertson, N. Dalton Transactions 2014, 43, 4127.
(19) Brennan, B. J.; Lam, Y. C.; Kim, P. M.; Zhang, X.; Brudvig, G. W. ACS Applied Materials & Interfaces 2015, 7, 16124.
(20) Sakamoto, R.; Iwashima, T.; Tsuchiya, M.; Toyoda, R.; Matsuoka, R.; Kogel, J. F.; Kusaka, S.; Hoshiko, K.; Yagi, T.; Nagayama, T.; Nishihara, H. Journal of Materials Chemistry A 2015, 3, 15357.
(21) Toyoda, R.; Tsuchiya, M.; Sakamoto, R.; Matsuoka, R.; Wu, K.-H.; Hattori, Y.; Nishihara, H. Dalton Transactions 2015, 44, 15103.
(22) Hegde, V.; Madhukar, P.; Madura, J. D.; Thummel, R. P. Journal of the American Chemical Society 1990, 112, 4549.
(23) Lehuede, J.; Mettey, Y.; Vierfond, J. M. Synthetic Communications 1996, 26, 793.
(24) Bai, Y.; Xiang, S.; Leow, M. L.; Liu, X.-W. Chemical Communications 2014, 50, 6168.
(25) Ciszek, J. W.; Keane, Z. K.; Cheng, L.; Stewart, M. P.; Yu, L. H.; Natelson, D.; Tour, J. M. Journal of the American Chemical Society 2006, 128, 3179.