臺灣博碩士論文加值系統

以環三聚藜烴為基礎的分子籠可與市售之Sc3N@C80 形成準囚籠錯合物，藉此有效提升Sc3N@C80 在氘-氯仿中的溶解度。該金屬富勒烯的兩結構異構物 (Sc3N@D5h-C80 與 Sc3N@Ih-C80) 被包覆於分子籠內後，可在1H 及13C NMR 光譜中表現不同的特徵訊號，無須使用13C-濃化的樣品即可直接鑑定其結構異構物。

A cyclotriveratrylene-based molecular cage forms hemicarceplexes that significantly increase the solubility of commercially available Sc3N@C80 in CDCl3. When incarcerated within the molecular cage, the two structural isomers of this metallofullerene, Sc3N@D5h-C80 and Sc3N@Ih-C80, displayed characteristic signals in both 1H and 13C NMR spectra, allowing direct identification of each isomer without the need to enrich the sample with 13C atoms.

摘要 ..................................................................................... I
Abstract .............................................................................. II
論文發表 ............................................................................ III
目錄 ....................................................................................V
圖目錄 ...............................................................................VII
表目錄 ..............................................................................VIII
流程目錄 ........................................................................... IX
第一章 ................................................................................ 1
1.1 簡介 .............................................................................. 2
1.1.1 超分子化學 ................................................................ 2
1.1.2 富勒烯與金屬富勒烯 .................................................. 3
1.1.3 囚籠與環三聚藜烴 ..................................................... 4
1.1.4 環三聚藜烴與富勒烯 .................................................. 5
1.2 研究動機 ....................................................................... 8
1.3 分子籠設計與準囚籠錯合物之合成 ................................ 9
1.4 (Sc3N@C80)@4 的 1H 及 13C NMR 光譜................. 14
1.5 結論 ............................................................................. 17
第二章 ............................................................................... 19
2.1 車輪烷簡介 .................................................................. 20
2.2 以尿素為辨識單元的車輪烷 ......................................... 22
2.3 研究動機 ...................................................................... 25
2.4 大環分子之合成與鍵結測試 ......................................... 26
2.5 結論 ............................................................................. 30
參考文獻 ............................................................................ 31
附錄 1 ................................................................................ 34
附錄 2 ................................................................................ 56

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