臺灣博碩士論文加值系統

本研究採用靜態式總壓汽液量測裝置，完成13組混合物系統於恆溫下之汽液相平衡數據量測，這些混合物分別為hexane + 3-methylsulfolane、heptane + 3-methylsulfolane、octane + 3-methylsulfolane、nonane + 3-methylsulfolane、cyclohexane + 3-methylsulfolane、methylcyclopentane + 3-methylsulfolane、methylcyclohexane + 3-methylsulfolane、benzene + 3-methylsulfolane、toluene + 3-methylsulfolane、p-xylene + 3-methylsulfolane、o-xylene + 3-methylsulfolane、m-xylene + 3-methylsulfolane、1,2,4-trimethylbenzene + 3-methylsulfolane，量測之溫度包括363.15 K、393.15 K、433.15 K與473.15 K。本實驗所量得之汽液相平衡數據分別以NRTL-ideal與NRTL-HOC模式關聯，一般而言，計算值與實驗數據相符程度高，且兩模式之計算值差異不大。

In the study, the total pressure method was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of hexane + 3-methylsulfolane, heptane + 3-methylsulfolane, octane + 3-methylsulfolane, nonane + 3-methylsulfolane, cyclohexane + 3-methylsulfolane, methylcyclopentane + 3-methylsulfolane, methylcyclohexane + 3-methylsulfolane, benzene + 3-methylsulfolane, toluene + 3-methylsulfolane, p-xylene + 3-methylsulfolane, o-xylene + 3-methylsulfolane, m-xylene + 3-methylsulfolane, 1,2,4-trimethylbenzene + 3-methylsulfolane at 363.15 K, 393.15 K, 433.15 K, 473.15 K. Both NRTL-ideal and NRTL-HOC models were applied to correlate the VLE data for each binary system. Generally, the calculated results agree well with the experimental values, and the correlated results from both NRTL-ideal and NRTL-HOC models are not much different.

摘要
Abstract
誌謝
目錄
表目錄
圖目錄
第一章 緒論
第二章 汽液相平衡量測
第三章 相平衡研究之模式關聯
第四章 結論與建議
參考文獻
符號說明

Chemistry WebBook, the National Institute of Standards and Technology (NIST), http://webbook.nist.gov/chemistry/, USA.
Coca, J. and Pis, J. J., Effect of morpholine on the vapor-liquid equilibrium of the system methylcyclohexane-toluene. J. Chem. Eng. Data, 24, 103-105 (1979).
Deshpande, A. K. and Lu, B. C.-Y., Vapor-liquid equilibrium of toluene-n-octane at 760 mm Hg. Indian J. Technol., 1, 403-404 (1963).
Fink, J. K., Guide to the practical use of chemicals in refineries and pipelines, Gulf Professional Publishing, Houston, Texas (2016).
Gaile, A. A., Development and improvement of extraction processes for separation and purification of petroleum products. Russ. J. Appl. Chem., 81, 1311-1324 (2008).
Gaile, A. A., Somov, V. E., Semenov, L. V., Zalishchevskii, G. D., Varshavskii, O. M., Koldobskaya, L. L. and Kaifadzhyan, E. A., Extraction technology for production of environmentally clean diesel and jet fuels. Chem. Technol. Fuels Oils, 35, 257-263 (1999).
Gupta, B. S. and Lee, M. J., Isobaric vapor-liquid equilibrium for the binary mixtures of nonane with cyclohexane, toluene, m-xylene, or p-xylene at 101.3 kPa. Fluid Phase Equilib., 313, 190-195 (2011).
Hamid, S. H. and Ali, M. A., Comparative study of solvents for the extraction of aromatics from naphtha. Energ. Source., 18, 65-84 (1986).
Hayden, J. G. and O' Connell, J. P., A generalized method for predicting second virial coefficients. Ind. Eng. Chem. Process Des. Dev., 14, 209-216 (1975).

Ledyashova, G. E. and Dorogochinskii, A. Z., Aqueous dimethylformamide, a solvent for aromatic hydrocarbons. Chem. Technol. Fuels Oils, 2, 181-184 (1966).
Ledyashova, G. E. and Dorogochinskii, A. Z., Mono- and dimethylformamides, solvents for low molecular weight aromatic hydrocarbons. Chem. Technol. Fuels Oils, 2, 303-306 (1966).
Lee, F. M., Use of organic sulfones as the extractive distillation solvent for aromatics recovery. Ind. Eng. Chem. Process Des. Dev., 25, 949-957 (1986).
Lin, W. C., Studies on the extraction of aromatics from C9+ oil. J. Chem. Eng. Jpn., 35, 1257-1262 (2002).
Meindersma, G.W., Extraction of aromatics from naphtha with ionic liquids : from solvent development to pilot RDC evaluation, University of Twente, Enschede, Netherlands (2005).
Mihkelson, V., Kirss, H., Kudryavtseva, L. S. and Eisen, O. G., Vapour—liquid equilibrium T—x measurements by a new semi-micro method. Fluid Phase Equilib., 1, 201-209 (1977).
Myers, H. S., Binary mixtures of naphthenes and aromatics. Ind. Eng. Chem., 48, 1104-1108 (1956).
Myers, H. S., Vapor-liquid equilibrium data for binary mixtures of paraffins and aromatics. Ind. Eng. Chem., 47, 2215-2219 (1955).
Pavlyuk, N. F., Gaile, A. A. and Semenov, L. V., Extractive dearomatization of liquid n-paraffins by mixture of acetonitrile and ethylene glycol. Chem. Technol. Fuels Oils, 17, 673-675 (1981).
Peng, D.-Y. and Robinson, D. B., A new two-constant equation of state. Ind. Eng. Chem. Fundam., 15, 59-64 (1976).

Prausnitz, J. M., Lichtenthaler, R. N. and de Azevedo, E. G., Molecular thermodynamics of fluid-phase equilibria, 3rd edition, Prentice-Hall, Englewood Cliffs, New Jersey (1999).
Renon, H. and Prausnitz, J. M., Local compositions in thermodynamic excess functions for liquid mixtures. AIChE J., 14, 135-144 (1968).
Sharma, M., Sharma, P. and Kim, J. N., Solvent extraction of aromatic components from petroleum derived fuels: a perspective review. RSC Adv., 3, 10103-10126 (2013).
Soave, G., Equilibrium Constants from a modified Redlich-Kwong equation of state. Chem. Eng. Sci., 27, 1197-1203 (1972).
Stellman, J. M., Encyclopaedia of occupational health and safety, 4th edition, International Labour Organization, Geneva, Switzerland (1998).
Viswanathan, B., Energy sources: fundamentals of chemical conversion processes and applications, Elsevier, Amsterdam, Netherlands (2016).
Zhurba, A. S., Levenets, V. P., Bondar, A. E. and Sabirova, G. V., Comparison of efficiencies of various solvents used in dearomatizing kerosine distillates from East Ukrainian crudes. Chem. Technol. Fuels Oils, 11, 923-927 (1975).
柯經緯、陳萬容、賴宗成、蔡銘璋、薛虹紅、莊秀淓、黃正彥、袁煥屏、李明禮、陳維德，「芳香烴萃取工場之貧溶劑提純研究」，石油季刊，第53卷，第1期（2017）。
李世雄，「六輕計畫相關製程」，出國報告，台灣中油公司林園石化廠，台灣（2013）。
蔡信行，「最新化工製程及材料」，新文京開發，台灣（2005）。