臺灣博碩士論文加值系統

本文目的在於探討化石柴油分別混合綠色柴油與單酸甘油酯生質柴油對於引擎零組件磨潤性能的影響。利用Cameron-Plint TE-77往復式磨耗試驗機在不同溫度條件下進行滑動磨耗試驗，分別根據摩擦係數、磨耗型態、磨痕深度進行測試油品的磨潤性能評估。此外，利用SEM、EDS等儀器進行磨耗表面形貌觀察與表面膜成份分析。除了磨耗試驗外，也同時進行靜態腐蝕實驗，藉以瞭解生質柴油在不同溫度情況下對引擎零組件的腐蝕行為。
試驗結果顯示，綠色柴油在不同試驗溫度的條件下，添加10%時有最佳的磨潤性能，當綠色柴油含量20%以上時，摩擦係數有明顯的下降。但是，高濃度綠色柴油在摩擦表面產生磨潤化學反應使其磨耗量高於適當濃度之混合油品。
在10°C試驗條件下，含單酸甘油酯生質柴油的混合油品其抗磨耗能力主要由酯類的物理吸附膜與局部液動壓效應的強弱所主導；而在80°C試驗條件下，由於摩擦表面化學反應速率較快，因此可在摩擦表面形成較佳的化學反應膜保護表面。但單酸甘油酯濃度較高之油品，其腐蝕行為也相對得較為劇烈。

This paper aims to investigate the effects of biodiesel (Monoglyceride,MG) and Hydrotreated Vegetable Oil (HVO) blended with fossil diesel on the tribological performance of engine components. Sliding wear test are performed under different test temperature by Cameron-Plint TE77 reciprocating test rig. According to friction coefficient, wear mechanism and wear depth of specimen evaluate the tribological performance of the different tests results. In addition, scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS) were separately used to observe the morphology of wear specimens and identify the composition of surface. In addition to the wear test, static corrosion experiments were carried out at the same time to understand the corrosion behavior of the engine components at different temperatures.
The tests results demonstrate that the tribological behavior of the blend fuel content with 10% green diesel was superior to that of the other testing blended fuels. When the content of green diesel is more than 20%, the friction coefficient of the specimen declined obviously. Test in the green diesel, a tribochemical reaction takes place on the rubbing surface.
The anti-wear ability is mainly by physical adsorption capacity and locallyhydrodynamic effects at 10°C; while at 80°C, due to the rapid chemical reaction rate on the rubbing surface, it is possible to form a better chemical reaction film on the rubbing surface to prevent the direct contact of rough surface during wear test. As the higher concentration of monoglyceride oil, the corrosion behavior is relatively intense.

摘要 I
Abstract II
致謝 III
目錄 IV
表目錄 VI
圖目錄 VII
第一章 緒論 1
1.1 研究動機 1
1.2 模型構想簡介 3
第二章 文獻回顧 4
2.1生質柴油種類與製造方法 4
2.2生質柴油的特性 5
2.2.1 亞麻籽油(linseed oil) 7
2.2.2 大豆油(soybean oil) 8
2.2.3 油菜籽油(rapeseed oil) 10
2.2.4 蓖麻油(castor oil) 10
2.2.5 其他種類生質油相關研究 11
2.3腐蝕(Corrosion) 15
2.3.1腐蝕定義 15
2.3.2腐蝕型態 15
2.3.3腐蝕率計算 17
2.4潤滑模式之分類【63】 18
2.5磨耗機構 23
2.6固體表面與接觸型態 28
2.6.1表面粗糙度 28
2.6.2接觸應力計算 29
第三章 實驗儀器與方法 31
3.1 實驗儀器 31
3.2 分析儀器 38
3.3 試片規格 39
3.4 試驗用油 43
3.5 試驗條件 47
3.6 試驗步驟 50
第四章 結果與討論 54
4.1 靜態腐蝕實驗 55
4.1.1 靜態腐蝕試驗後之表面形貌分析 55
4.1.2 靜態腐蝕試驗之腐蝕率比較 67
4.2 生質柴油往復運動下的磨潤性能評估 74
4.2.1 含不同濃度綠色柴油之混合油在室溫25°C的磨潤性能評估 74
4.2.2 含不同濃度綠色柴油之混合油在油溫80°C的磨潤性能評估 84
4.2.3 綜合討論-綠色柴油的磨痕深度比較 93
4.2.4 FAME0.1單酸甘油酯生質柴油之混合油於不同溫度的磨潤性能評估 96
4.2.5 FAME0.2單酸甘油酯生質柴油之混合油於不同溫度的磨潤性能評估 109
4.2.6 FAME0.4單酸甘油酯生質柴油之混合油於不同溫度的磨潤性能評估 119
4.2.7 FAME0.6單酸甘油酯生質柴油之混合油於不同溫度的磨潤性能評估 129
4.2.8 綜合討論-不同濃度之FAME單酸甘油酯生質柴油之磨潤性能評估 139
第五章 結論 142
5.1 結論 142
5.2 建議 144
參考文獻 145
附錄 151

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