臺灣博碩士論文加值系統

本研究在探討高黏度壓克力系光硬化性樹脂(OCA)其光學性能、固化性能。實驗結果發現，OCA經TGA測試發現不同著照光硬化程度之OCA會隨著能量變強時，裂解溫度有些微上升；但在照光能量過多時，便會造成分子連斷裂進而產生較低溫之裂解溫度；在FTIR分析結果OCA會因照光而逐漸聚合；UV-vis之分析檢測可確認OCA之光硬化波段需為UV-A光源；經由photo-RPT之流變行為分析可有效了解OCA之光硬化行為及最試化條件。
本研究使用環狀烯烴共聚物薄膜(COP film)及聚對苯二甲酸乙二酯薄膜(PET film)為軟性基材，利用電暈與大氣電漿表面處理方式，增加表面薄膜基材極性，找出最佳接著參數，以探討其表面性質之改變(如表面能、表面鍵結等)，接著以水接觸角量測其親疏水性、X光電子能譜儀分析經電漿處理後之表面官能基組成變化。分析結果發現，經表面處理後之軟性基材會獲得較低的接觸角數值，接觸角大約下降了26~35%。XPS分析結果，皆含氧基團如羰基（C = O鍵）和羧基（OC = O）等親水性官能基經過表面處理後於基材表面上產生。
再者，利用CP5196塗佈於基材上，測試表面處理對基材/OCA界面相互作用力影響效應。剝離強度試驗依據ASTM D1876規範製備，經紫外光乾燥後進行機械性質測試。經電暈表面改質之基材在剝離強度測試上發現，其剝離強度都增強了15~51%；經大氣電漿表面改質其剝離強度則增強了33~49%，其中大氣電漿表面處理方式優於電暈表面處理；PET film之剝離強度高於COP film之剝離強度，其照光硬化的最佳能量皆為10000mJ/cm2。

In this study, the optical properties, curing properties of photohardenable resin (OCA) with high viscosity were studied. The results show that OCA has found that the OCA of the OCA will increase slightly with the increase of the degree of photo hardening, and the cleavage temperature will increase slightly when the energy becomes stronger. However, when the irradiation energy is too much, it will cause the molecular interruption to produce the lower temperature cracking temperature; In the FTIR analysis results OCA will be due to light and gradually polymerization ; UV-vis analysis can confirm that OCA light hardening band need to be UV-A light source; The rheological behavior of the OCA can be effectively understood by the rheological behavior analysis of photo-RPT.
In this study, COP film and PET film were used as soft substrates. The surface of the surface film was increased by corona and atmospheric plasma surface treatment. (Such as surface energy, surface bonding, etc.), and then the hydrophobic water was measured with water contact angle. The X-ray photoelectron spectroscopy was used to analyze the surface function after plasma treatment. Base composition changes. The results show that the surface of the soft substrate will get a lower contact angle values, the contact angle decreased by about 26 to 35%. As a result of XPS analysis, hydrophilic functional groups such as carbonyl groups such as carbonyl (C = O bond) and carboxyl group (OC = O) are surface-treated to produce on the surface of the substrate.
Furthermore, the effect of surface treatment on the interaction of substrate/OCA interface was tested by CP5196 coating on the substrate. The peel strength test was prepared according to ASTM D1876 and subjected to mechanical testing by UV drying. The peel strength of the substrate modified by corona surface was improved by 15 ~ 51% on the peel strength test. The peel strength of the plasma was increased by 33 ~ 49%, and the surface of the atmospheric plasma The stripping strength of PET film is higher than that of COP film, and the optimum energy for photohardening is 10000mJ/cm2.

摘要 I
Abstract III
誌謝 V
目錄 VIII
圖目錄 XII
表目錄 XVI
第一章 緒論 1
1.1 前言 1
1.2 研究動機與目的 4
1.3 各章提要 5
第二章 相關理論及文獻回顧 6
2.1 紫外光硬化原理 6
2.1.1 紫外光硬化原理簡介 6
2.1.2 紫外光硬化型樹脂之組成[6],[7],[8],[9] 6
2.1.3 UV光硬化反應機制 14
2.2 高分子材料簡介 17
2.2.1 光硬化型樹脂 18
2.2.1.1 光硬化型樹脂之源起 18
2.2.1.2 壓克力系光硬化型樹脂之簡介[42],[43],[21] 20
2.2.1.3 壓克力系光硬化型樹脂之特性 21
2.2.2 環狀烯烴共聚合物 25
2.2.2.1 環狀烯烴共聚合物簡介[52],[53] 25
2.2.2.2 環狀烯烴共聚物(COP)材料的特性[53] 26
2.2.2.3 環狀烯烴共聚物(COP)薄膜之表面改質研究 29
2.2.3 聚對苯二甲酸乙二酯 30
2.2.3.1聚對苯二甲酸乙二酯簡介[57],[58] 30
2.2.3.2聚對苯二甲酸乙二酯(PET)薄膜材料的特性 31
2.2.3.3 聚對苯二甲酸乙二酯(PET)薄膜之表面改質研究 31
2.3 高分子材料表面改質 34
2.4 電漿簡介 37
2.4.1 電漿原理[76] 38
2.4.1.1 電漿的基本碰撞反應 40
2.4.2 電漿分類(以溫度及壓力來區分) 43
2.4.3 電漿分類(以系統來區分) 45
第三章 實驗材料、儀器與方法 51
3.1 實驗材料 51
3.2 實驗儀器 52
3.3 實驗流程 53
3.3.1 實驗架構 53
3.3.2 試片製作 54
3.4 實驗項目 56
3.4.1 熱性質 56
熱重損失分析儀 (TGA) 56
3.4.2 光硬化流變行為分析 57
剛性擺錘振動減衰儀 (RPT) 57
3.4.1 力學性質 60
萬能拉力試驗機(正向力、剪切力、剝離強度) 60
3.4.1 光學性質 61
紫外光-可見光/近紅外光分析儀 (UV.VIS/NIR) 61
3.4.2 鑑定分析 62
水滴接觸角量測儀 (Contact angle) 62
傅立葉紅外線光譜儀 (FTIR) 66
X射線光電子能譜儀 (XPS) 68
第四章 實驗結果與討論 71
4.1 原物料(CP5196)基本物性分析 71
4.1.1 熱重損失分析儀(TGA) 71
4.1.2 傅立葉紅外線光譜儀 (FTIR) 74
4.1.3 紫外光-可見光/近紅外光分析儀 (UV.VIS/NIR) 75
4.1.4 剛性擺錘振動減衰儀(RPT) 76
4.2 機械性質(Mechanical properties) 81
4.2.1 力學性質(軟性基材) 81
4.3 表面處理效果鑑定 87
4.3.1 接觸角(contact angle) 87
4.3.2 X射線光電子能譜儀 (XPS) 92
第五章 結論與未來展望 101
參考文獻 103

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