臺灣博碩士論文加值系統

質子交換膜水電解器內部的去離子水流速、去離子水溫度、電壓及電流四種內部物理數據對質子交換膜水電解器的性能與壽命有著關鍵性的影響。去離子水的流速太低會使質子交換膜水電解器的產氫效率變低，而流速太高又有膜電極組(Membrane Electrode Assembly, MEA)破孔的風險。去離子水的溫度太低達不到MEA的工作溫度也會使質子交換膜水電解器的產氫效率變低，而溫度太高也有可能破壞MEA。因此找到最適當的工作條件是本研究的重點。
本研究利用微機電系統(Micro-electro-mechanical systems, MEMS)技術開發出具有流量、溫度、電壓與電流的可撓式整合型微感測器並嵌入質子交換膜水電解器內部即時微觀感測與診斷。透過可撓式整合型微感測器所擷取的內部物理資訊即可找出最適合質子交換膜水電解器的工作參數。對提升質子交換膜水電解器的產氫效率與工作壽命有很大的幫助。

The four internal physical data of proton exchange membrane water electrolysis, including the DI water flow velocity, DI water temperature, voltage and current, have critical effect on the performance and life of proton exchange membrane water electrolysis. If the flow velocity of DI water is too low, the hydrogen production efficiency of proton exchange membrane water electrolysis is low, but the MEA may be breached if the flow velocity is too high. The working temperature of MEA is failed if the temperature of DI water is too low, the hydrogen production efficiency of proton exchange membrane water electrolysis is also reduced, and the MEA may be damaged if the temperature is too high. Therefore, the key point of this study is to find out the optimal working conditions.
This study uses Micro-electro-mechanical systems (MEMS) technology to develop a flexible integrated microsensor for flow, temperature, voltage and current, which is embedded in the proton exchange membrane water electrolysis for real-time microscopic sensing and diagnosis. The optimal working parameters for proton exchange membrane water electrolysis can be found out of the internal physical information extracted by the flexible integrated microsensor. It is very helpful to enhancing the hydrogen production efficiency and operating life of proton exchange membrane water electrolysis

目錄
封面 ..…………………………………………………………………… i
書名頁 ..………………………………………………………………... ii
論文口試委員審定書 ..…………………………………………………. iii
授權書 ..……………………………………………………….………. iv
中文摘要 ..…………………………………………………………..…. v
英文摘要 ..……………………………………………………….……. vi
目錄 ………………………………………………………..…………. viii
圖目錄 …………………………………………………………………. xi
表目錄 ………………………………………………………………… xv
第一章 緒論 1
1.1 前言 1
1.2 燃料電池 5
1.3 質子交換膜水電解器 7
1.4 研究背景與目的 8
1.5 文獻回顧 10
1.5.1 質子交換膜水電解器設計及測試 10
1.5.2 流量診斷 14
1.5.3 溫度診斷 18
1.5.4 電壓診斷 21
1.5.5 電流診斷 24
1.6 研究方法 27

第二章 可撓式整合型微感測器之設計與製程開發 29
2.1 可撓式整合型微感測器之感測原理 29
2.1.1 微流量感測器 29
2.1.2 微溫度感測器 31
2.1.3 微電壓感測器 34
2.1.4 微電流感測器 34
2.2 可撓式整合型微感測器之整合設計 35
2.3 可撓式整合型微感測器之製作流程 36
2.3.1 濕蝕刻 37
第三章 質子交換膜水電解器 46
3.1 端板與集電板 46
3.2 雙極板 48
3.2.1 雙極板流道設計 48
3.2.2 雙極板材料選擇 49
3.3 膜電極組 50
3.4 質子交換膜水電解器組裝程序 53
3.5 質子交換膜水電解器測試設備 54
第四章 整合質子交換膜水電解器與可撓式整合型微感測器 56
4.1 可撓式整合型微感測器之封裝 56
4.2 可撓式整合型微感測器之可靠度測試 57
4.2.1 微溫度感測器之可靠度測試 (溫度校正) 58
4.2.2 微流量感測器之可靠度測試 (流量校正) 61
4.3 質子交換膜水電解器活化 63
4.4 可撓式整合型微感測器嵌入於質子交換膜水電解器 64
第五章 質子交換膜水電解器之即時微觀診斷 66
5.1 質子交換膜水電解器性能測試 66
5.1.1 溫度測試 66
5.1.2 流量測試 67
5.2 質子交換膜水電解器測試環境 68
5.2.1 質子交換膜水電解器之局部流量分佈 68
5.2.2 質子交換膜水電解器之局部溫度分佈 70
5.2.3 質子交換膜水電解器之局部電壓分佈 72
5.2.4 質子交換膜水電解器之局部電流分佈 73
5.3 產氫量 75
第六章 結論與未來展望 76
6.1 結論 76
6.2 未來展望 76

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