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研究生:賴昶岳
研究生(外文):Chang-Yue Lai
論文名稱:靜電紡絲製備聚偏氟乙烯/聚乙烯吡咯烷酮/銀沸石複合纖維膜之性質探討
論文名稱(外文):A research of preparation and characterization of PVDF/PVP/Ag-MCM-41 composite fibers by electrostatic spinning technology
指導教授:邱維銘
指導教授(外文):Wei-Ming Chiou
學位類別:碩士
校院名稱:國立勤益科技大學
系所名稱:化工與材料工程系
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2018
畢業學年度:106
語文別:中文
論文頁數:128
中文關鍵詞:聚偏氟乙烯聚乙烯吡咯烷酮銀沸石靜電紡絲PM2.5
外文關鍵詞:polyvinylidene fluoridepolyvinyl pyrrolidonesilver zeoliteelectrostatic spinningPM2.5
相關次數:
  • 被引用被引用:2
  • 點閱點閱:148
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  • 下載下載:8
  • 收藏至我的研究室書目清單書目收藏:0
本研究利用溶膠-凝膠法製備中孔MCM-41沸石,再利用氨蒸發沉澱法將銀粒子沉澱於MCM-41載體上,製備出功能性粉末(Ag-MCM-41),並由各項儀器多方面佐證合成結果。透過靜電紡絲技術製備出聚偏氟乙烯(PVDF)/聚乙烯吡咯烷酮(PVP)/銀沸石(Ag-MCM-41)複合纖維薄膜,探討不同比例之Ag-MCM-41對纖維之影響與效果。
由研究結果得知,當添加適當比例之Ag-MCM-41,纖維型態、機械強度、熱裂解溫度與水接觸角都有明顯上升,且PM2.5的過濾率可高達98.5%還能吸附污染物燃燒時所產生的化學物質,且製備出含有Ag-MCM-41之複合薄膜還具有抑菌之效果,使此複合薄膜達到淨化空氣且抑菌雙效果。
In this study, using the sol-gel method to prepare the mesoporous MCM-41 zeolite, the silver particles were deposited on the MCM-41 carrier by ammonia evaporation precipitation method, and the functional powder (Ag-MCM-41) was prepared, and by various instruments evidence synthesis results in many aspects.
By the research results indicate that when adding appropriate proportion of Ag - MCM - 41, fiber type, mechanical strength, thermal cracking temperature and water contact Angle has increased dramatically, and PM2.5 filtration rate can be as high as 98.5% and can absorb pollutants produced by chemical during burning, containing Ag - MCM - 41 preparation of composite membrane has antibacterial effect, make the composite film to purify air and bacteriostatic effect.
摘要......I
Abstract......II
致謝......III
目錄......V
圖目錄......XI
表目錄......XVIII
第一章 緒論......1
1-1 前言......1
1-2 研究動機......6
1-3 研究目的......8
第二章 文獻回顧......10
2-1 空氣汙染......10
2-1-1 空氣汙染來源......10
2-1-2 空氣汙染的影響......12
2-1-3 空氣品質指標......16
2-2 空氣過濾......17
2-2-1 空氣過濾指標......23
2-3 奈米材料介紹......24
2-4 奈米纖維簡介......27
2-5 靜電紡絲簡介......28
2-5-1 靜電紡絲原理與特性......28
2-6 沸石......33
2-6-1 沸石結構......34
2-6-2 沸石總類......36
2-6-3 MCM–41沸石應用......41
2-7 銀沸石......44
2-7-1 奈米銀殺菌機制......48
2-8 聚偏氟乙烯......49
2-9 聚乙烯吡咯烷酮......51
第三章 實驗方法......53
3-1 實驗藥品......53
3-2 實驗儀器......54
3-2-1 靜電紡絲機(Electrostatic spinning machine) ......54
3-2-2 高溫鍛燒爐......55
3-2-3 其他實驗設備......56
3-3 分析儀器......57
3-3-1 X–射線繞射分析(X–ray diffraction,XRD)......57
3-3-2 紫外光可見光光譜儀(UV–Vis Spectrophotometer,UV-Vis)......58
3-3-3 比表面積分析與孔隙度分析儀(N2Adsorption/Desorption,BET)......59
3-3-4 場發射掃描式電子顯微鏡 (Field–emission Scanning Electron Microscope,FE-SEM)......60
3-3-5 材料試驗儀(Materials Testing machines)......61
3-3-6 熱重分析儀(Thermogravimeteric analysis,TGA) ......62
3-3-7 接觸角計(Water contact angel )......63
3-3-8 傅立葉轉換紅外光譜儀(Fourier Transform infrared spectroscopy)......64
3-3-9 手持式微粒子計數器(TSI AEROTRAKTM 9303)......65
3-3-10 簡易空氣過濾裝置......66
3-4 實驗流程......68
3-4-1 實驗架構......68
3-4-2 沸石合成......69
3-4-3 銀沸石合成......70
3-4-4 電紡纖維製備......71
3-4-5 實驗方法......72
第四章 結果與討論......74
4-1 沸石(MCM-41) 之鑑定......74
4-1-1 場發射掃描式電子顯微鏡分析......75
4-1-2 穿透式電子顯微鏡分析......76
4-1-3 比表面積分析......76
4-1-4 X-射線繞射分析......78
4-2 銀沸石(Ag-MCM-41)之鑑定......79
4-2-1 穿透式電子顯微鏡分析......79
4-2-2 比表面積分析......80
4-2-3 EDS元素分析......82
4-2-4 X-射線繞射分析......82
4-2-5 紫外光可見光分析......84
4-3 複合纖維薄膜之分析......85
4-3-1 場發射掃描式電子顯微鏡分析......86
4-3-2 EDS元素分析......91
4-3-3 水接觸角分析......91
4-3-4 材料試驗儀分析......94
4-3-5 熱重性質分析......96
4-4 複合纖維空氣過濾分析......98
4-4-1 複合纖維透氣率比較......98
4-4-2 線香與香菸燃燒後粒子數檢測......100
4-4-3 空氣過濾後之複合纖維SEM圖......104
4-4-4 空氣過濾後之複合纖維EDS元素分析......108
4-4-5 空氣過濾後之複合纖維FTIR官能基分析......111
4-5 複合纖維抑菌測試......112
第五章 結論......115
第六章 未來展望......118
第七章 參考文獻......119
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