臺灣博碩士論文加值系統

目錄
圖目錄
表目錄
摘要
摘要
Abstract
第一章 前言
1-1 刺激應答型高分子
1-2 聚甲基丙烯酸二甲胺基乙酯之簡介
1-3 聚甲基丙烯酸之簡介
1-4 較低臨界溶解溫度（LCST）簡介
1-5 較低臨界溶解溫度（LCST）之測定
1-6 原子轉移自由基聚合（ATRP）之簡介
1-6-1 原子轉移自由基聚合之原理
1-6-2 原子轉移自由基聚合優缺點
1-7 奈米碳管之簡介
1-8 奈米碳管之特性
1-9 奈米碳管分散性行為簡介
1-10 自我修復材料之簡介
第二章 文獻回顧
2-1 利用 ATRP 接枝共聚物
2-2 CO2 刺激應答的官能基團
2-3 奈米碳管之分散性
2-4 油/水混合溶液之刺激型過濾材料
2-4-1 溫度與pH響應型濾材
2-4-2 CO2響應型過濾材料
2-5 自我修復材料
2-6 研究動機
第三章 實驗步驟及方法
3-1 實驗藥品
3-2 實驗設備
3-3 實驗步驟
3-3-1 以ATRP法合成PDMAEMA、PtBuMA、PMAA
3-3-1-1 PDMAEMA聚合
3-3-1-2 PtBuMA聚合
3-3-1-3 將PtBuMA-Br水解為PMAA
3-3-2 CNT接枝PDMAEMA、PtBuMA、PMAA
3-3-2-1 CNT-g-PDMAEMA
3-3-2-2 CNT-g- PtBuMA之聚合
3-3-2-3 CNT-g- PMAA之聚合
3-3-3 自我修復材料之合成
3-3-3-1 PDMAEMA溶液聚合
3-3-3-2 PMAA溶液聚合
3-3-3-3 自我修復材料之製備
3-3-4 以H-NMR鑑定分析材料之組成
3-3-5 以FT-IR鑑定分析材料之官能基團
3-3-6 以UV-vis鑑定分析材料之相轉變溫度（LCST）
3-3-7 以DSC鑑定分析材料之玻璃轉移溫度（Tg）
3-3-8 以TGA鑑定分析材料之熱裂解溫度
3-3-9 以SEM鑑定分析CNT-g-PDMAEMA之表面形貌
3-3-10 以數位攝影觀察PDMAEMA在不同pH下之溫度應答行為
3-3-11 以數位攝影觀察奈米碳管接之共聚物在不同pH值下之分散能力
3-3-12 以數位攝影觀察奈米碳管接之共聚物對CO2應答之行為
3-3-13 以Zeta potential 測量水溶液界面電位
第四章 結果與討論
4-1 以ATRP法合成PDMAEMA與PMAA之鑑定分析
4-1-1 以1H-NMR分析材料組成及計算分子量
4-1-2 以FT-IR鑑定分析PtBuMA及PMAA之官能基
4-1-3 以UV-Vis光譜儀測量PDMAEMA水溶液之相轉變（LCST）
4-1-4 以數位攝影觀察PDMAEMA水溶液之pH響應行為
4-1-5 以數位攝影觀察PDMAEMA水溶液對CO2之響應行為
4-2 以ATRP法將PDMAEMA及PtBuMA高分子接枝到CNT上
4-2-1 以TGA測量材料之熱裂解溫度及計算接枝率
4-2-1-1 CNT-g-PDMAEMA
4-2-1-2 CNT-g-PtBuMA
4-2-1-3 CNT-g-PMAA
4-2-2 以SEM觀察CNT-g-PDMAEMA之表面形貌
4-2-3 以數位攝影觀察CNT-g-PDMAEMA及CNT-g-PMAA之分散性
4-2-3-1 CNT-g-PDMAEMA隨pH值變化之分散性
4-2-3-2 CNT-g-PMAA隨pH值變化之分散性
4-2-4 以數位攝影觀察CNT接枝高分子之CO2響應行為
4-2-4-1 CNT-g-PDMAEMA分散溶液之CO2響應行為
4-2-4-2 CNT-g-PMAA分散溶液之CO2響應行為
4-3 自我修復材料
4-3-1 以1H-NMR分析材料組成
4-3-2 以DSC測量PDMAEMA及PMAA之玻璃轉換溫度（Ｔｇ）
4-3-3 以Zeta potential 測量高分子水溶液之界面電位
4-3-4 以數位攝影觀察自我修復材料水溶液之pH響應行為
4-3-5 以數位攝影觀察自我修復材料之修復行為
第五章 結論
5-1 以ATRP法合成PDMAEMA與PMAA
5-2 以ATRP法將PDMAEMA及PtBuMA高分子接枝到CNT上
5-3 PDMAEMA/PMAA自我修復材料
第六章 參考文獻

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