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研究生:溫佳豪
研究生(外文):Chia-Hao Wen
論文名稱:應用於高溫質子交換膜燃料電池之Pt/PyPBI-CNT 觸媒與改質聚苯並咪唑質子交換膜製備
論文名稱(外文):Preparation of Pt/PyPBI-CNT catalysts and modification PBI membranes for high temperature proton exchange membrane fuel cells
指導教授:林秀麗林秀麗引用關係
指導教授(外文):Hsiu-Li Lin
口試委員:余子隆鄭欽獻
口試委員(外文):Tz-Lung YuChin-Shian Jeng
口試日期:2018-06-29
學位類別:碩士
校院名稱:元智大學
系所名稱:化學工程與材料科學學系
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2018
畢業學年度:106
語文別:中文
論文頁數:54
中文關鍵詞:奈米碳管聚苯並咪唑高溫質子交換膜燃料電池
外文關鍵詞:PyPBIPSi-EPCNTPBIHT-PEMFC
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目錄 1
圖目錄 4
表目錄 6
第一章 序論 7
1.1 燃料電池構造及原理 8
1.2 燃料電池分類 9
1.3 質子交換膜燃料電池應用與產氫重組器連結技術 10
1.3.1 產氫重組器 (reformer) 10
1.3.2 質子交換膜燃料電池與產氫重組器連結之問題 12
1.4膜電極組簡介 13
1.4.1 觸媒層 14
1.4.2 質子交換膜 14
1.4.3 氣體擴散層 15
1.5聚苯並咪唑 (polybenzimidazole, PBI) 16
1.6 PBI 在燃料電池的應用 17
1.6.1 PBI/H3PO4 膜之質子傳導機制 17
1.6.2 PBI/epoxy 交聯 18
1.7吡啶-聚苯並咪唑 (Pyridine-polybenzimidazol , PyPBI) 19
1.8奈米碳管應用於觸媒載體 19
1.8.1奈米碳管的優點與缺點 19
1.9 研究目的 20
第二章 實驗 21
2.1 試藥 21
2.2 儀器設備 22
2.3實驗步驟 23
2.3.1 PBI 與 PyPBI製備及分析鑑定 23
(1) PBI化學合成反應方程式 23
(2) PBI合成 23
(3) PyPBI化學合成反應方程式 24
(4) PyPBI 合成 24
(5) PBI 及 PyPBI 化學結構鑑定與分析 24
2.3.2 膜材分析鑑定 26
2.4電池組裝 27
28
2.5 質子交換膜燃料電池 (PEMFC) 單電池測試 29
2.6 電化學阻抗圖譜 (Electrochemical Impedance Spectroscopy, EIS) 30
2.6.1 電化學阻抗介紹 30
2.6.2 EIS 阻抗數據分析法 31
第三章 實驗結果與討論 32
3.1 PBI 與 PyPBI 的合成及結構分析鑑定 32
3.2 膜材 TGA分析 34
3.3 膜材H3PO4含量測試 35
3.4 觸媒TEM及XRD分析 36
3.5 觸媒TGA分析 38
3.6 觸媒層Mapping與EDS表面結構分析 40
3.7 單電池測試數據 42
3.8 阻抗分析測試 46
第四章 結論 48
第五章 參考文獻 49
1. Rikukawa M., Sanui K., “Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers”, Prog. Polym. Sci., 25, 1463-1502, 2000
2. 黃朝榮,“燃料電池”,五南出版社,台北,2009
3. Wainright J. S., Wang J. T., Savinell R. F., Litt M. H., “Acid-doped polybenzimidazoles: A new polymer electrolyte”, J. Electrochem. Soc., 142, 121-123, 1995.
4. Sorensen B., Hydrogen and fuel cells- Emerging technologies and applications, Elsevier Academic Press, 2005, Chapter 2.
5. Wang J. T., Savinell R. F., Wainright J., Litt M. H., Yu H., “A H2/O2 fuel cell using acid doped polybenzimidazole as polymer electrolyte”, Electrochim. Acta., 41, 193-197, 1996.
6. S. Kim, T. D. Myles, H. R. Kunz, D. Kwak, Y. Wang, R. Maric, The effect of binder content on the performance of a high temperature polymer electrolyte membrane fuel cell produced with reactive spray deposition technology, Electrochimica Acta., 177, 190-200, 2015
7. Wainright J. S., Wang J. T., Savinell R. F., Litt M. H., “Acid-doped polybenzimidazoles: A new polymer electrolyte”, J. Electrochem. Soc., 142, 121-123, 1995.
8. Wainright J. S., Wang J. T., Savinel R. F., “A direct methanol fuel cell using acid-doped polybenzimidazole as polymer electrolyte”, J. Electrochem., 26, 751-756, 1996.
9. Wang J. T., Savinell R. F., Wainright J., Litt M. H., Yu H., “A H2/O2 fuel cell using acid doped polybenzimidazole as polymer electrolyte”, Electrochim. Acta., 41, 193-197, 1996.

10. Wang J. T., Savinell R. F., Wainright J., M. Litt, H. Yu, “H2/O2 fuel cell using acid doped polybenzimidazole as polymer electrolyte” Electrochim. Acta., 41, 193-197, 1996.
11. Lin H. L., Chou Y. C., S. W. Lai,, Yu T. L., “Poly(benzimidazole)-epoxide crosslink membranes for high temperature proton exchange membrane fuel cells” J. of Hydrogen Energy, 37, 382-392, 2012.
12. Jung D. H., Cho S. Y., Peck D. H., Shin D. R., Kim J. S., “Performance evaluation jf a Nafion/silicon oxide hybrid membranes for DMFCs”. J. Power sources, 106, 173-177, 2002.
13. Rodges M. P., Shi Z., Hold Crolt S., “Transport properties of composite membranes containing silicone oxide and Nafion”. J. Membr. Sci., 325, 346-356, 2008.
14. Xu W., Lu T., Liu C., Xing w., “Low methanol permeable composite Nafion /silica/PWA membranes for low temperature DMFCs”. Electrochem. Acta., 50, 3280-3285, 2005.
15. Tay S. W., Zhang X., Liu Z., Hong L., Chan S. H., “Composite Nafion membrane embedded with hybrid nanofillers for promoting DMFC performance”. J. Membr. Sci., 321, 139-145, 2007.
16. Kumar G. G., Kim A. R., Nahm K. S., Elizabeth R., “Nafion membranes modified with silica-sulfuric acid for the elevated temperature and lower humidity operation of PEMFC”. Int. J. Hydrogen Energy, 34, 9788-9794, 2009.
17. He. R., Li. Q., Xian G., Bjermm N. J., “Proton conductivity of H3PO4 doped PBI and its composite with inorganic proton conductors”. J. Membr. Sci., 226, 169-184, 2003.
18. Staiti P., “Proton conductive membranes based on silicontungstic
acid/silica and PBI”. Mater. Leff., 47, 241-246, 2001.
19. Labato J., Canzares P., Rodrigo M. A., Vbeda D., Pinar F. J., “A
novel titanium PBI-based composite membrane for high temp
PEMFCs”. J. Membr. Sci., 369, 105-111, 2011.
20. Yu T. L., “ Overview of Electrochemical polymer electrolyte
membranes”. Ed.by Fang J., Qiao J., Wilkinson D. P., Zhang J., CRC
press, 2015, Chap.1.
21. Ossiander T., Henzl C., Gleich S., Schonberger F., Volk P., Welch
M., Scheu C., “Influence of the size and shape of silica nanoparticles
on the properties and degradation of a PBI-based high temperater
PEM”. J. Membr. Sci, 454, 12-19, 2014.
22. Lin H. L., Tang T. H., Hu C. R., Yu T. L., “Poly/Silica-ehtyl-
phosphoric acid hybrid membranes for PEMFCs” J. Power. Sources,
201, 72-80, 2012.
23. Jiang S. P., “Functionalized mesoporous structured inorganic
materials as high temperature proton exchange membranes for fuel
cells”. J. Mater. Chem. A, 2, 7637–7655, 2014.
24. Aili D., Zhang J., Jakobsen M., Zhu H., Yang T., Liu J., Forsyth M.,
Pan C., Jensen J. O., Cleemann L. N., Jiang S. P., “Exceptional
durability enhancement of PA/PBI based polymer electrolyte
membrane fuel cells for high temperature operation at 2000C ”. J.
Mater. Chem. A, 4, 4019–4024, 2016.
25. Zeng J., He B., Lamb K., De Marco R., Shen P. K., Jiang S. P.,
“Phosphoric acid functionalized pre-sintered meso-silica for high
temperature proton exchange membrane fuel cells”. Chem.
Commun., 49, 4655-4657, 2013.
26. Zeng J., Shen P. K., Lu S., Xiang Y., Li L., De Marco R., Jiang S. P.,
“Correlation between proton conductivity thermal stability and
structural symmetries in novel HPW-meso-silica nano composite
membranes and their performance in DMFCs”. J. Membr. Sci., 397-
398, 92-101, 2012.
27. Lu J., Tang H., Lu S., Wu H., Jiang S. P., “ A novel inorganic PEM
based on self-assembled HPW-meso-silica for DMFCs”. J. Mater.
Che., 21, 6668-6676, 2011.
28. Shabanikia A., Javanbakht M., Amoli H. S., Hooshyari K.,
Enhessari M., “Polybenzimidazole/strontium cerate nanocomposites
with enhanced proton conductivity for proton exchange membrane
fuelcells operating at high temperature” Electrochimica Acta., 154, 370-378, 2015
29. Suryani., Chang Y. N., Lai J. Y., Liu Y. L., “Polybenzimidazole (PBI)-
functionalized silica nanoparticles modified PBI nanocomposite
membranes for proton exchange membranes fuel cells” J. Membr. Sci.,
403-404, 1-7, 2012
30. Linlin M., Mishra A. K., Kim N. H., Lee J. H., “Poly(2,5-
benzimidazole)/silica nanocomposite membranes for high
temperature proton exchange membrane fuel cell” J. Membr. Sci.,
411-412, 91-98, 2012.
31. Li. Q., Jenson. J. O, Savinell. R. F., Bjerrum. N. J., “High
temperature proton exchange membranes based on
polybenzimidazoles for fuel cells”, Polym. Sci., 34, 449-477, 2009.
32. Devrim Y., Devrim H., Eroglu I., “Polybenzimidazole/SiO2 hybrid
membranes for high temperature proton exchange membrane fuel
cells ” , J. of Hydrogen Energy, 41, 1-9, 2016
33. 蔡宜祐,乙基磷酸接枝聚矽氧化物高溫質子交換膜燃料電池,
碩士論文,元智大學化學工程與材料科學學系(2017)
34. Okamoto M., Fujigaya T., Nakashima N., “Individual dissolution of
single-walled carbon nanotubes by using polybenzimidazole, and
highly effective reinforcement of their composite films”, Adv. Funct.
Mater., 18, 1776-1782, 2008.
35. Qu L., Dai L., “Substrate-enhanced electroless deposition of metal
nanoparticles on carbon nanotubes”, J. Am. Chem. Soc., 127, 10806-10807, 2005.
36. Ostrander J. W., Mamedov A. A., Kotov N. A., “Two modes of linear
Layer-by-Layer growth of nanoparticle-polylectrolyte multilayers
and different interactions in the Layer-by-layer deposition”, J. Am.
Chem. Soc., 123, 1101-1110, 2001.
37. Zhou J., Zhou X., Sun X., Li R., Murphy M., Ding Z., Sham T. K.,
“Interaction between Pt nanoparticles and carbon nanotubes-An X-
ray absorption near edge structures (XANES) study”, Chem. Phys.
Lett., 437, 229-232, 2007.
38. Wunderlich W., “Growth model for plasma-CVD growth of carbon
nano-tubes on Ni sheets”, Diamond Relat. Mater., 16, 369-378,
2007.
39. Baughman R. H., Zakhidov A. A., de Heer W. A., “Carbon
nanotubes-the route toward applications”, Science, 297, 787-793,
2002.
40. Hu C. P., Keller N., Roddatis V. V., Mestl G., Schlögl R., Ledoux M.
J., “Large scale synthesis of carbon nanofibers by catalytic
decomposition of ethane on nickel nanoclusters decorating carbon
nanotubes”, Phys. Chem. Phys., 4, 514-521, 2005.


41. Kaewai D., Lin H. L., Yu T. L., “Influence of PyPBI film thickness of
CNT supported Pt on fuel cell applications, Fiel cells”, 15, 361-374,
2015
42. Kaewai D., Lin H. L., Liu Y. C., Yu T. L., Pt on PyPBI wraped CNT
supports for high temperature PEMFCs, Int. J. Hydrogen Energy, 41,
10430, 2016
43. Okamoto M., Fujigaya T., Nakashima N., “Design of an assembly of
poly (benzimidazole), carbon nanotubes, and Pt nanoparticles for a
fuel-cell electrocatalyst with an ideal interfacial nanostructure”,
5, 735-740, 2009.
44. Fujigaya T., Nakashima N., “Fuel cell electrocatalyst using
polybenzimidazole-modified Carbon nanotubes As Support
Materials”, Adv. Mater., 25, 1666-1681, 2013.
45. 劉宇宸,應用於高溫質子交換膜燃料電池之 Pt/PyPBI-CNT 觸
媒製備,碩士論文,元智大學化學工程與材料科學學系(2015)
46. Asensio J. A., Borros S., Pedro G. R., “Proton-conducting polymers
based on benzimidazoles and sulfonated benzimidezoles’’, J of
Polym. Sci. : Part A: Polym. Che., 40, 3703-3710, 2002.
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