臺灣博碩士論文加值系統

本計畫係以開發近紅外光遮蔽之高分子複合材料應用於透明隔熱塗料，透過混摻紅外光遮蔽無機奈米顆粒(如ITO、LaB6、和Cs0.33WO3)於高分子薄膜中可提高近紅外光遮蔽的效率和波長範圍，太陽光所產生的近紅外波長範圍(800~2500 nm)的輻射(熱射線)可有效率地被吸收或反射，並維持可見光區域之高穿透度。因此，具有近紅外光遮蔽及高可見光穿透度的高分子複合材料中以減少使用空調能源之消耗，從而減低二氧化碳的排放，達到綠能與節能之目的。另外，近紅外光遮蔽無機奈米顆粒可透過表面改質給予官能化，來改善近紅外光遮蔽無機奈米顆粒和高分子樹脂之間的分散性、流動性(降低黏度)、相容性、減少霧度及維持機械性質。

Novel near infrared (NIR) shielding polymer composites containing near IR shielding inorganic nanoparticles (such as ITO, LaB6, and Cs0.33WO3) are developed in this project to the applications of transparent heat-insulated coatings. To enhance the absorption efficiency and to cover broader wavelength ranges of NIR, the radian wavelength of NIR (800~2500 nm) (heat rays) from sun can be effectively absorbed or reflected by doping near IR shielding inorganic nanoparticles in polymer films to maintain the high transmittance of visible light. Hence, the goal of energy saving and green energy can be achieved by the near IR shielding and high transmittance of visible light in polymer composites to reduce the consumption of air conditioning energy and CO2 release. In addition, the NIR shielding nanoparticles can be surface-modified with functional groups to improve the compatibility, reduced-haze, mechanical properties, dispersion and liquidity (reduce the viscosity) between polymer and NIR shielding nanoparticles.

中文摘要 i
Abstract ii
致謝 iii
目錄 iv
圖目錄 vi
表目錄 xi
第一章 緒論 1
1.1 前言 1
1.2 研究動機與目的 2
第二章 文獻回顧 4
2.1 氧化銦錫(ITO) 4
2.2 氧化鎢(WOx) 6
2.3 六硼化鑭(LaB6) 16
第三章 理論 21
3.1 氧化銦錫 21
3.2 鎢酸銫 22
3.3 六硼化鑭 24
3.4 近紅外光遮蔽原理 26
3.4.1 奈米複合材料之光性質 26
3.4.2 等離子共振 29
3.4.3 瑞利散射 31
3.5 紅外光遮蔽複合材料 32
3.5.1 複合材料定義 32
3.5.2 近紅外光吸收高分子複合材料之基材 33
3.5.3 紫外光固化技術 34
3.6 無機奈米顆粒改質方法 34
第四章 實驗方法 39
4.1 藥品及材料 39
4.2 儀器設備 39
4.3 實驗流程 40
4.3.1 分散性測試 42
4.3.2 無機奈米顆粒改質 42
4.3.3 薄膜製作 43
4.3.4 照光隔熱實驗 43
4.4 測量方法與儀器 44
第五章 結果與討論 47
5.1 分散性測試 47
5.2 SEM/EDS、DLS、TGA 50
5.3 無、有改質無機奈米顆粒分散於UV膠 56
5.3.1 氧化銦錫薄膜 57
5.3.2 鎢酸銫薄膜 65
5.3.3 六硼化鑭薄膜 73
5.3.4 不同無機奈米顆粒比例分析 80
5.4.5 總結 83
第六章 結論 86
第七章 未來與展望 88
第八章 參考文獻 89

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