臺灣博碩士論文加值系統

摘要 i
ABSTRACT ii
誌謝 iii
目錄 iv
圖目錄 vi
表目錄 vii
第一章緒論 1
1-1前言 1
1-2論文架構 2
第二章文獻回顧與研究動機 3
2-1研究動機 3
2-2光電材料 4
2-3光感測器 5
2-4 CZTS材料介紹 6
2-5 合成方法 7
2-5-1溶膠凝膠法 7
2-5-2溶膠凝膠法之優點 8
2-5-3硫化處理 8
第三章實驗方法與步驟 9
3-1.實驗材料 9
3-2.量測儀器 9
3-3實驗儀器 10
3-4.實驗方法與流程 10
3-4-1. 以溶膠凝膠法製備CZTS粉末 10
3-4-2. 硫化處理CZTS粉末 12
3-4-3.製備濕度感測器 13
3-4-4.濕度感測 13
3-4-5光催化實驗 14
3-5.材料特性量測與分析 15
3-5-1.X-ray繞射儀(X-ray diffractometer , XRD) 15
3-5-2紫外光/可見光光譜儀 (UV-Visible Spectroscopy) 15
3-5-3 光催化降解 16
第四章 結果與討論 17
4-1.材料特性與分析 17
4-1-1.XRD 17
4-1-2. 未硫化各燒結溫度之紫外光/可見光光譜儀分析 19
4-2.感測器結果與探討 20
4-2-1.濕度感測實驗 20
4-3.光催化降解 23
第五章 結論 26
參考文獻 27

[1] Ito, K, Nakazawa, T. “Electrical and Optical Properties of Stannite-Type Quaternary Semiconductor Thin Films”, In: Japanese Journal of Applied Physics. 27 (1988), S.2094–2097.

[2] A. Y. Tang, J. J. Liu, J. Ji, M. L. Dou, Z. L. Li, and F. Wang, “One-step electrodeposition for targeted off-stoichiometry Cu2ZnSnS4 thin films”, Applied Surface Science, vol. 383, pp. 253-260, Oct 2016.

[3] M. I. Khalil, O. Atici, A. Lucotti, S. Binetti, A. Le Donne, and L. Magagnin, “CZTS absorber layer for thin film solar cells from electrodeposited metallic stacked precursors (Zn/Cu-Sn)”, Applied Surface Science, vol. 379, pp. 91-97, Aug 2016.

[4] Y. P. Lin, Y. F. Chi, T. E. Hsieh, Y. C. Chen, and K. P. Huang, “Preparation of Cu2ZnSnS4 (CZTS) sputtering target and its application to the fabrication of CZTS thin-film solar cells”, Journal of Alloys and Compounds, vol. 654, pp. 498-508, Jan 2016.

[5] Chinnaiyah Sripan, R.Ganesan, E.M. Viond, Annamraju Kasi Viswanth, “The effect of sulfur on the phase formation of Cu2ZnSnS4 solar cell material”, Materials Letters, Volume. 180, Pages. 295-297, 1 October 2016.

[6] Amin Emrani, Parag Vasekar, Charles R. Westgate, “Effects of sulfurization temperature on CZTS thin film solar cell performances”, Solar Energy, Volume. 98, Part C, Pages. 335-340, December 2013.

[7] Zhishan Li, Shurong Wang, Xun Ma, Min Yang, Zhi Jiang, Tao Liu, Yilei Lu, Sijia Liu, “A simple structure of Cu2ZnSnS4/Cds solar cells prepared by sputtering”, Physica B: Condensed Matter, Volume. 526, Pages.80-83, 1 December 2017.

[8] P. Prabeesh, I. Packia Selvam, S.N. Potty, “Effect of annealing temperature on a single step processed Cu2ZnSnS4 thin film via solution method”, Thin Solid Films, Volume. 606, Pages. 94-98, 1 May 2016.

[9] Sandip Mahajan, Elias Stathaots, Nanasaheb Huse, Ravikiran Birajdar, Alexandros Kalarakis, Ramphal Sharma, “Low cost nanostructure kesterite CZTS thin films for solar cells application”, Materials Letters, Volume. 210, Pages. 92-96,1 January 2018.

[10] Xinhua Guo, Jiecai Han, Huayu Zhang, Xinguanag Lv, Jianwei Yan, Rui Sun, “Sol-gel synthesis of Cu2ZnSnS4 thin films under mild conditions”, Journal of Alloy and Compounds, Volume. 697, Pages. 361-366, 15 March 2017.

[11] Z. Laghfour, S. Aazou, M. Taibi, G. Schmerber, A. Ulyashin, A. Dinia, A. Slaoui, M. Abd-Lefdil, Z. Sekkat, “Sodium doping mechanism on sol-gel processed
kesterite Cu2ZnSnS4 thin films”, Superlattices and Microstructures, Volume. 120, Pages. 747-752, August 2018.

[12] G. Rajesh, N. Muthukumarasamy, S. Agilan, Dhayalan Velauthapillai, Kallol Mohanta, Sudip K. Batabyal, “Electrical bistability of sol-gel derived Cu2ZnSnS4 thin films”, Materials Letters, Volume. 220, Pages.285-288, 1 June 2018.

[13] Birendra Kumar Rajwar, Shailendra Kumar Sharma, “Structural and optical properties of Cu2ZnSnS4 synthesized by ultrasonic assisted sol-gel method”, Physica B: Condensed Matter, Volume. 537, Pages. 111-115, 15 May 2018.

[14] M. A. Olgar, J. Klaer, R. Mainz, S. Levcenco, J. Just, E. Bacaksiz, et al., “Effect of precursor stacking order and sulfurization temperature on compositional homogeneity of CZTS thin films”, Thin Solid Films, vol. 615, pp. 402-408, Sep 2016.

[15] M. Yang, Z. Jiang, Z. S. Li, S. J. Liu, Y. L. Lu, and S. R. Wang, “Effects of different precursors on Cu2ZnSnS4 thin film solar cells prepared by sputtering method”, Materials Science in Semiconductor Processing, vol. 56, pp. 238-242, Dec 2016.

[16] P. A. Cormier and R. Snyders, “Phase transformation during Cu2ZnSnS4 synthesis by reactive magnetron co-sputtering”, Acta Materialia, vol. 110, pp. 53-60, May 2016.

[17] O. P. Singh, R. Parmar, K. S. Gour, M. K. Dalai, J. Tawale, S. P. Singh, et al., “Synthesis and characterization of petal type CZTS by stacked layer reactive sputtering”, Superlattices and Microstructures, vol. 88, pp. 281-286, Dec 2015.

[18] 葉旻彥、武東星, 銅鋅錫硫(CZTS)太陽電池的發展簡介 vol. 295: 工業材料雜誌, 2011.

[19] 馬振基, 奈米材料科技原理與應用: 全華圖書股份有限公司, 2015.

[20] Kuyyadi P. Biju, Mahaveer K. Jain, 2008,” Effect of crystallization on humidity sensing properties of sol–gel derived nanocrystalline TiO2 thin films”, Thin Solid Films Volume 516, Issue 8, Pages 2175-2180, 29 February.

[21] Ting Xie, Asha Rani, Baomei Wen, Audie Castillo, Brian Thomson,Ratan Debnath, Thomas E. Murphy, R.D. Gomez, Abhishek Motayed, 2016”, The effects of surface conditions of TiO2 thin film on the UV assisted sensing response at room temperature”, Thin Solid Films Volume 620, Pages 76-81, 1 December.

[22] A. L. Patterson, 1939, “The Scherrer Formula for X-Ray Particle Size Determination”, Phys. Rev., vol. 56, pp. 978-982, November.