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研究生:林岳陞
研究生(外文):Yue-Sheng Lin
論文名稱:應用田口法優化rGO/SPHC電極於電-芬頓系統之特性研究
論文名稱(外文):Study on Application of Taguchi Method to optimize the rGO/SPHC electrode in Electro-Fenton system
指導教授:王朝正王宜達
指導教授(外文):Chaur-Jeng WangYi-Ta Wang
口試委員:陳士勛王宜達
口試委員(外文):Shih-Hsun ChenYi-Ta Wang
口試日期:2019-07-11
學位類別:碩士
校院名稱:國立臺灣科技大學
系所名稱:機械工程系
學門:工程學門
學類:機械工程學類
論文種類:學術論文
論文出版年:2019
畢業學年度:107
語文別:中文
論文頁數:97
中文關鍵詞:電-芬頓系統還原氧化石墨烯電泳沉積田口法實驗
外文關鍵詞:Electro-Fentonreduced Graphene OxideElectrophoretic depositionTaguchi experiment
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電極材料性質對電-芬頓系統處理效能產生顯著影響。本研究以成本低廉及良好導電性之低碳鋼(SPHC)電極,藉由電泳沉積(Electrophoretic Deposition, EPD),進行製備SPHC 表面披覆還原氧化石墨烯(rGO/SPHC)電極,冀優化SPHC 電極之電化學特性及耐腐蝕性。過程以田口實驗(Taguchi method)分別針對電泳前驅物濃度、沉積電壓及電泳時間進行性能測試。
結果顯示,電泳參數為濃度0.5 mg/mL、電壓30 V 及時間15分鐘,可獲得緻密表面鍍層,並具最大極化阻抗491.84 Ω。而電泳參數為1.00 mg/L、電壓30 V 及時間15 分鐘下所製得rGO/SPHC 電極,偶氮染料(Rh B)脫色率為48.1 %及脫色反應常數0.0204 min-1,分別為未修飾SPHC 電極之2.15 及2.72倍。綜上, rGO/SPHC 電極可促使電-芬頓反應效率及電極耐腐蝕性能獲得提升。
The properties of the electrode material bring in a significant effect for efficiency of the electro-Fenton system. In this study, the SPHC with low cost
and good conductivity was used as electrode, and made reduced Graphene Oxide (rGO) on the surface of SPHC by electrophoretic deposition (EPD). To optimize the electrochemical performance and corrosion resistance of the SPHC electrode, the Taguchi experiment was used to test the property of the concentration, deposition voltage and deposition time.
That results showed that rGO/SPHC prepared with concentration of 0.5 mg/mL, 30 V and deposition time of 15 minutes possess the compact coating, and got the maximum polarized impedance of the electrode 491.84 Ω. The rGO/SPHC electrode prepared with concentration 1.00 mg/L, 30 V and electrophoresis time for 15 minutes. The decolorization rate of Rh B dye was 48.1% and the reaction coefficient was 0.0204 min-1, which was 2.15 and 2.72 times than SPHC, respectively. In summary, the results show that the rGO/SPHC electrode can improve the efficiency of the electro-Fenton and corrosion resistance for electrode.
摘要 I
Abstract II
謝誌III
目錄 IV
圖目錄 VII
表目錄 X
第一章 前言 1
第二章 文獻回顧 3
2.1 高級氧化程序 3
2.2 芬頓法 4
2.3 電-芬頓法 5
2.3.1 電-芬頓法參數 7
2.3.2 電極材料選用 9
2.4 石墨烯(Graphene) 10
2.4.1 石墨烯組成及製備 10
2.4.2 石墨烯系列材料於電子元件/電極材料之應用 12
2.4.3 石墨烯系列材料於防腐蝕材料之應用 13
2.5 電泳沉積 14
2.5.1 電泳沉積原理 14
2.5.2 電泳沉積參數 15
2.5.3 電泳沉積製備氧化石墨烯/還原氧化石墨烯複合鍍層 17
2.6 田口法 20
第三章 實驗方法 24
3.1 實驗流程圖 24
3.2 實驗材料 25
3.2.1 電極製備材料及藥品 25
3.2.2 實驗場域之材料及藥品 26
3.2.3 實驗儀器設備 26
3.3 電極製備流程 27
3.3.1 田口法實驗設計 27
3.3.2 SPHC電極前處理 28
3.3.3 氧化石墨製備流程 29
3.3.4 電泳沉積還原氧化石墨烯流程 29
3.4 rGO/SPHC電極耐腐蝕性能分析 30
3.4.1 電極極化曲線分析 30
3.4.2 電化學交流阻抗法 31
3.5 rGO/SPHC電極於電-芬頓系統之性能測試 32
3.5.1 電-芬頓實驗場域架設 32
3.5.2 線性掃描伏安分析 34
3.6 rGO/SPHC電極材料性能分析 35
3.6.1 掃描式電子顯微鏡 35
3.6.2 X光繞射分析儀 35
3.6.3 傅立葉紅外線光譜儀 35
3.6.4 拉曼光譜 36
第四章 結果與討論 37
4.1 rGO/SPHC田口法參數設置 37
4.1.1 氧化石墨(Graphite oxide)前驅物鑑定 37
4.1.2 田口法實驗控制因子水準設置 39
4.1.3 rGO/SPHC電極拉曼光譜分析 44
4.1.4 rGO/SPHC電極表面形貌觀察 46
4.2 rGO/SPHC電極腐蝕性能分析 50
4.2.1 L9極化曲線測試 50
4.2.2 rGO/SPHC電極耐腐蝕性能評估 53
4.2.3 製程參數對rGO/SPHC電極腐蝕性能影響 54
4.3 SPHC電極於電-芬頓系統之性能評估 58
4.3.1 SPHC電極之操作電位評估 58
4.3.2 SPHC電極於電-芬頓系統之性能測試 59
4.4 rGO/SPHC電極於電-芬頓系統之性能評估 62
4.4.1 rGO/SPHC電極脫色效能評估 62
4.4.2 rGO/SPHC電極表面含氧官能基量測 65
4.4.3 rGO/SPHC電極電化學性能量測 67
4.4.4 rGO/SPHC電極於電-芬頓系統之效能分析 68
第五章 結論 74
參考文獻 76
附錄A rGO/SPHC電極表面孔隙率 85
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