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研究生:高國域
研究生(外文):GAO, GUO-YU
論文名稱:利用Metallocene觸媒合成長支鏈聚丙烯及合成熔噴聚丙烯
論文名稱(外文):Syntheses of Long-chain-branched Polypropylene and Melt Blown Polypropylene Using Metallocene Catalyst
指導教授:蔡敬誠
指導教授(外文):TSAI, JING-CHERNG
口試委員:梁孟陳靜誼
口試委員(外文):LIANG, MONGCHEN, CHING-YI
口試日期:2020-07-30
學位類別:碩士
校院名稱:國立中正大學
系所名稱:化學工程研究所
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2020
畢業學年度:108
語文別:中文
論文頁數:93
中文關鍵詞:長支鏈聚丙烯選擇性鏈轉移反應大開角金屬茂觸媒
外文關鍵詞:Long chain branchesSelective chain transfer reactionT-reagentAnsa-metallocene catalyst
相關次數:
  • 被引用被引用:0
  • 點閱點閱:38
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  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
目錄
摘要 I
Abstract III
圖目錄 VI
表目錄 VIII
第一章、 緒論 1
1-1、 前言 1
1-2、 原理與文獻探討 3
1-2-1、 聚丙烯簡介 3
1-2-2、Ziegler-Natta觸媒背景介紹 17
1-2-3、Metallocene觸媒背景介紹 19
1-2-4、MAO 助觸媒 22
1-2-5、Metallocene/MAO 觸媒系統聚合機制 25
1-2-6、Ansa-Metallocene 觸媒與 T-reagent 聚合反應機制 27
1-2-7、觸媒載體 29
1-2-8、聚烯烴製程介紹 31
1-3、研究動機與目的 35
1-3-1、實驗構想 35
1-3-2、Metallocene觸媒挑選 36
1-3-3、Metallocene聚合反應條件與適化反應條件探討 37
1-3-4、矽化雙官能基試劑(Si-based T-reagent)之合成 38
第二章、實驗部分 40
2-1、實驗相關器材 40
2-1-1、藥品清單 40
2-1-2、器材清單 45
2-2、分析儀器簡介 47
2-2-1、3D GPC 47
2-2-2、SEM 49
2-2-3、NMR 51
2-2-4、差示掃描量熱法(DSC) 52
2-3、實驗步驟 54
2-3-1、溶劑純化步驟 54
2-3-2、T-reagent 合成步驟 57
2-3-3、solid-MAO/silica擔體部分 58
2-3-4、聚合步驟 60
第三章、結果與討論 63
3-1、T-reagent 合成分析 64
3-1-1、Pre T-reagent之1H-NMR圖譜合成分析 64
3-1-2、T-reagent之1H-NMR圖譜合成分析 65
3-2、Ansa-Metallocene 觸媒均相聚合長支鏈聚丙烯 66
3-2-1、Me2Si(Ind)2ZrCl2 觸媒(I)均相聚合反應條件測試 67
3-2-2、Me2Si(2-Me-4-Ph-Ind)2ZrCl2 觸媒(II)均相聚合反應條件測試 72
3-3、Ansa-Metallocene 觸媒載體化 82
3-3-1、均相聚合聚丙烯 82
3-3-2、合成 Metallocene 觸媒載體化條件測試 84
第四章、結論 90
第五章、參考文獻 92


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[19]"."
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