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研究生:翁崇華
研究生(外文):WENG, CHUNG-HUA
論文名稱:Metallocene載體觸媒之合成及應用於LLDPE之技術開發
論文名稱(外文):Synthetic Conditions for Metallocene Supported Catalysts and Applications for LLDPE
指導教授:蔡敬誠
指導教授(外文):TSAI, JING-CHERNG
口試委員:粱孟陳靜誼
口試委員(外文):LIANG, MONGCHEN, CHING-YI
口試日期:2020-07-30
學位類別:碩士
校院名稱:國立中正大學
系所名稱:化學工程研究所
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2020
畢業學年度:108
語文別:中文
論文頁數:95
中文關鍵詞:茂金屬觸媒載體觸媒型態控制
外文關鍵詞:metallocenesupported catalystmorphology control
相關次數:
  • 被引用被引用:0
  • 點閱點閱:38
  • 評分評分:
  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
目錄
摘要 1
Abstract 2
目錄 3
表目錄 4
圖目錄 5
第一章、緒論 7
1.1、前言 7
1.2、原理與文獻探討 9
1.2.1、聚烯烴簡介 9
1.2.2、Ziegler-Natta觸媒 17
1.2.3、Metallocene 觸媒 19
1.2.4、MAO 助觸媒 24
1.2.5、Silica與 MAO之結合 38
1.2.6、觸媒載體 41
1.2.7、工業界之聚烯烴製程介紹 44
1.3、研究動機與目的 48
1.3.1、實驗構想 48
1.3.2、觸媒挑選 49
1.3.3、silica sMAO載體 49
第二章、實驗部分 50
2.1、實驗相關器材 50
2.1.1、藥品清單 50
2.1.2、器材清單 55
2.2、分析儀器簡介 58
2.2.1、3D GPC 58
2.2.2、SEM 59
2.2.3、差示掃描量熱法(DSC) 60
2.2.4、粒徑分析儀(Malvern Mastersizer) 61
2.3、實驗步驟 62
2.3.1、溶劑純化步驟 62
2.3.2、solid-MAO/silica載體部分 65
2.3.3、聚合步驟 68
第三章、結果與討論 72
3.1、silica sMAO載體合成 73
3.1.1、silica sMAO合成條件–mesh目數及攪拌方法探討 73
3.1.2、silica sMAO載體觸媒聚合PE–載體反應時間及攪拌方式探討 78
3.1.3、silica sMAO合成條件–載體比例探討 79
3.1.4、silica sMAO載體觸媒聚合PE–載體比例探討 79
3.1.5、silica sMAO合成條件–載體合成方法探討 81
3.1.6、silica sMAO載體觸媒聚合PE–載體合成方法探討 85
3.1.7、silica sMAO載體觸媒 – 3SMAO8 (大壓力)測試 86
3.1.8、silica sMAO/ansa-metallocene載體觸媒 88
3.2、(nBuCp)2ZrCl2活化條件探討 89
第四章、結論 91
第五章、參考文獻 93
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