臺灣博碩士論文加值系統

誌 謝 I
摘 要 II
Abstract III
目錄 IV
圖目錄 IX
表目錄 XI
第一章 緒論 1
1-1前言 1
1-2研究動機 2
第二章 文獻回顧 3
2-1再生能源 3
2-1-1再生能源的定義 3
2-1-2再生能源的種類 3
2-1-3生質物與生質能源 4
2-1-3-1生質物的定義以及來源 4
2-1-3-2何謂生質能源 4
2-1-4生質能源的轉換特性 5
2-2氣化技術 9
2-2-1發展歷史 9
2-2-2氣化原理 10
2-2-3氣化爐種類 13
2-2-4氣化程序 17
2-2-4-1預熱前處理程序 17
2-2-4-2氣化反應程序 21
2-2-4-3產物純化分離程序 24
2-3觸媒輔助氣化 26
2-4田口方法 29
2-4-1歷史回顧 29
2-4-2實驗設計 29
2-4-3實驗設計因子 30
2-4-4直交表 31
2-4-5信號雜訊比 31
2-4-6 實驗驗證 32
第三章 實驗方法及流程 33
3-1實驗目的及方法 33
3-2實驗規劃 33
3-2-1田口實驗設計法 34
3-2-2稻殼觸媒共氣化 36
3-3料源性質分析 37
3-4觸媒製備 37
3-4-1 白雲石觸媒 37
3-4-2橄欖石觸媒 38
3-4-3鎳金屬搭載铈基底觸媒 38
3-5氣化反應實驗及分析 39
3-6氣化爐本體及週邊設備 40
第四章 實驗結果 41
4-1料源及觸媒分析 41
4-1-1稻殼基本性質分析 41
4-1-2掃描式電子顯微鏡分析 42
4-2氣化實驗及分析 44
4-2-1 在高比例水蒸氣下氣化稻殼 44
4-2-2焦油的濃度分析 51
4-2-3焦油的質譜分析 51
第五章 結果討論與未來展望 54
附錄 56
附錄 A: 實驗化學藥品與儀器 56
附錄A-1：實驗化學藥品 56
附錄A-2：實驗儀器 57
附錄A-3：實驗所用氣體 58
附錄A-4：儀器、藥品供應商資料 59
附錄B：氣化爐本體及周邊設備 62
附錄B-1：氣化床爐體 62
附錄B-2：冷卻採樣系統 63
附錄B-3：連續取樣系統 64
附錄B-4：氣體進料系統 65
附錄B-5：水蒸氣製造系統 66
附錄B-6：料源進料系統 67
附錄C：氣化反應實驗及結果分析 68
附錄C-1：料源前處理 68
附錄C-2：料源進料速率校正 69
附錄C-3：氣化爐氣化反應參數 70
附錄C-4：氣化實驗步驟 71
附錄C-5：反應結果分析 72
附錄D：分析設備及方法 73
附錄D-1：三成份分析 73
附錄D-2：元素分析 75
附錄D-3：檢測分析儀 77
附錄D-4：氣相色層分析儀 79
附錄D-5：超高解析熱電子型場發射掃描式電子顯微鏡 81
附錄D-6：氣相層析質譜儀分析 82
參考文獻 83

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