臺灣博碩士論文加值系統

誌　　謝 i
摘　　要 ii
Abstract iii
目　　錄 iv
圖目錄 vii
表目錄 xv
第一章 緒論 1
1-1 氧氣的介紹 1
1-2 氧氣還原觸媒發展現況 3
1-2-1 氧氣還原觸媒應用 3
1-2-2 氧氣還原觸媒選擇 5
1-3 掃描式電化學顯微鏡（SECM）介紹 7
1-3-1 SECM在氧氣還原觸媒方面之應用 8
1-3-2 SECM篩選氧氣還原觸媒文獻回顧 9
1-4 研究動機 11
第二章 原理介紹 12
2-1 氧氣還原途徑與機制 12
2-2 掃描式電化學顯微鏡理論 14
2-2-1 回饋模式 14
2-2-2 微電極產生-基材收集模式 16
2-2-3 逼近曲線動力學 17
2-2-4 微電極/基材雙循環伏安法 20
2-3 旋轉電極理論 21
2-4 亨利定律 24
第三章 實驗設備與方法 25
3-1 藥品與材料 25
3-2 儀器與設備 28
3-3 實驗方法 30
3-3-1 微電極的製作與前處理 30
3-3-2 三元觸媒陣列製備 31
3-3-3 氧氣還原最佳比例觸媒之製備 34
3-4 分析方法 35
3-4-1 觸媒表面特性分析 36
3-4-2 微電極產生-基材收集模式之分析 37
3-4-3 雙循環伏安法分析 39
3-4-4 逼近曲線分析 40
3-4-5 旋轉電極分析 42
第四章 實驗結果與討論 44
4-1 三元陣列催化氧氣還原之篩選與特性分析 44
4-1-1 在硫酸水溶液中之觸媒篩選 44
4-1-2 在過氯酸水溶液中之觸媒篩選 56
4-1-3三元鉑合金觸媒與鉑觸媒之比較 68
4-1-4 能量分散式光譜儀（EDS）分析 70
4-1-5 觸媒元素表面型態分析 73
4-2 最優化觸媒表面特性分析 85
4-2-1 最優化觸媒之能量分散式光譜儀（EDS）分析 85
4-2-2 最優化觸媒之高解析X光繞射儀（XRD）分析 86
4-2-3 最優化觸媒之雙循環伏安法分析 89
4-2-4 最優化觸媒之逼近曲線動力學分析 94
4-2-5 最優化觸媒之旋轉電極動力學分析 109
4-3 綜合討論 122
第五章 結論 125
參考文獻 127

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