臺灣博碩士論文加值系統

Table of Content

Abstract--------------------------------------------------------------------------------------------------------6
Preface---------------------------------------------------------------------------------------------------------8
Table of contents---------------------------------------------------------------------------------------------9
List of Figures-----------------------------------------------------------------------------------------------11
List of Schemes----------------------------------------------------------------------------------------------12
List of Tables------------------------------------------------------------------------------------------------14
List of Abbreviations---------------------------------------------------------------------------------------16
CHAPTER 1: General introduction-----------------------------------------------------------------------20
1.1 Overview----------------------------------------------------------------------------------------21
1.2 Ethers in the radical reactions----------------------------------------------------------------23
1.3 Enynes in the radical reactions---------------------------------------------------------------25
1.4 Objectives---------------------------------------------------------------------------------------29
CHAPTER II: Mild Access to N-Formylation of Primary Amines using Ethers as C1
Synthons under Metal-Free Condition----------------------------------------------------------------31
2.1. Abstract----------------------------------------------------------------------------------------32
2.2. Introduction and Background---------------------------------------------------------------32
2.3. Result and Discussion------------------------------------------------------------------------35
2.4. Conclusion-------------------------------------------------------------------------------------45
2.5. Experimental Section ------------------------------------------------------------------------46
2.6. Analytical data---------------------------------------------------------------------------------46
CHAPTER III: Regio- and chemoselective synthesis of nitrogen-containing heterocycles
via the oxidative cascade cyclization of unactivated 1,n-enynes----------------------------55
3.1. Abstract-----------------------------------------------------------------------------------------56
3.2. Introduction and Background----------------------------------------------------------------56
3.3. Result and Discussion-------------------------------------------------------------------------59
3.4. Conclusion--------------------------------------------------------------------------------------73
3.5. Experimental Section-------------------------------------------------------------------------73
3.6. Analytical data --------------------------------------------------------------------------------77
CHAPTER IV: Alkene versus alkyne reactivity in unactivated 1,6-enynes: regio and chemoselective radical cyclization with chalcogens under metal- and oxidant-free conditions--------------------------------------------------------------------93
4.1. Abstract-----------------------------------------------------------------------------------------94
4.2. Introduction and Background----------------------------------------------------------------94
4.3. Result and Discussion-------------------------------------------------------------------------98
4.4. Conclusion------------------------------------------------------------------------------------110
4.5. Experimental Section------------------------------------------------------------------------110
4.6. Analytical data -------------------------------------------------------------------------------113

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